Robosure_Bulk_English
Safety Data Sheet Regulation EC No 1907/2006 Art.31
Productname : Robosure Creationdate : 27.04.20 Version : 3.0
Ref.Nr.: BDS000226_3_20200427 (EN) Replaces: BDS000226_20190416
 
SECTION 1: Identification of the substance/mixture and of the company/undertaking
 
1.1. Product identifier
 
 
Robosure
Bulk
 
1.2. Relevant identified uses of the substance or mixture and uses advised against
 
Release Agents
 
1.3. Details of the supplier of the safety data sheet
 
 
CRC Industries Europe BV
Touwslagerstraat 1
9240 Zele
Belgium
Tel.: +32(0)52/45.60.11
Fax.: +32(0)52/45.00.34
E-mail : hse@crcind.com
 
SubsidiariesTelFax
CRC Industries Finland OySmedsgatan 3-5 LT4, PL62, 08101 LOJO+358/(19)32.921
CRC Industries France6, avenue du marais, C.S. 90028, 95102 Argenteuil Cedex01.34.11.20.0001.34.11.09.96
CRC Industries Deutschland GmbHSüdring 9, D-76473 Iffezheim(07229) 303 0(07229)30 32 66
CRC INDUSTRIES IBERIA S.L.U.GREMIO DEL CUERO-PARC.96, POLIGONO INDUSTR. DE HONTORIA, 40195 SEGOVIA0034/921.427.5460034/921.436.270
CRC Industries SwedenLaxfiskevägen 16, 433 38 Partille0046/31 706 84 800046/31 27 39 91
 
1.4. Emergency telephone number
 
 
CRC Industries Europe, Belgium: Tel.: +32(0)52/45.60.11 (office hours: 9-17h pm CET)
 
SECTION 2: Hazards identification
 
2.1. Classification of the substance or mixture
 
Classification according to Regulation (EC) No 1272/2008
 
Physical: Not classified
Classification is based on test data.
Health: Skin sensitization, category 1
 May cause an allergic skin reaction.
Classification based on calculation method.
Environment: Not classified
Classification based on calculation method.
Other hazards : Not classified
 
2.2. Label elements
 
Labelling according to Regulation (EC) No 1272/2008
 
Product identifier: Contains:
 2-methyl-2H-isothiazol-3-one
Hazard pictogram(s):      
Signal word: Warning
Hazard statement(s): H317 : May cause an allergic skin reaction.
P280-1 : Wear protective gloves/protective clothing.
P302/352 : IF ON SKIN: Wash with plenty of water.
 P333/313 : If skin irritation or rash occurs: Get medical advice/attention.
P501-2 : Dispose of contents/container to an authorised waste collection point.
 
2.3. Other hazards
 
No information available
 
SECTION 3: Composition/information on ingredients
 
3.1. Substances
 
Not applicable.
 
3.2. Mixtures
 
 
Hazardous ingredientRegistration numberCAS-nr.EC-nrw/w %Hazard Class and CategoryHazard statementNotes
triethanolamine01-2119486482-31102-71-6203-049-81-5--B
1,2-benzisothiazol-3(2H)-one-2634-33-5220-120-9<0.005Acute Tox. 2, Acute Tox. 4, Skin Irrit. 2, Eye Dam. 1, Skin Sens. 1, Aquatic Acute 1, Aquatic Chronic 2H330,H302,H315,H318,H317,H400,H411X,R
2-methyl-2H-isothiazol-3-one2682-20-4220-239-60.001-0.005Acute Tox. 3, Acute Tox. 2, Skin Corr. 1B, Eye Dam. 1, Skin Sens. 1, Aquatic Acute 1, Aquatic Chronic 2H301,H330,H314,H318,H317,H400,H411M,X
Explanation notes
B : substance with national established workplace exposure limit
M : M acute = 10
R : substance in plant protection or biocidal product regarded as being registered (art.15 REACH Regulation No 1907/2006)
X : SCL (specific concentration limit)in accordance with art.10 of CLP Regulation No 1272/2008
(* Explanation phrases : see chapter 16)
 
SECTION 4: First aid measures
 
4.1. Description of first aid measures
 
Contact with eyes : If substance has got into eyes, immediately wash out with plenty of water for several minutes
 Seek medical attention if irritation persists
Contact with skin : Wash with water and soap.
 Seek medical attention if irritation persists
Inhalation : Fresh air, keep warm and at rest.
 Seek medical attention if ill effects occur
Ingestion : Seek medical attention if ill effects occur
 
4.2. Most important symptoms and effects, both acute and delayed
 
Inhalation : Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Ingestion : May cause gastrointestinal disturbances
Skin contact : May cause sensitization by skin contact.
 Symptoms : redness and pain
Eye contact : Mildly irritating to eyes
 Symptoms : redness and pain
 
4.3. Indication of any immediate medical attention and special treatment needed
 
General Advice : If skin irritation or rash occurs: Get medical advice/attention.
 
SECTION 5: Firefighting measures
 
5.1. Extinguishing media
 
water, foam, carbon dioxide or dry agent
 
5.2. Special hazards arising from the substance or mixture
 
May form explosive vapour/air mixtures
Forms hazardous decomposition products
CO,CO2
 
5.3. Advice for firefighters
 
Keep container(s) exposed to fire cool, by spraying with water
In case of fire, do not breathe fumes
 
SECTION 6: Accidental release measures
 
6.1. Personal precautions, protective equipment and emergency procedures
 
Shut off all ignition sources
Ensure adequate ventilation
Wear suitable protective clothing including eye/face protection.
 
6.2. Environmental precautions
 
Do not allow to enter public sewers and watercourses
 
6.3. Methods and material for containment and cleaning up
 
Absorb spillage in suitable inert material
 
6.4. Reference to other sections
 
For further information see section 8
 
SECTION 7: Handling and storage
 
7.1. Precautions for safe handling
 
Keep away from heat and sources of ignition
It is advisable to take precautions to avoid contact with skin and eyes when handling the product.
Ensure adequate ventilation
Avoid contact with skin and eyes.
Wash thoroughly after use
Wear protective gloves/protective clothing/eye protection/face protection.
 
7.2. Conditions for safe storage, including any incompatibilities
 
Keep container tightly closed, in a cool, well ventilated place.
Keep out of reach of children.
 
7.3. Specific end use(s)
 
Release Agents
 
SECTION 8: Exposure controls/personal protection
 
8.1. Control parameters
 
Exposure limits :
 
 
Hazardous ingredientCAS-nr.method
National established exposure limits, Ireland
triethanolamine102-71-6TWA5 mg/m3
STEL-
 
8.2. Exposure controls
 
Control procedures : Ensure adequate ventilation
Keep away from heat and sources of ignition
Personal protection : Take precautions to avoid contact with skin and eyes when handling the product.
Ensure adequate ventilation
inhalation : In case of insufficient ventilation, wear suitable respiratory equipment.
recommended respiratory protection: Air purifying respirator equiped with organic gas/vapor cartridge (type A)
hands and skin : When handling the product wear chemical-resistant gloves (standard EN 374).
 The breakthrough time of the glove should be longer than the total duration of product use. If work lasts longer than the breakthrough time, gloves should be changed part-way through.
Recommended gloves: Nitrile
eyes : Wear safety eyewear according to EN 166.
 
SECTION 9: Physical and chemical properties
 
9.1. Information on basic physical and chemical properties
 
Appearance : physical state : Liquid.
colour : White.
odour : Not applicable.
pH : 9-9.5
Boiling point/range : Not available.
Flash point : None
Explosion limits : upper limit : Not available.
lower limit : Not available.
Vapour pressure : Not available.
Relative density : 0.95 g/cm3 (@ 20°C).
Solubility in water : Soluble in water
Auto-ignition : > 200 °C
 
9.2. Other information
 
SECTION 10: Stability and reactivity
 
10.1. Reactivity
 
No hazardous reactions known if used for its intended purpose
 
10.2. Chemical stability
 
Stable
 
10.3. Possibility of hazardous reactions
 
No hazardous reactions known if used for its intended purpose
 
10.4. Conditions to avoid
 
Avoid overheating
 
10.5. Incompatible materials
 
Strong oxidising agent
 
10.6. Hazardous decomposition products
 
CO,CO2
 
SECTION 11: Toxicological information
 
11.1. Information on toxicological effects
 
acute toxicity: based on available data the classification criteria are not met
skin corrosion/irritation: based on available data the classification criteria are not met
serious eye damage/irritation: based on available data the classification criteria are not met
respiratory or skin sensitisation: May cause an allergic skin reaction.
germ cell mutagenicity: based on available data the classification criteria are not met
carcinogenicity: based on available data the classification criteria are not met
toxicity for reproduction: based on available data the classification criteria are not met
STOT-single exposure: based on available data the classification criteria are not met
STOT repeated exposure: based on available data the classification criteria are not met
aspiration hazard: based on available data the classification criteria are not met
 
Information on likely routes of exposure:
 
Inhalation : Inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Ingestion : May cause gastrointestinal disturbances
Skin contact : May cause sensitization by skin contact.
Eye contact : May cause irritation.
 
Toxicological data :
 
 
Hazardous ingredientCAS-nr.method
triethanolamine102-71-6LD50 oral rat6400 mg/kg
LC50 inhal.rat1.8 mg/m3
LD50 derm.rabit> 2000 mg/kg
 
SECTION 12: Ecological information
 
12.1. Toxicity
 
Not classified
 
Ecotoxicological data:
 
 
Hazardous ingredientCAS-nr.method
triethanolamine102-71-6LC50 fish1460 mg/l
EC50 daphnia609.9 mg/l
 
12.2. Persistence and degradability
 
No experimental data available
 
12.3. Bioaccumulative potential
 
No experimental data available
 
12.4. Mobility in soil
 
Soluble in water
 
12.5. Results of PBT and vPvB assessment
 
No information available
 
12.6. Endocrine disrupting properties
 
No experimental data available
 
SECTION 13: Disposal considerations
 
13.1. Waste treatment methods
 
Do not discharge into drains or the environment, dispose to an authorised waste collection point.
 
SECTION 14: Transport information
 
14.1. UN number
 
UN-number : Not classified as hazardous for transport
 
14.2. UN proper shipping name
 
Proper shipping name: Not applicable.
 
14.3. Transport hazard class(es)
 
Class: Not applicable.
ADR/RID - Classification code: Not applicable.
 
14.4. Packing group
 
Packing group: Not applicable.
 
14.5. Environmental hazards
 
ADR/RID - Environmentally hazardous: No
IMDG - Marine pollutant: No
IATA/ICAO - Environmentally hazardous: No
 
14.6. Special precautions for user
 
ADR/RID - Tunnelcode: Not applicable.
IMDG - Ems: Not applicable.
IATA/ICAO - PAX: Not applicable.
IATA/ICAO - CAO Not applicable.
 
14.7. Maritime transport in bulk according to IMO instruments
 
Not applicable.
 
SECTION 15: Regulatory information
 
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
 
The Safety Data Sheet is compiled according to the current European requirements.
Regulation (EC) No 1907/2006 (REACH)
Regulation (EC) No 1272/2008 (CLP)
 
15.2. Chemical safety assessment
 
No information available
 
SECTION 16: Other information
 
*Explanation hazard statements: - : -
 H301 : Toxic if swallowed.
 H302 : Harmful if swallowed.
 H314 : Causes severe skin burns and eye damage.
 H315 : Causes skin irritation.
 H317 : May cause an allergic skin reaction.
 H318 : Causes serious eye damage.
 H330 : Fatal if inhaled.
 H400 : Very toxic to aquatic life.
 H411 : Toxic to aquatic life with long lasting effects.
REVISIONS IN CHAPTRE : Classification according to Regulation (EC) No 1272/2008
 Labelling according to Regulation (EC) No 1272/2008
acronyms and synonyms: TWA = time weight average
 STEL = short time exposure limit
 VOC = volatile organic compounds
 PBT = persistant bioaccumulative toxic
 vPvB = very persitant very bioaccumulative
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.