Safety Data Sheet

Regulation EC No 1907/2006 Art.31

Productname :	Acrylic Paint	Creationdate :	28.08.15 Version : 2.2
Ref.Nr.:	BDS000794_3_20150828 (EN)	Replaces:	BDS000794_20150528

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Acrylic Paint

all solid colours

Aerosol

1.2. Relevant identified uses of the substance or mixture and uses advised against

Paints

1.3. Details of the supplier of the safety data sheet

CRC Industries UK Ltd.

Wylds Road

Castlefield Industrial Estate

TA6 4DD Bridgwater Somerset

United Kingdom

Tel.: +44 1278 727200

Fax.: +44 1278 425644

E-mail : hse.uk@crcind.com

1.4. Emergency telephone number

(+44)(0)1278 72 7200 (office hours)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Physical:	Aerosols, category 1
	Extremely flammable aerosol.
	Pressurised container: May burst if heated.

Health:	Eye irritation, category 2
	Causes serious eye irritation.
	Specific target organ toxicity - single exposure, category 3
	May cause drowsiness or dizziness.

Environment:

Not classified

Classification according to 67/548/EEC or 1999/45/EC:

Health:	R36: Irritating to eyes.
	R66: Repeated exposure may cause skin dryness or cracking.
	R67: Vapours may cause drowsiness and dizziness.

Physical:

EXTREMELY FLAMMABLE

Environment:

Not classified

2.2. Label elements

Labelling according to Regulation (EC) No 1272/2008

Product identifier:	Contains:
	acetone; propan-2-one; propanone
	n-butyl acetate

Hazard pictogram(s):

Signal word:

Danger

Hazard statement(s):	H222 : Extremely flammable aerosol.
	H229 : Pressurised container: May burst if heated.
	H319 : Causes serious eye irritation.
	H336 : May cause drowsiness or dizziness.

Precautionary statement(s):	P101 : If medical advice is needed, have product container or label at hand.
	P102 : Keep out of reach of children.

	P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
	P211 : Do not spray on an open flame or other ignition source.
	P251 : Do not pierce or burn, even after use.
	P261 : Avoid breathing dust/fume/gas/mist/vapours/spray.

P410/412 : Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.

P501-2 : Dispose of contents/container to an authorised waste collection point.

Supplemental Hazard information:

Repeated exposure may cause skin dryness or cracking.

2.3. Other hazards

None

SECTION 3: Composition/information on ingredients

3.1. Substances

Not applicable.

3.2. Mixtures

Hazardous ingredient	CAS-nr.	EC-nr	w/w %	symbol	R-phrases*	Notes
acetone; propan-2-one; propanone	67-64-1	200-662-2	25-50	F,Xi	11-36-66-67	A
n-butyl acetate	123-86-4	204-658-1	12.5-20		10-66-67
propane	74-98-6	200-827-9	12.5-20	F+	12	B
2-methoxy-1-methylethyl acetate	108-65-6	203-603-9	5-10		10	A
Cellulose nitrate	9004-70-0	-	2.5-5	-	-
isobutane	75-28-5	200-857-2	2.5-5	F+	12
butane (<= 0,1 % butadiene)	106-97-8	203-448-7	10-12.5	F+	12
Solvent naphtha (petroleum), heavy arom. (benzene<0.1%)	64742-94-5	265-198-5	0-2.5	Xn	65	B
propan-2-ol; isopropyl alcohol; isopropanol	67-63-0	200-661-7	0-2.5	F,Xi	11-36-67	B

Explanation notes

A : substance with Community workplace exposure limit

B : substance with national established workplace exposure limit

Hazardous ingredient	Registration number	CAS-nr.	EC-nr	w/w %	Hazard Class and Category	Hazard statement	Notes
acetone; propan-2-one; propanone	01-2119471330-49	67-64-1	200-662-2	25-50	Flam. Liq. 2, Eye Irrit. 2, STOT SE 3	H225,H319,H336	A
n-butyl acetate	01-2119485493-29	123-86-4	204-658-1	12.5-20	Flam. Liq. 3, STOT SE 3	H226,H336
propane	01-2119486944-21	74-98-6	200-827-9	12.5-20	Flam. Gas 1, Press. Gas	H220,H280	B
2-methoxy-1-methylethyl acetate	01-2119475791-29	108-65-6	203-603-9	5-10	Flam. Liq. 3	H226	A
isobutane	01-2119485395-27	75-28-5	200-857-2	2.5-5	Flam. Gas 1, Press. Gas	H220
butane (<= 0,1 % butadiene)	01-2119474691-32	106-97-8	203-448-7	10-12.5	Flam. Gas 1, Press. Gas	H220
Solvent naphtha (petroleum), heavy arom. (benzene<0.1%)	02-2119510128-50	64742-94-5	265-198-5	0-2.5	Asp. Tox. 1	H304	B
propan-2-ol; isopropyl alcohol; isopropanol	01-2119457558-25	67-63-0	200-661-7	0-2.5	Flam. Liq. 2, Eye Irrit. 2, STOT SE 3	H225,H319,H336	B

Explanation notes

A : substance with Community workplace exposure limit

B : substance with national established workplace exposure limit

(* Explanation phrases : see chapter 16)

SECTION 4: First aid measures

4.1. Description of first aid measures

Contact with eyes :	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
	If eye irritation persists: Get medical advice/attention.

Contact with skin :	Take off contaminated clothing and wash before reuse.
	IF ON SKIN: Wash with plenty of water.
	If skin irritation occurs: Get medical advice/attention.

Inhalation :	IF INHALED: Remove person to fresh air and keep comfortable for breathing.
	Call a POISON CENTER or doctor/physician if you feel unwell.

Ingestion :

If swallowed accidentally, do not induce vomiting and seek medical advice.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation :

Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness

Ingestion :	May cause gastrointestinal disturbances
	Symptoms : sore throat, abdominal pain, nausea, vomiting

Skin contact :	May cause irritation.
	Symptoms : redness and pain

Eye contact :	Irritating to eyes
	Symptoms : redness and pain

4.3. Indication of any immediate medical attention and special treatment needed

General Advice :	If you feel unwell, seek medical advice (show the label where possible
	If symptoms persist always call a doctor

SECTION 5: Firefighting measures

5.1. Extinguishing media

foam, carbon dioxide or dry agent

5.2. Special hazards arising from the substance or mixture

Aerosols may explode if heated above 50°C

Forms hazardous decomposition products

CO,CO2

5.3. Advice for firefighters

Keep container(s) exposed to fire cool, by spraying with water

In case of fire, do not breathe fumes

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Shut off all ignition sources

Ensure adequate ventilation

Wear suitable protective clothing and gloves.

6.2. Environmental precautions

Do not allow to enter public sewers and watercourses

If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities

6.3. Methods and material for containment and cleaning up

Absorb spillage in suitable inert material

Place in appropriate container

6.4. Reference to other sections

For further information see section 8

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Keep away from heat and sources of ignition

Take precautionary measures against static discharges

Equipment should be earthed

Use explosion-proof electrical/ventilating/lighting/.../equipment.

Use only non-sparking tools.

Do not breathe aerosols or vapours.

Ensure adequate ventilation

Avoid contact with skin and eyes.

Wash thoroughly after use

Wear protective gloves/protective clothing/eye protection/face protection.

Eyewash bottles should be available

7.2. Conditions for safe storage, including any incompatibilities

Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C.

Keep out of reach of children.

7.3. Specific end use(s)

Paints

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits :

Hazardous ingredient	CAS-nr.	method
EU established exposure limits:
2-methoxy-1-methylethyl acetate	108-65-6	TWA	50 ppm
		STEL	100 ppm
propan-2-ol; isopropyl alcohol; isopropanol	67-63-0	TWA	400 ppm
		STEL	500 ppm
acetone; propan-2-one; propanone	67-64-1	TWA	500 ppm
National established exposure limits, United Kingdom
butane (<= 0,1 % butadiene)	106-97-8	TWA	600 ppm
		STEL	750 ppm
n-butyl acetate	123-86-4	TWA	150 ppm
		STEL	200 ppm
propan-2-ol; isopropyl alcohol; isopropanol	67-63-0	TWA	400 ppm
		STEL	500 ppm
acetone; propan-2-one; propanone	67-64-1	TWA	500 ppm
		STEL	1500 ppm

8.2. Exposure controls

Control procedures :	Ensure adequate ventilation
	Keep away from heat and sources of ignition
	Take precautionary measures against static discharges

Personal protection :	Take precautions to avoid contact with skin and eyes when handling the product.
	Ensure adequate ventilation

inhalation :

In case of insufficient ventilation, wear suitable respiratory equipment.

recommended respiratory protection:

(filter AXP2)

hands and skin :

Wear suitable protective gloves

Recommended gloves:

(butyl rubber)

eyes :

Wear safety eyewear according to EN 166.

Environmental protection:	Avoid release to the environment.
	Collect spillage.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

(for aerosols data for the product without propellant)

Appearance : physical state :

Liquid under pressure.

colour :

See color cap.

odour :

Characteristic odor.

pH :	Not applicable.

Boiling point/range :

Not available.

Flash point :

< 0 °C

Evaporation rate :

Not available.

Explosion limits : upper limit :

13 %

lower limit :

1.2 %

Vapour pressure :

830 kPa (@ 20°C).

Relative density :

0.8 g/cm3 (@ 20°C).

Solubility in water :

Not available.

Auto-ignition :

315 °C

Viscosity :

Not applicable.

9.2. Other information

VOC = volatile organic compounds

726 g/l

SECTION 10: Stability and reactivity

10.1. Reactivity

No hazardous reactions known if used for its intended purpose

10.2. Chemical stability

Stable

10.3. Possibility of hazardous reactions

No hazardous reactions known if used for its intended purpose

10.4. Conditions to avoid

Avoid overheating

10.5. Incompatible materials

Strong oxidising agent

10.6. Hazardous decomposition products

CO,CO2

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on likely routes of exposure:

Inhalation :

Inhalation of solvent vapours may give rise to nausea, headaches and dizziness

Ingestion :

May cause gastrointestinal disturbances

Skin contact :

May cause irritation.

Eye contact :

Irritating to eyes

Toxicological data :

Hazardous ingredient	CAS-nr.	method
2-methoxy-1-methylethyl acetate	108-65-6	LD50 oral rat	> 5000 mg/kg
		LD50 derm.rabit	> 5000 mg/kg
n-butyl acetate	123-86-4	LD50 oral rat	> 2000 mg/kg
		LC50 inhal.rat	> 20 mg/l
Solvent naphtha (petroleum), heavy arom. (benzene<0.1%)	64742-94-5	LD50 oral rat	> 2000 mg/kg
		LD50 derm.rabit	> 2000 mg/kg
propan-2-ol; isopropyl alcohol; isopropanol	67-63-0	LD50 oral rat	> 5000 mg/kg
		LC50 inhal.rat	> 20 mg/l
		LD50 derm.rabit	> 5000 mg/kg
acetone; propan-2-one; propanone	67-64-1	LD50 oral rat	> 5000 mg/kg
		LC50 inhal.rat	> 20 mg/l
		LD50 derm.rabit	> 2000 mg/kg

SECTION 12: Ecological information

12.1. Toxicity

Not classified

Ecotoxicological data:

Hazardous ingredient	CAS-nr.	method
2-methoxy-1-methylethyl acetate	108-65-6	LC50 fish	> 100 mg/l
		EC50 daphnia	> 400 mg/l
n-butyl acetate	123-86-4	IC50 algae	647 mg/l
		LC50 fish	18 mg/l
		EC50 daphnia	44 mg/l
Solvent naphtha (petroleum), heavy arom. (benzene<0.1%)	64742-94-5	IC50 algae	1-10 mg/l
		LC50 fish	1-10 mg/l
		EC50 daphnia	1-10 mg/l
propan-2-ol; isopropyl alcohol; isopropanol	67-63-0	IC50 algae	> 1000 mg/l
		LC50 fish	> 1000 mg/l
		EC50 daphnia	> 1000 mg/l
acetone; propan-2-one; propanone	67-64-1	IC50 algae	> 100 mg/l
		LC50 fish	> 100 mg/l
		EC50 daphnia	> 100 mg/l

12.2. Persistence and degradability

No experimental data available

12.3. Bioaccumulative potential

No experimental data available

12.4. Mobility in soil

No experimental data available

12.5. Results of PBT and vPvB assessment

No information available

12.6. Endocrine disrupting properties

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product :	This material and its container must be disposed of in a safe way.
	Do not discharge into drains or the environment, dispose to an authorised waste collection point.

National regulations :

Disposal should be in accordance with local, state or national legislation

SECTION 14: Transport information

14.1. UN number

UN-number :

1950

14.2. UN proper shipping name

Proper shipping name:

AEROSOLS

14.3. Transport hazard class(es)

Class:

2.1

ADR/RID - Classification code:

14.4. Packing group

Packing group:

Not applicable.

14.5. Environmental hazards

ADR/RID - Environmentally hazardous:

IMDG - Marine pollutant:

IATA/ICAO - Environmentally hazardous:

14.6. Special precautions for user

ADR/RID - Tunnelcode:

(D)

IMDG - Ems:

F-D, S-U

IATA/ICAO - PAX:

203

IATA/ICAO - CAO

203

14.7. Maritime transport in bulk according to IMO instruments

Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

The Safety Data Sheet is compiled according to the current European requirements.

Dir. 2013/10/EU, 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC.

Regulation (EC) No 1272/2008 (CLP)

EU-directive 99/45/EC

Regulation (EC) No 1907/2006 (REACH)

15.2. Chemical safety assessment

No information available

SECTION 16: Other information

*Explanation hazard statements:	H220 : Extremely flammable gas.
	H225 : Highly flammable liquid and vapour.
	H226 : Flammable liquid and vapour.
	H280 : Contains gas under pressure; may explode if heated.
	H304 : May be fatal if swallowed and enters airways.
	H319 : Causes serious eye irritation.
	H336 : May cause drowsiness or dizziness.

This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.