FORMULA 20_Aerosol_English
Safety Data Sheet Regulation EC No 1907/2006 Art.31
Productname : FORMULA 20 Creationdate : 29.06.17 Version : 4.0
Ref.Nr.: BDS000508_3_20170629 (EN) Replaces: BDS000508_20170106
 
SECTION 1: Identification of the substance/mixture and of the company/undertaking
 
1.1. Product identifier
 
 
FORMULA 20
Aerosol
 
1.2. Relevant identified uses of the substance or mixture and uses advised against
 
Release Agents
 
1.3. Details of the supplier of the safety data sheet
 
 
CRC Industries UK Ltd.
Wylds Road
Castlefield Industrial Estate
TA6 4DD Bridgwater Somerset
United Kingdom
Tel.: +44 1278 727200
Fax.: +44 1278 425644
E-mail : hse.uk@crcind.com
 
1.4. Emergency telephone number
 
 
(+44)(0)1278 72 7200 (office hours)
 
SECTION 2: Hazards identification
 
2.1. Classification of the substance or mixture
 
Classification according to Regulation (EC) No 1272/2008
 
Physical: Aerosols, category 1
 Extremely flammable aerosol.
 Pressurised container: May burst if heated.
Classification is based on test data.
Health: Skin irritation, category 2
 Causes skin irritation.
 Specific target organ toxicity - single exposure, category 3
 May cause drowsiness or dizziness.
Classification based on calculation method.
Environment: Hazardous to the aquatic environment, chronic category 2
 Toxic to aquatic life with long lasting effects.
Classification based on calculation method.
 
2.2. Label elements
 
Labelling according to Regulation (EC) No 1272/2008
 
Product identifier: Contains:
 hydrocarbons
Hazard pictogram(s):  
Signal word: Danger
Hazard statement(s): H222 : Extremely flammable aerosol.
 H229 : Pressurised container: May burst if heated.
 H315 : Causes skin irritation.
 H336 : May cause drowsiness or dizziness.
 H411 : Toxic to aquatic life with long lasting effects.
Precautionary statement(s): P102 : Keep out of reach of children.
P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
 P211 : Do not spray on an open flame or other ignition source.
 P251 : Do not pierce or burn, even after use.
 P261 : Avoid breathing dust/fume/gas/mist/vapours/spray.
 P271 : Use only outdoors or in a well-ventilated area.
P410/412 : Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
P501-2 : Dispose of contents/container to an authorised waste collection point.
Supplemental Hazard information: Contains fluorinated greenhouse gases:
 HFC-134a
 quantity expressed in weight and CO2 equivalent depend on actual volume of the packaging: see label
GWP mixture: see section 12.6
 
2.3. Other hazards
 
No information available
 
SECTION 3: Composition/information on ingredients
 
3.1. Substances
 
Not applicable.
 
3.2. Mixtures
 
 
Hazardous ingredientRegistration numberCAS-nr.EC-nrw/w %Hazard Class and CategoryHazard statementNotes
pentane01-2119459286-30109-66-0203-692-425-50Flam. Liq. 2, Asp. Tox. 1, STOT SE 3, Aquatic Chronic 2H225,H304,H336,H411A
hydrocarbons,C6,isoalkanes,< 5% n-hexane01-2119484651-34-(931-254-9)25-50Flam. Liq. 2, Skin Irrit. 2, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2H225,H315,H336,H304,H411Q
tetrafluoroethane01-2119459374-33811-97-2212-377-010-25Press. GasH280B
carbon dioxide-124-38-9204-696-91-5Press. GasH280A,G
Methyldodecyl,methyl(2-fenylpropyl)siloxaan-68037-76-31-5Aquatic Chronic 2H411
Explanation notes
A : substance with Community workplace exposure limit
B : substance with national established workplace exposure limit
G : exempted from the obligation to register in accordance with art.2(7)of REACH Regulation No 1907/2006
Q : The CAS-no is only an indicative identifier to be used outside the EU for global inventory entries.
(* Explanation phrases : see chapter 16)
 
SECTION 4: First aid measures
 
4.1. Description of first aid measures
 
Contact with eyes : IF IN EYES:
 Rinse cautiously with water for several minutes.
 If eye irritation persists: Get medical advice/attention.
Contact with skin : Take off contaminated clothing and wash before reuse.
 IF ON SKIN:
 Rinse cautiously with water for several minutes.
 If skin irritation occurs: Get medical advice/attention.
Inhalation : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
 Call a POISON CENTER or doctor/physician if you feel unwell.
Ingestion : If swallowed do not induce vomiting because of risk of aspiration into the lungs. If aspiration is suspected obtain immediate medical attention
 
 
4.2. Most important symptoms and effects, both acute and delayed
 
Inhalation : Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Ingestion : After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia.
 Symptoms : sore throat, abdominal pain, nausea, vomiting
Skin contact : Irritating to skin
 Symptoms : redness and pain
Eye contact : May cause irritation.
 Symptoms : redness and pain
 
4.3. Indication of any immediate medical attention and special treatment needed
 
General Advice : If you feel unwell, seek medical advice (show the label where possible
 If symptoms persist always call a doctor
 
SECTION 5: Firefighting measures
 
5.1. Extinguishing media
 
foam, carbon dioxide or dry agent
 
5.2. Special hazards arising from the substance or mixture
 
Aerosols may explode if heated above 50°C
Forms hazardous decomposition products
CO,CO2
HF may be formed
 
5.3. Advice for firefighters
 
Keep container(s) exposed to fire cool, by spraying with water
In case of fire, do not breathe fumes
 
SECTION 6: Accidental release measures
 
6.1. Personal precautions, protective equipment and emergency procedures
 
Shut off all ignition sources
Ensure adequate ventilation
Wear suitable protective clothing and gloves.
 
6.2. Environmental precautions
 
Do not allow to enter public sewers and watercourses
 
6.3. Methods and material for containment and cleaning up
 
Absorb spillage in suitable inert material
 
6.4. Reference to other sections
 
For further information see section 8
 
SECTION 7: Handling and storage
 
7.1. Precautions for safe handling
 
Keep away from heat and sources of ignition
Take precautionary measures against static discharges
Equipment should be earthed
Use explosion-proof electrical/ventilating/lighting/.../equipment.
Use only non-sparking tools.
Do not breathe aerosols or vapours.
Ensure adequate ventilation
Avoid contact with skin and eyes.
Wash thoroughly after use
Wear protective gloves/protective clothing/eye protection/face protection.
 
7.2. Conditions for safe storage, including any incompatibilities
 
Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C.
Keep out of reach of children.
 
7.3. Specific end use(s)
 
Release Agents
 
SECTION 8: Exposure controls/personal protection
 
8.1. Control parameters
 
Exposure limits :
 
 
Hazardous ingredientCAS-nr.method
EU established exposure limits:
pentane109-66-0TWA1000 ppm
carbon dioxide124-38-9TWA9000 mg/m3
STEL1800 mg/m3
National established exposure limits, United Kingdom
pentane109-66-0TWA600 ppm
carbon dioxide124-38-9TWA5000 ppm
STEL15000 ppm
tetrafluoroethane811-97-2TWA1000 ppm
 
8.2. Exposure controls
 
Control procedures : Ensure adequate ventilation
 Keep away from heat and sources of ignition
 Take precautionary measures against static discharges
Personal protection : Take precautions to avoid contact with skin and eyes when handling the product.
 In all cases handle and use the product in accordance with good industrial hygiene practices.
 Ensure adequate ventilation
inhalation : In case of insufficient ventilation, wear suitable respiratory equipment.
recommended respiratory protection: Air purifying respirator equiped with organic gas/vapor cartridge (type AX)
hands and skin : When handling the product wear chemical-resistant gloves (standard EN 374).
 Use a reusable glove with a minimum breakthrough time of 30 minutes. The breakthrough time of the glove should be longer than the total duration of product use. If work lasts longer than the breakthrough time, gloves should be changed part-way through.
Recommended gloves: Nitrile
eyes : Wear safety eyewear according to EN 166.
Environmental protection: Avoid release to the environment.
 Collect spillage.
 
SECTION 9: Physical and chemical properties
 
9.1. Information on basic physical and chemical properties
 
Appearance : physical state : Liquid under pressure.
colour : Colorless.
odour : Solvent.
pH : Not applicable.
Boiling point/range : 40-65 °C
Flash point : < 0 °C
Evaporation rate : Not available.
Explosion limits : upper limit : Not available.
lower limit : Not available.
Vapour pressure : Not available.
Relative density : 0.675 g/cm3 (@ 20°C).
Solubility in water : Insoluble in water
Auto-ignition : > 200 °C
Viscosity : Not available.
 
9.2. Other information
 
VOC = volatile organic compounds 660 g/l
 
SECTION 10: Stability and reactivity
 
10.1. Reactivity
 
No hazardous reactions known if used for its intended purpose
 
10.2. Chemical stability
 
Stable
 
10.3. Possibility of hazardous reactions
 
No hazardous reactions known if used for its intended purpose
 
10.4. Conditions to avoid
 
Avoid overheating
 
10.5. Incompatible materials
 
Strong oxidising agent
 
10.6. Hazardous decomposition products
 
CO,CO2
HF may be formed
 
SECTION 11: Toxicological information
 
11.1. Information on toxicological effects
 
acute toxicity: based on available data the classification criteria are not met
skin corrosion/irritation: Causes skin irritation.
serious eye damage/irritation: based on available data the classification criteria are not met
respiratory or skin sensitisation: based on available data the classification criteria are not met
germ cell mutagenicity: based on available data the classification criteria are not met
carcinogenicity: based on available data the classification criteria are not met
toxicity for reproduction: based on available data the classification criteria are not met
STOT-single exposure: May cause drowsiness or dizziness.
STOT repeated exposure: based on available data the classification criteria are not met
aspiration hazard: based on available data the classification criteria are not met
 
Information on likely routes of exposure:
 
Inhalation : Inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Ingestion : After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia.
Skin contact : Irritating to skin
Eye contact : May cause irritation.
 
Toxicological data :
 
 
Hazardous ingredientCAS-nr.method
pentane109-66-0LD50 oral rat> 5000 mg/kg
LD50 derm.rabit> 3000 mg/kg
tetrafluoroethane811-97-2LC50 inhal.rat567000 ppm
hydrocarbons,C6,isoalkanes,< 5% n-hexane-LD50 oral rat> 5000 mg/kg
LC50 inhal.rat> 20 mg/l
LD50 derm.rabit> 3000 mg/kg
 
SECTION 12: Ecological information
 
12.1. Toxicity
 
Hazardous to the aquatic environment, chronic category 2
Toxic to aquatic life with long lasting effects.
 
Ecotoxicological data:
 
 
Hazardous ingredientCAS-nr.method
tetrafluoroethane811-97-2LC50 fish450 mg/l
EC50 daphnia980 mg/l
hydrocarbons,C6,isoalkanes,< 5% n-hexane-IC50 algae55 mg/l
LC50 fish> 1 mg/l
EC50 daphnia3.87 mg/l
 
12.2. Persistence and degradability
 
No experimental data available
 
12.3. Bioaccumulative potential
 
No experimental data available
 
12.4. Mobility in soil
 
Insoluble in water
 
12.5. Results of PBT and vPvB assessment
 
No information available
 
12.6. Endocrine disrupting properties
 
No experimental data available
GWP (global warming potential): 203
(calculated in accordance with Annex IV of Regulation (EU) No 517/2014 on fluorinated greenhouse gases)
 
SECTION 13: Disposal considerations
 
13.1. Waste treatment methods
 
Product : This material and its container must be disposed of in a safe way.
 Do not discharge into drains or the environment, dispose to an authorised waste collection point.
Contaminated packaging : Disposal should be in accordance with local, state or national legislation
 
SECTION 14: Transport information
 
14.1. UN number
 
UN-number : 1950
 
14.2. UN proper shipping name
 
Proper shipping name: AEROSOLS (pentane, hydrocarbons)
 
14.3. Transport hazard class(es)
 
Class: 2.1
ADR/RID - Classification code: 5F
 
14.4. Packing group
 
Packing group: Not applicable.
 
14.5. Environmental hazards
 
ADR/RID - Environmentally hazardous: Yes
IMDG - Marine pollutant: Marine pollutant
IATA/ICAO - Environmentally hazardous: Yes
 
14.6. Special precautions for user
 
ADR/RID - Tunnelcode: (D)
IMDG - Ems: F-D, S-U
IATA/ICAO - PAX: 203
IATA/ICAO - CAO 203
 
14.7. Maritime transport in bulk according to IMO instruments
 
Not applicable.
 
SECTION 15: Regulatory information
 
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
 
The Safety Data Sheet is compiled according to the current European requirements.
Regulation (EC) No 1907/2006 (REACH)
Regulation (EC) No 1272/2008 (CLP)
Dir. 2013/10/EU, 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC.
 
15.2. Chemical safety assessment
 
No information available
 
SECTION 16: Other information
 
*Explanation hazard statements: H225 : Highly flammable liquid and vapour.
 H280 : Contains gas under pressure; may explode if heated.
 H304 : May be fatal if swallowed and enters airways.
 H315 : Causes skin irritation.
 H336 : May cause drowsiness or dizziness.
 H411 : Toxic to aquatic life with long lasting effects.
REVISIONS IN CHAPTRE : 8.2. Exposure controls
acronyms and synonyms: TWA = time weight average
 STEL = short time exposure limit
 VOC = volatile organic compounds
 PBT = persistant bioaccumulative toxic
 vPvB = very persitant very bioaccumulative
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.