Safety Data Sheet Regulation EC No 1907/2006 Art.31
Productname : Galva Brite Creationdate : 19.09.16 Version : 3.0
Ref.Nr.: BDS000214_3_20160919 (EN) Replaces: BDS000214_20150423
 
 
This is a translation of the standard EU-safety data sheet, therefore national data are not included.
 
SECTION 1: Identification of the substance/mixture and of the company/undertaking
 
1.1. Product identifier
 
 
Galva Brite
Aerosol
 
1.2. Relevant identified uses of the substance or mixture and uses advised against
 
Anti Corrosion Products
 
1.3. Details of the supplier of the safety data sheet
 
 
CRC Industries Europe bvba
Touwslagerstraat 1
9240 Zele
Belgium
Tel.: +32(0)52/45.60.11
Fax.: +32(0)52/45.00.34
E-mail : hse@crcind.com
 
SubsidiariesTelFax
CRC Industries Finland OyLaurinkatu 57 A 23 B, 08100 Lohja+358/(19)32.921
CRC Industries France6, avenue du marais, C.S. 90028, 95102 Argenteuil Cedex01.34.11.20.0001.34.11.09.96
CRC Industries Deutschland GmbHSüdring 9, D-76473 Iffezheim(07229) 303 0(07229)30 32 66
CRC INDUSTRIES IBERIA S.L.U.GREMIO DEL CUERO-PARC.96, POLIGONO INDUSTR. DE HONTORIA, 40195 SEGOVIA0034/921.427.5460034/921.436.270
CRC Industries SwedenLaxfiskevägen 16, 433 38 Partille0046/31 706 84 800046/31 27 39 91
 
1.4. Emergency telephone number
 
 
CRC Industries Europe, Belgium: Tel.: +32(0)52/45.60.11 (office hours: 9-17h pm CET)
 
SECTION 2: Hazards identification
 
2.1. Classification of the substance or mixture
 
Classification according to Regulation (EC) No 1272/2008
 
Physical: Aerosols, category 1
 Extremely flammable aerosol.
 Pressurised container: May burst if heated.
Health: Specific target organ toxicity - single exposure, category 3
 May cause drowsiness or dizziness.
 Specific Target Organ Toxicity - Repeated Exposure Category 1
 Causes damage to organs through prolonged or repeated exposure.
Environment: Hazardous to the aquatic environment, chronic category 2
 Toxic to aquatic life with long lasting effects.
 
2.2. Label elements
 
Labelling according to Regulation (EC) No 1272/2008
 
Hazard pictogram(s):
Signal word: Danger
Hazard statement(s): H222 : Extremely flammable aerosol.
 H229 : Pressurised container: May burst if heated.
 H336 : May cause drowsiness or dizziness.
 H372 : Causes damage to organs through prolonged or repeated exposure.
 H411 : Toxic to aquatic life with long lasting effects.
Precautionary statement(s): P102 : Keep out of reach of children.
P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
 P211 : Do not spray on an open flame or other ignition source.
 P251 : Do not pierce or burn, even after use.
 P260 : Do not breathe dust/fume/gas/mist/vapours/spray.
 P271 : Use only outdoors or in a well-ventilated area.
P314 : Get medical advice/attention if you feel unwell.
P410/412 : Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
P501-2 : Dispose of contents/container to an authorised waste collection point.
Supplemental Hazard information: None
 
2.3. Other hazards
 
None
 
SECTION 3: Composition/information on ingredients
 
3.1. Substances
 
Not applicable.
 
3.2. Mixtures
 
 
Hazardous ingredientRegistration numberCAS-nr.EC-nrw/w %Hazard Class and CategoryHazard statementNotes
dimethyl ether01-2119472128-37115-10-6204-065-850-75Flam. Gas 1, Press. GasH220,H280A
Hydrocarbons, C9-12, n-alkanes, isoalkanes, cyclic01-2119458049-33-919-446-05-25Flam. Liq. 3, Asp. Tox. 1, STOT SE 3, STOT RE 1, Aquatic Chronic 2H226,H304,H336,H372,H411B
ethyl acetate01-2119475103-46141-78-6205-500-45-10Flam. Liq. 2, Eye Irrit. 2, STOT SE 3H225,H319,H336B
n-butyl acetate01-2119485493-29123-86-4204-658-11-5Flam. Liq. 3, STOT SE 3H226,H336
Hydrocarbons, C9, aromatics01-2119455851-35-918-668-50-5Flam. Liq. 3, STOT SE 3, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2H226,H335,H336,H304,H411
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics01-2119463258-3364742-48-9919-857-50-5Flam. Liq. 3, Asp. Tox. 1, STOT SE 3H226,H304,H336B
zinc oxide01-2119463881-321314-13-2215-222-5<2.5Aquatic Acute 1, Aquatic Chronic 1H400,H410B
2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime01-2119539477-2896-29-7202-496-6<0.1Carc. 2, Acute Tox. 4, Eye Dam. 1, Skin Sens. 1H351,H312,H318,H317B
Explanation notes
A : substance with Community workplace exposure limit
B : substance with national established workplace exposure limit
(* Explanation phrases : see chapter 16)
 
SECTION 4: First aid measures
 
4.1. Description of first aid measures
 
Contact with eyes : If substance has got into eyes, immediately wash out with plenty of water
 If eye irritation persists: Get medical advice/attention.
Contact with skin : Wash with plenty of soap and water.
 If skin irritation occurs: Get medical advice/attention.
Inhalation : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
 Call a POISON CENTER or doctor/physician if you feel unwell.
Ingestion : If swallowed do not induce vomiting because of risk of aspiration into the lungs. If aspiration is suspected obtain immediate medical attention
 
4.2. Most important symptoms and effects, both acute and delayed
 
Inhalation : Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Ingestion : After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia.
 Symptoms : sore throat, abdominal pain, nausea, vomiting
Skin contact : May cause irritation.
 Symptoms : redness and pain
Eye contact : May cause irritation.
 Symptoms : redness and pain
 
4.3. Indication of any immediate medical attention and special treatment needed
 
General Advice : If you feel unwell, seek medical advice (show the label where possible
 If symptoms persist always call a doctor
 
SECTION 5: Firefighting measures
 
5.1. Extinguishing media
 
foam, carbon dioxide or dry agent
 
5.2. Special hazards arising from the substance or mixture
 
Aerosols may explode if heated above 50°C
Forms hazardous decomposition products
CO,CO2
 
5.3. Advice for firefighters
 
Keep container(s) exposed to fire cool, by spraying with water
In case of fire, do not breathe fumes
 
SECTION 6: Accidental release measures
 
6.1. Personal precautions, protective equipment and emergency procedures
 
Shut off all ignition sources
Ensure adequate ventilation
Wear suitable protective clothing and gloves.
 
6.2. Environmental precautions
 
Do not allow to enter public sewers and watercourses
If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities
 
6.3. Methods and material for containment and cleaning up
 
Absorb spillage in suitable inert material
 
6.4. Reference to other sections
 
For further information see section 8
 
SECTION 7: Handling and storage
 
7.1. Precautions for safe handling
 
Keep away from heat and sources of ignition
Take precautionary measures against static discharges
Equipment should be earthed
Use explosion-proof electrical/ventilating/lighting/.../equipment.
Use only non-sparking tools.
Do not breathe aerosols or vapours.
Ensure adequate ventilation
Avoid contact with skin and eyes.
Wash thoroughly after use
Wear protective gloves/protective clothing/eye protection/face protection.
 
7.2. Conditions for safe storage, including any incompatibilities
 
Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C.
Keep out of reach of children.
 
7.3. Specific end use(s)
 
Anti Corrosion Products
 
SECTION 8: Exposure controls/personal protection
 
8.1. Control parameters
 
Exposure limits :
 
 
Hazardous ingredientCAS-nr.method
EU established exposure limits:
dimethyl ether115-10-6TWA1000 ppm
 
8.2. Exposure controls
 
Control procedures : Ensure adequate ventilation
 Keep away from heat and sources of ignition
 Take precautionary measures against static discharges
Personal protection : Take precautions to avoid contact with skin and eyes when handling the product.
 Ensure adequate ventilation
inhalation : In case of insufficient ventilation, wear suitable respiratory equipment.
recommended respiratory protection: Air purifying respirator equiped with organic gas/vapor cartridge (type A)
hands and skin : Wear suitable protective gloves
Recommended gloves: Nitrile
eyes : Wear safety eyewear according to EN 166.
Environmental protection: Avoid release to the environment.
 Collect spillage.
 
SECTION 9: Physical and chemical properties
 
9.1. Information on basic physical and chemical properties
 
(for aerosols data for the product without propellant)
Appearance : physical state : DME propelled liquid.
colour : Grey.
odour : Solvent.
pH : Not applicable.
Boiling point/range : Not available.
Flash point : < 0 °C
Evaporation rate : Not available.
Explosion limits : upper limit : Not available.
lower limit : Not available.
Vapour pressure : Not available.
Relative density : 0.969 g/cm3 (@ 20°C).
Solubility in water : Insoluble in water
Auto-ignition : > 200 °C
Viscosity : Not applicable.
 
9.2. Other information
 
VOC = volatile organic compounds 675 g/l
 
SECTION 10: Stability and reactivity
 
10.1. Reactivity
 
No hazardous reactions known if used for its intended purpose
 
10.2. Chemical stability
 
Stable
 
10.3. Possibility of hazardous reactions
 
No hazardous reactions known if used for its intended purpose
 
10.4. Conditions to avoid
 
Avoid overheating
 
10.5. Incompatible materials
 
Strong oxidising agent
 
10.6. Hazardous decomposition products
 
CO,CO2
 
SECTION 11: Toxicological information
 
11.1. Information on toxicological effects
 
acute toxicity: based on available data the classification criteria are not met
skin corrosion/irritation: based on available data the classification criteria are not met
serious eye damage/irritation: based on available data the classification criteria are not met
respiratory or skin sensitisation: based on available data the classification criteria are not met
germ cell mutagenicity: based on available data the classification criteria are not met
carcinogenicity: based on available data the classification criteria are not met
toxicity for reproduction: based on available data the classification criteria are not met
STOT-single exposure: May cause drowsiness or dizziness.
STOT repeated exposure: Causes damage to organs through prolonged or repeated exposure.
 
Information on likely routes of exposure:
 
Inhalation : Inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Ingestion : After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia.
Skin contact : Prolonged skin contact will result in defatting of the skin, leading to irritation, and in some cases, dermatitis
 Repeated exposure may cause skin dryness or cracking.
Eye contact : May cause irritation.
 
Toxicological data :
 
 
Hazardous ingredientCAS-nr.method
dimethyl ether115-10-6LC50 inhal.rat309 mg/l
n-butyl acetate123-86-4LD50 oral rat10760 mg/kg
LC50 inhal.rat> 20 mg/l
LD50 derm.rabit> 1400 mg/kg
zinc oxide1314-13-2LC50 inhal.rat> 5.7 mg/l
ethyl acetate141-78-6LD50 oral rat5620 mg/kg
LC50 inhal.rat30 mg/l
LD50 derm.rabit> 20000 mg/kg
2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime96-29-7LD50 oral rat2326 mg/kg
LD50 derm.rabit1000 mg/kg
Hydrocarbons, C9, aromatics-LD50 oral rat3492 mg/kg
LC50 inhal.rat> 6.393 mg/l
LD50 derm.rabit> 3160 mg/kg
Hydrocarbons, C9-12, n-alkanes, isoalkanes, cyclic-LD50 oral rat> 5000 mg/kg
LC50 inhal.rat> 10 mg/l
LD50 derm.rabit> 4 mg/kg
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics64742-48-9LD50 oral rat>5000 mg/kg
LC50 inhal.rat4951 mg/m3
LD50 derm.rabit>5000 mg/kg
 
SECTION 12: Ecological information
 
12.1. Toxicity
 
Hazardous to the aquatic environment, chronic category 2
Toxic to aquatic life with long lasting effects.
 
Ecotoxicological data:
 
 
Hazardous ingredientCAS-nr.method
dimethyl ether115-10-6IC50 algae154.9 mg/l
LC50 fish4.1 mg/l
EC50 daphnia4.4 mg/l
n-butyl acetate123-86-4IC50 algae647 mg/l
LC50 fish18 mg/l
EC50 daphnia44 mg/l
zinc oxide1314-13-2IC50 algae0.136 mg/l
LC50 fish0.169 mg/l
EC50 daphnia1.7 mg/l
ethyl acetate141-78-6IC50 algae5600 mg/l
LC50 fish230 mg/l
EC50 daphnia610 mg/l
2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime96-29-7IC50 algae11.8 mg/l
LC50 fish> 100 mg/l
EC50 daphnia201 mg/l
Hydrocarbons, C9-12, n-alkanes, isoalkanes, cyclic-IC50 algae4.6-10 mg/l
LC50 fish10-30 mg/l
EC50 daphnia10-22 mg/l
 
12.2. Persistence and degradability
 
No experimental data available
 
12.3. Bioaccumulative potential
 
No experimental data available
 
12.4. Mobility in soil
 
Insoluble in water
 
12.5. Results of PBT and vPvB assessment
 
No information available
 
12.6. Endocrine disrupting properties
 
No experimental data available
(calculated in accordance with Annex IV of Regulation (EU) No 517/2014 on fluorinated greenhouse gases)
 
SECTION 13: Disposal considerations
 
13.1. Waste treatment methods
 
Product : This material and its container must be disposed of in a safe way.
 Do not discharge into drains or the environment, dispose to an authorised waste collection point.
National regulations : Disposal should be in accordance with local, state or national legislation
 
SECTION 14: Transport information
 
14.1. UN number
 
UN-number : 1950
 
14.2. UN proper shipping name
 
Proper shipping name: AEROSOLS (zinc oxide)
 
14.3. Transport hazard class(es)
 
Class: 2.1
ADR/RID - Classification code: 5F
 
14.4. Packing group
 
Packing group: Not applicable.
 
14.5. Environmental hazards
 
ADR/RID - Environmentally hazardous: Yes
IMDG - Marine pollutant: Marine pollutant
IATA/ICAO - Environmentally hazardous: Yes
 
14.6. Special precautions for user
 
ADR/RID - Tunnelcode: (D)
IMDG - Ems: F-D, S-U
IATA/ICAO - PAX: 203
IATA/ICAO - CAO 203
 
14.7. Maritime transport in bulk according to IMO instruments
 
Not applicable.
 
SECTION 15: Regulatory information
 
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
 
The Safety Data Sheet is compiled according to the current European requirements.
Dir. 2013/10/EU, 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC.
Regulation (EC) No 1907/2006 (REACH)
EU-directive 99/45/EC
Regulation (EC) No 1272/2008 (CLP)
 
15.2. Chemical safety assessment
 
No information available
 
SECTION 16: Other information
 
*Explanation hazard statements: H220 : Extremely flammable gas.
 H225 : Highly flammable liquid and vapour.
 H226 : Flammable liquid and vapour.
 H280 : Contains gas under pressure; may explode if heated.
 H304 : May be fatal if swallowed and enters airways.
 H312 : Harmful in contact with skin.
 H317 : May cause an allergic skin reaction.
 H318 : Causes serious eye damage.
 H319 : Causes serious eye irritation.
 H335 : May cause respiratory irritation.
 H336 : May cause drowsiness or dizziness.
 H351 : Suspected of causing cancer .
 H372 : Causes damage to organs through prolonged or repeated exposure.
 H400 : Very toxic to aquatic life.
 H410 : Very toxic to aquatic life with long lasting effects.
 H411 : Toxic to aquatic life with long lasting effects.
REVISIONS IN CHAPTRE : Classification according to Regulation (EC) No 1272/2008
 Labelling according to Regulation (EC) No 1272/2008
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.