Safety Data Sheet

Regulation EC No 1907/2006 Art.31

Productname :	Galva Shine	Creationdate :	04.09.12 Version : 2.0
Ref.Nr.:	BDS000656_3_20120904 (EN)	Replaces:	BDS000656_20111109

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Galva Shine

Aerosol

1.2. Relevant identified uses of the substance or mixture and uses advised against

Anti Corrosion Products

1.3. Details of the supplier of the safety data sheet

CRC Industries UK Ltd.

Wylds Road

Castlefield Industrial Estate

TA6 4DD Bridgwater Somerset

United Kingdom

Tel.: +44 1278 727200

Fax.: +44 1278 425644

E-mail : hse.uk@crcind.com

1.4. Emergency telephone number

(+44)(0)1278 72 7200 (office hours)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to 67/548/EEC or 1999/45/EC:

Health:

R66: Repeated exposure may cause skin dryness or cracking.

Physical:

EXTREMELY FLAMMABLE

Environment:

Not classified

2.2. Label elements

Warning symbol(s) :	EXTREMELY FLAMMABLE

Risk-phrase(s) :

R66: Repeated exposure may cause skin dryness or cracking.

Safety-phrase(s) :	S2: Keep out of the reach of children.
	S16: Keep away from sources of ignition - No smoking.
	S23: Do not breathe vapours/spray.
	S51: Use only in well-ventilated areas.

Extra label elements according to Aerosol Dispenser Directive 75/324/EC:	Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material.
	Without adequate ventilation formation of explosive mixtures may be possible.

Other extra label elements:

Remark: Preparations classified as harmful on the basis of an aspiration hazard need not be labelled as harmful with R65 when placed on the market in aerosol containers or in containers fitted with a sealed spray attachment. (EU-Directive 67/548 Annex VI 9.4)

2.3. Other hazards

None

SECTION 3: Composition/information on ingredients

3.1. Substances

Not applicable.

3.2. Mixtures

Hazardous ingredient	CAS-nr.	EC-nr	w/w %	symbol	R-phrases*	Notes
dimethyl ether	115-10-6	204-065-8	60-100	F+	12	A
acetone; propan-2-one; propanone	67-64-1	200-662-2	10-30	F,Xi	11-36-66-67	A
xylene	1330-20-7	215-535-7	1-10	Xn	10-20/21-38	A
butan-1-ol; n-butanol	71-36-3	200-751-6	0-1	Xn	10-22-37/38-41-67	B
1,2,4-trimethylbenzene	95-63-6	202-436-9	0-1	Xn,N	10-20-36/37/38-51/53	A
mesitylene1,3,5-trimethylbenzene	108-67-8	203-604-4	0-1	Xi,N	10-37-51/53	A
ethylbenzene	100-41-4	202-849-4	0.5-2.5	F,Xn	11-20	A
Naphtha (petroleum), hydrotreated light	64742-49-0	265-151-9	0.5-2.5	Xn	65	B,P
Naphtha (petroleum), hydrodesulfurized heavy	64742-82-1	265-185-4	0.5-2.5	Xn	65	B,P
Solvent naphtha (petroleum), light arom. (benzene<0.1%)	64742-95-6	265-199-0	0.5-2.5	Xn	65	B,P

Explanation notes

A : substance with Community workplace exposure limit

B : substance with national established workplace exposure limit

P : not classified as carcinogen, less than 0.1% w/w benzene (Einecs-nr. 200-753-7)

Hazardous ingredient	Registration number	CAS-nr.	EC-nr	w/w %	Hazard Class and Category	Hazard statement	Notes
dimethyl ether	01-2119472128-37	115-10-6	204-065-8	60-100	Flam. Gas 1, Press. Gas	H220,H280	A
acetone; propan-2-one; propanone	01-2119471330-49	67-64-1	200-662-2	10-30	Flam. Liq. 2, Eye Irrit. 2, STOT SE 3	H225,H319,H336	A
xylene		1330-20-7	215-535-7	1-10	Flam. Liq. 3, Acute Tox. 4, Acute Tox. 4, Skin Irrit. 2	H226,H332,H312,H315	A
mesitylene1,3,5-trimethylbenzene		108-67-8	203-604-4	0-1	Flam. Liq. 3, STOT SE 3, Aquatic Chronic 2	H226,H335,H411	A
butan-1-ol; n-butanol	01-2119484630-38	71-36-3	200-751-6	0-1	Flam. Liq. 3, Acute Tox. 4, STOT SE 3, Skin Irrit. 2, Eye Dam. 1, STOT SE 3	H226,H302,H335,H315,H318,H336	B
1,2,4-trimethylbenzene	ABNA	95-63-6	202-436-9	0-1	Flam. Liq. 3, Acute Tox. 4, Eye Irrit. 2, STOT SE 3, Skin Irrit. 2, Aquatic Chronic 2	H226,H332,H319,H335,H315,H411	A
ethylbenzene		100-41-4	202-849-4	0.5-2.5	Flam. Liq. 2, Acute Tox. 4	H225,H332	A

Explanation notes

A : substance with Community workplace exposure limit

B : substance with national established workplace exposure limit

(* Explanation phrases : see chapter 16)

SECTION 4: First aid measures

4.1. Description of first aid measures

Contact with eyes :	If substance has got into eyes, immediately wash out with plenty of water
	Seek medical attention if irritation persists

Contact with skin :	Wash with water and soap.
	Seek medical attention if irritation persists

Inhalation :	Fresh air, keep warm and at rest.
	Seek medical attention if ill effects occur

Ingestion :

If swallowed do not induce vomiting because of risk of aspiration into the lungs. If aspiration is suspected obtain immediate medical attention

4.2. Most important symptoms and effects, both acute and delayed

Inhalation :

Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness

Ingestion :	After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia.
	Symptoms : sore throat, abdominal pain, nausea, vomiting

Skin contact :	May cause irritation.
	Symptoms : redness and pain

Eye contact :	May cause irritation.
	Symptoms : redness and pain

4.3. Indication of any immediate medical attention and special treatment needed

General Advice :	If you feel unwell, seek medical advice (show the label where possible
	If symptoms persist always call a doctor

SECTION 5: Firefighting measures

5.1. Extinguishing media

foam, carbon dioxide or dry agent

5.2. Special hazards arising from the substance or mixture

Aerosols may explode if heated above 50°C

Forms hazardous decomposition products

CO,CO2

5.3. Advice for firefighters

Keep container(s) exposed to fire cool, by spraying with water

In case of fire, do not breathe fumes

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Shut off all ignition sources

Ensure adequate ventilation

Wear suitable protective clothing and gloves.

6.2. Environmental precautions

Do not allow to enter public sewers and watercourses

If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities

6.3. Methods and material for containment and cleaning up

Absorb spillage in suitable inert material

6.4. Reference to other sections

For further information see section 8

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Keep away from heat and sources of ignition

Take precautionary measures against static discharges

Equipment should be earthed

Use explosion-proof electrical/ventilating/lighting/.../equipment.

Use only non-sparking tools.

Do not breathe aerosols or vapours.

Ensure adequate ventilation

Avoid contact with skin and eyes.

Wash thoroughly after use

Wear protective gloves/protective clothing/eye protection/face protection.

7.2. Conditions for safe storage, including any incompatibilities

Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C.

Keep out of reach of children.

7.3. Specific end use(s)

Anti Corrosion Products

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits :

Hazardous ingredient	CAS-nr.	method
EU established exposure limits:
ethylbenzene	100-41-4	TWA	100 ppm
		STEL	200 ppm
mesitylene1,3,5-trimethylbenzene	108-67-8	TWA	20 ppm
dimethyl ether	115-10-6	TWA	1000 ppm
xylene	1330-20-7	TWA	50 ppm
		STEL	100 ppm
acetone; propan-2-one; propanone	67-64-1	TWA	500 ppm
1,2,4-trimethylbenzene	95-63-6	TWA	20 ppm
National established exposure limits, United Kingdom
ethylbenzene	100-41-4	TWA	100 ppm
		STEL	125 ppm
dimethyl ether	115-10-6	TWA	400 ppm
		STEL	500 ppm
xylene	1330-20-7	TWA	50 ppm
		STEL	100 ppm
acetone; propan-2-one; propanone	67-64-1	TWA	500 ppm
		STEL	1500 ppm

8.2. Exposure controls

Control procedures :	Ensure adequate ventilation
	Keep away from heat and sources of ignition
	Take precautionary measures against static discharges

Personal protection :	Take precautions to avoid contact with skin and eyes when handling the product.
	Ensure adequate ventilation

inhalation :

In case of insufficient ventilation, wear suitable respiratory equipment.

Air purifying respirator equiped with organic gas/vapor cartridge (type A)

hands and skin :

Wear suitable protective gloves

eyes :

Wear safety eyewear according to EN 166.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

(for aerosols data for the product without propellant)

Appearance : physical state :

DME propelled liquid.

colour :

Grey.

odour :

Characteristic odor.

pH :	Not applicable.

Boiling point/range :

Not available.

Flash point :

< 0 °C

Evaporation rate :

Not available.

Explosion limits : upper limit :

Not available.

lower limit :

Not available.

Vapour pressure :

Not available.

Relative density :

0.905 g/cm3 (@ 20°C).

Solubility in water :

Insoluble in water

Auto-ignition :

> 200 °C

Viscosity :

Not available.

9.2. Other information

VOC = volatile organic compounds

625 g/l

SECTION 10: Stability and reactivity

10.1. Reactivity

No hazardous reactions known if used for its intended purpose

10.2. Chemical stability

Stable

10.3. Possibility of hazardous reactions

No hazardous reactions known if used for its intended purpose

10.4. Conditions to avoid

Avoid overheating

10.5. Incompatible materials

Strong oxidising agent

10.6. Hazardous decomposition products

CO,CO2

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Inhalation :

Inhalation of solvent vapours may give rise to nausea, headaches and dizziness

Ingestion :

After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia.

Skin contact :	Prolonged skin contact will result in defatting of the skin, leading to irritation, and in some cases, dermatitis
	Repeated exposure may cause skin dryness or cracking.

Eye contact :

May cause irritation.

Toxicological data :

Hazardous ingredient	CAS-nr.	method
Naphtha (petroleum), hydrodesulfurized heavy	64742-82-1	LD50 oral rat	> 2000 mg/kg
acetone; propan-2-one; propanone	67-64-1	LD50 oral rat	> 2000 mg/kg
		LD50 derm.rabit	> 2000 mg/kg

SECTION 12: Ecological information

12.1. Toxicity

Not classified

Ecotoxicological data:

Hazardous ingredient	CAS-nr.	method
Naphtha (petroleum), hydrodesulfurized heavy	64742-82-1	IC50 algae	1 - 10 mg/l
		LC50 fish	10 - 100 mg/l
		EC50 daphnia	10 - 100 mg/l
acetone; propan-2-one; propanone	67-64-1	IC50 algae	> 100 mg/l
		LC50 fish	> 100 mg/l
		EC50 daphnia	> 100 mg/l

12.2. Persistence and degradability

No experimental data available

12.3. Bioaccumulative potential

No experimental data available

12.4. Mobility in soil

Insoluble in water

12.5. Results of PBT and vPvB assessment

No information available

12.6. Endocrine disrupting properties

No experimental data available

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product :	This material and its container must be disposed of in a safe way.
	Do not discharge into drains or the environment, dispose to an authorised waste collection point.

Contaminated packaging :

Disposal should be in accordance with local, state or national legislation

SECTION 14: Transport information

14.1. UN number

UN-number :

1950

14.2. UN proper shipping name

Proper shipping name:

AEROSOLS

14.3. Transport hazard class(es)

Class:

2.1

ADR/RID - Classification code:

14.4. Packing group

Packing group:

Not applicable.

14.5. Environmental hazards

ADR/RID - Environmentally hazardous:

IMDG - Marine pollutant:

IATA/ICAO - Environmentally hazardous:

14.6. Special precautions for user

ADR/RID - Tunnelcode:

(D)

IMDG - Ems:

F-D, S-U

IATA/ICAO - PAX:

203

IATA/ICAO - CAO

203

14.7. Maritime transport in bulk according to IMO instruments

Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

The Safety Data Sheet is compiled according to the current European requirements.

Dir. 2013/10/EU, 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC.

EU-directive 99/45/EC

Regulation (EC) No 1272/2008 (CLP)

Regulation (EC) No 1907/2006 (REACH)

15.2. Chemical safety assessment

No information available

SECTION 16: Other information

*Explanation hazard statements:	H220 : Extremely flammable gas.
	H225 : Highly flammable liquid and vapour.
	H226 : Flammable liquid and vapour.
	H280 : Contains gas under pressure; may explode if heated.
	H302 : Harmful if swallowed.
	H312 : Harmful in contact with skin.
	H315 : Causes skin irritation.
	H318 : Causes serious eye damage.
	H319 : Causes serious eye irritation.
	H332 : Harmful if inhaled.
	H335 : May cause respiratory irritation.
	H336 : May cause drowsiness or dizziness.
	H411 : Toxic to aquatic life with long lasting effects.

REVISIONS IN CHAPTRE :	Classification according to 67/548/EEC or 1999/45/EC:
	2.2. Label elements

This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.