COMPLEX BLUE_Bulk_English
Safety Data Sheet Regulation EC No 1907/2006 Art.31
Productname : COMPLEX BLUE Creationdate : 08.01.19 Version : 2.0
Ref.Nr.: BDS000304_3_20190108 (EN) Replaces: BDS000304_20130506
 
SECTION 1: Identification of the substance/mixture and of the company/undertaking
 
1.1. Product identifier
 
 
COMPLEX BLUE
Bulk
 
1.2. Relevant identified uses of the substance or mixture and uses advised against
 
Cleaners - Heavy duty
 
1.3. Details of the supplier of the safety data sheet
 
 
CRC Industries Europe bvba
Touwslagerstraat 1
9240 Zele
Belgium
Tel.: +32(0)52/45.60.11
Fax.: +32(0)52/45.00.34
E-mail : hse@crcind.com
 
SubsidiariesTelFax
CRC Industries Finland OySmedsgatan 3-5 LT4, PL62, 08101 LOJO+358/(19)32.921
CRC Industries France6, avenue du marais, C.S. 90028, 95102 Argenteuil Cedex01.34.11.20.0001.34.11.09.96
CRC Industries Deutschland GmbHSüdring 9, D-76473 Iffezheim(07229) 303 0(07229)30 32 66
CRC INDUSTRIES IBERIA S.L.U.GREMIO DEL CUERO-PARC.96, POLIGONO INDUSTR. DE HONTORIA, 40195 SEGOVIA0034/921.427.5460034/921.436.270
CRC Industries SwedenLaxfiskevägen 16, 433 38 Partille0046/31 706 84 800046/31 27 39 91
 
1.4. Emergency telephone number
 
 
CRC Industries Europe, Belgium: Tel.: +32(0)52/45.60.11 (office hours: 9-17h pm CET)
 
SECTION 2: Hazards identification
 
2.1. Classification of the substance or mixture
 
Classification according to Regulation (EC) No 1272/2008
 
Physical: Not classified
Classification is based on test data.
Health: Serious eye damage, category 1
 Causes serious eye damage.
Classification based on calculation method.
Environment: Not classified
Classification based on calculation method.
Other hazards : Not classified
 
2.2. Label elements
 
Labelling according to Regulation (EC) No 1272/2008
 
Product identifier: Contains:
 Decan-1-ol, ethoxylated
Hazard pictogram(s):      
Signal word: Danger
Hazard statement(s): H318 : Causes serious eye damage.
Precautionary statement(s): P102 : Keep out of reach of children.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
P305/351/338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 P313 : Get medical advice/attention.
P405 : Store locked up.
P501-2 : Dispose of contents/container to an authorised waste collection point.
 
Regulation (EC) No 648/2004 on detergents:anionic surfactants< 5 %
non-ionic surfactants< 5 %
 
2.3. Other hazards
 
No information available
 
SECTION 3: Composition/information on ingredients
 
3.1. Substances
 
Not applicable.
 
3.2. Mixtures
 
 
Hazardous ingredientRegistration numberCAS-nr.EC-nrw/w %Hazard Class and CategoryHazard statementNotes
Decan-1-ol, ethoxylated -26183-52-8500-046-61-5Acute Tox. 4, Eye Dam. 1H302,H318F,X
(2-methoxymethylethoxy)propanol01-2119450011-6034590-94-8252-104-21-5--A
Explanation notes
A : substance with Community workplace exposure limit
F : not registered due to polymer status (no longer polymer list - directive 92/32/EEC)
X : SCL (specific concentration limit)in accordance with art.10 of CLP Regulation No 1272/2008
(* Explanation phrases : see chapter 16)
 
SECTION 4: First aid measures
 
4.1. Description of first aid measures
 
Contact with eyes : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 Immediately call a POISON CENTER or doctor/physician.
Contact with skin : Take off contaminated clothing and wash before reuse.
 IF ON SKIN: Wash with plenty of water.
 If skin irritation occurs: Get medical advice/attention.
Inhalation : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
 Call a POISON CENTER or doctor/physician if you feel unwell.
Ingestion : If swallowed do not induce vomiting
 Seek medical advice
 
4.2. Most important symptoms and effects, both acute and delayed
 
Inhalation : May cause irritation.
 Symptoms : sore throat, cough
Ingestion : May cause gastrointestinal disturbances
 Symptoms : sore throat, abdominal pain, nausea, vomiting
Skin contact : May cause irritation.
 Symptoms : redness and pain
Eye contact : Risk of serious damage to eyes.
 Symptoms : redness and pain, impaired vision
 
4.3. Indication of any immediate medical attention and special treatment needed
 
General Advice : If you feel unwell, seek medical advice (show the label where possible
 If symptoms persist always call a doctor
 
SECTION 5: Firefighting measures
 
5.1. Extinguishing media
 
foam, carbon dioxide or dry agent
 
5.2. Special hazards arising from the substance or mixture
 
May give off noxious and toxic fumes in a fire
 
5.3. Advice for firefighters
 
Keep container(s) exposed to fire cool, by spraying with water
In case of fire, do not breathe fumes
Wear breathing apparatus
 
SECTION 6: Accidental release measures
 
6.1. Personal precautions, protective equipment and emergency procedures
 
Avoid contact with skin and eyes.
Ensure adequate ventilation
Wear suitable protective clothing including eye/face protection.
 
6.2. Environmental precautions
 
Do not allow to enter public sewers and watercourses
If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities
 
6.3. Methods and material for containment and cleaning up
 
Absorb spillage in suitable inert material
 
6.4. Reference to other sections
 
For further information see section 8
 
SECTION 7: Handling and storage
 
7.1. Precautions for safe handling
 
Do not breathe aerosols or vapours.
Ensure adequate ventilation
Avoid contact with skin and eyes.
Wash thoroughly after use
Wear protective gloves/protective clothing/eye protection/face protection.
Eyewash bottles should be available
 
7.2. Conditions for safe storage, including any incompatibilities
 
Keep container tightly closed, in a cool, well ventilated place.
Keep out of reach of children.
 
7.3. Specific end use(s)
 
Cleaners - Heavy duty
 
SECTION 8: Exposure controls/personal protection
 
8.1. Control parameters
 
Exposure limits :
 
 
Hazardous ingredientCAS-nr.method
EU established exposure limits:
(2-methoxymethylethoxy)propanol34590-94-8TWA50 ppm
National established exposure limits, United Kingdom
(2-methoxymethylethoxy)propanol34590-94-8TWA50 ppm
National established exposure limits, Ireland
(2-methoxymethylethoxy)propanol34590-94-8TWA50 ppm
STEL-
 
8.2. Exposure controls
 
Control procedures : Ensure adequate ventilation
Personal protection : Take precautions to avoid contact with skin and eyes when handling the product.
Ensure adequate ventilation
inhalation : In case of insufficient ventilation, wear suitable respiratory equipment.
recommended respiratory protection: Air purifying respirator equiped with ABEK type cartridge
hands and skin : When handling the product wear chemical-resistant gloves (standard EN 374).
 The breakthrough time of the glove should be longer than the total duration of product use. If work lasts longer than the breakthrough time, gloves should be changed part-way through.
Recommended gloves: Nitrile
eyes : Wear safety eyewear according to EN 166.
Environmental protection: Avoid release to the environment.
 Collect spillage.
 
SECTION 9: Physical and chemical properties
 
9.1. Information on basic physical and chemical properties
 
Appearance : physical state : Liquid.
colour : Blue.
odour : Neutral.
pH : 11
Boiling point/range : 100 °C
Flash point : None
Evaporation rate : Not applicable.
Explosion limits : upper limit : Not available.
lower limit : Not available.
Vapour pressure : Not available.
Relative density : 1.01 g/cm3 (@ 20°C).
Solubility in water : Soluble in water
Auto-ignition : > 200 °C
Viscosity : Not available.
 
9.2. Other information
 
VOC = volatile organic compounds 41 g/l
 
SECTION 10: Stability and reactivity
 
10.1. Reactivity
 
No hazardous reactions known if used for its intended purpose
 
10.2. Chemical stability
 
Stable
 
10.3. Possibility of hazardous reactions
 
In case of fire, do not breathe fumes
May give off noxious and toxic fumes in a fire
 
10.4. Conditions to avoid
 
heat
 
10.5. Incompatible materials
 
Strong oxidising agent
 
10.6. Hazardous decomposition products
 
CO,CO2
 
SECTION 11: Toxicological information
 
11.1. Information on toxicological effects
 
acute toxicity: based on available data the classification criteria are not met
skin corrosion/irritation: based on available data the classification criteria are not met
serious eye damage/irritation: Causes serious eye damage.
respiratory or skin sensitisation: based on available data the classification criteria are not met
germ cell mutagenicity: based on available data the classification criteria are not met
carcinogenicity: based on available data the classification criteria are not met
toxicity for reproduction: based on available data the classification criteria are not met
STOT-single exposure: based on available data the classification criteria are not met
STOT repeated exposure: based on available data the classification criteria are not met
aspiration hazard: based on available data the classification criteria are not met
 
Information on likely routes of exposure:
 
Inhalation : May cause irritation.
Ingestion : May cause gastrointestinal disturbances
Skin contact : May cause irritation.
Eye contact : Risk of serious damage to eyes.
 
Toxicological data :
 
 
Hazardous ingredientCAS-nr.method
Decan-1-ol, ethoxylated 26183-52-8LD50 oral rat1000 mg/kg
LD50 derm.rat> 2000 mg/kg
(2-methoxymethylethoxy)propanol34590-94-8LD50 oral rat> 5000 mg/kg
LD50 derm.rabit> 10000 mg/kg
 
SECTION 12: Ecological information
 
12.1. Toxicity
 
Not classified
 
Ecotoxicological data:
 
 
Hazardous ingredientCAS-nr.method
Decan-1-ol, ethoxylated 26183-52-8IC50 algae< 47 mg/l
LC50 fish< 7 mg/l
EC50 daphnia5.3 mg/l
(2-methoxymethylethoxy)propanol34590-94-8IC50 algae> 100 mg/l
LC50 fish> 10000 mg/l
EC50 daphnia> 100 mg/l
 
12.2. Persistence and degradability
 
Readily biodegradable - OECD 301B
 
12.3. Bioaccumulative potential
 
No experimental data available
 
12.4. Mobility in soil
 
Soluble in water
 
12.5. Results of PBT and vPvB assessment
 
No information available
 
12.6. Endocrine disrupting properties
 
No experimental data available
 
SECTION 13: Disposal considerations
 
13.1. Waste treatment methods
 
Do not discharge into drains or the environment, dispose to an authorised waste collection point.
 
SECTION 14: Transport information
 
14.1. UN number
 
UN-number : Not classified as hazardous for transport
 
14.2. UN proper shipping name
 
Proper shipping name: Not applicable.
 
14.3. Transport hazard class(es)
 
Class: Not applicable.
ADR/RID - Classification code: Not applicable.
 
14.4. Packing group
 
Packing group: Not applicable.
 
14.5. Environmental hazards
 
ADR/RID - Environmentally hazardous: No
IMDG - Marine pollutant: No
IATA/ICAO - Environmentally hazardous: No
 
14.6. Special precautions for user
 
ADR/RID - Tunnelcode: Not applicable.
IMDG - Ems: Not applicable.
 
14.7. Maritime transport in bulk according to IMO instruments
 
Not applicable.
 
SECTION 15: Regulatory information
 
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
 
The Safety Data Sheet is compiled according to the current European requirements.
Regulation (EC) No 1907/2006 (REACH)
Regulation (EC) No 1272/2008 (CLP)
 
15.2. Chemical safety assessment
 
No information available
 
SECTION 16: Other information
 
*Explanation hazard statements: - : -
 H302 : Harmful if swallowed.
 H318 : Causes serious eye damage.
REVISIONS IN CHAPTRE : 2.2. Label elements
 8.2. Exposure controls
acronyms and synonyms: TWA = time weight average
 STEL = short time exposure limit
 VOC = volatile organic compounds
 PBT = persistant bioaccumulative toxic
 vPvB = very persitant very bioaccumulative
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.