| SECTION 1: Identification of the substance/mixture and of the company/undertaking |
| 1.2. Relevant identified uses of the substance or mixture and uses advised against |
| 1.3. Details of the supplier of the safety data sheet |
| CRC Industries Europe bvba |
| Touwslagerstraat 1 |
| 9240 Zele |
| Belgium |
| Tel.: +32(0)52/45.60.11 |
| Fax.: +32(0)52/45.00.34 |
| E-mail : hse@crcind.com |
| Subsidiaries | | Tel | Fax |
| CRC Industries Finland Oy | Laurinkatu 57 A 23 B, 08100 Lohja | +358/(19)32.921 | |
| CRC Industries France | 6, avenue du marais, C.S. 90028, 95102 Argenteuil Cedex | 01.34.11.20.00 | 01.34.11.09.96 |
| CRC Industries Deutschland GmbH | Südring 9, D-76473 Iffezheim | (07229) 303 0 | (07229)30 32 66 |
| CRC INDUSTRIES IBERIA S.L.U. | GREMIO DEL CUERO-PARC.96, POLIGONO INDUSTR. DE HONTORIA, 40195 SEGOVIA | 0034/921.427.546 | 0034/921.436.270 |
| CRC Industries Sweden | Laxfiskevägen 16, 433 38 Partille | 0046/31 706 84 80 | 0046/31 27 39 91 |
| 1.4. Emergency telephone number |
| CRC Industries Europe, Belgium: Tel.: +32(0)52/45.60.11 (office hours: 9-17h pm CET) |
| SECTION 2: Hazards identification |
| 2.1. Classification of the substance or mixture |
| Classification according to Regulation (EC) No 1272/2008 |
| Physical: |
Flammable liquid, category 3 |
| | Flammable liquid and vapour. |
| Health: |
Eye irritation, category 2 |
| | Causes serious eye irritation. |
| | Specific Target Organ Toxicity - Repeated Exposure Category 1 |
| | Causes damage to organs through prolonged or repeated exposure. |
| Environment: |
Hazardous to the aquatic environment, chronic category 2 |
| | Toxic to aquatic life with long lasting effects. |
| Labelling according to Regulation (EC) No 1272/2008 |
| Product identifier: |
Contains: |
| | Stoddard solvent; Low boiling point naphtha - unspecified |
| Hazard statement(s): |
H226 : Flammable liquid and vapour. |
| | H319 : Causes serious eye irritation. |
| | H372 : Causes damage to organs through prolonged or repeated exposure. |
| | H411 : Toxic to aquatic life with long lasting effects. |
| Precautionary statement(s): |
P102 : Keep out of reach of children. |
|
P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. |
| | P260 : Do not breathe dust/fume/gas/mist/vapours/spray. |
| | P280 : Wear protective gloves/protective clothing/eye protection/face protection. |
|
P314 : Get medical advice/attention if you feel unwell. |
|
P403/235 : Store in a well-ventilated place. Keep cool. |
|
P501-2 : Dispose of contents/container to an authorised waste collection point. |
| SECTION 3: Composition/information on ingredients |
| Hazardous ingredient | Registration number | CAS-nr. | EC-nr | w/w % | Hazard Class and Category | Hazard statement | Notes |
| Stoddard solvent; Low boiling point naphtha - unspecified | | 8052-41-3 | 232-489-3 | 25-50 | Flam. Liq. 3, Eye Irrit. 2, STOT RE 1, Asp. Tox. 1, Aquatic Chronic 2 | H226,H319,H372,H304,H411 | B,P |
| Distillates (petroleum), hydrotreated light; Kerosine - unspecified | | 64742-47-8 | 265-149-8 | 5-10 | Flam. Liq. 3, STOT SE 3, Asp. Tox. 1 | H226,H336,H304 | B,P |
| Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, < 2% aromatics | 01-2119463258-33 | - | 919-857-5 | 5-10 | Flam. Liq. 3, Asp. Tox. 1, STOT SE 3 | H226,H304,H336 | B |
| Explanation notes |
B : substance with national established workplace exposure limit |
P : not classified as carcinogen, less than 0.1% w/w benzene (Einecs-nr. 200-753-7) |
| (* Explanation phrases : see chapter 16) |
| SECTION 4: First aid measures |
| 4.1. Description of first aid measures |
| Contact with eyes : |
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Contact with skin : |
Wash with water and soap. |
| | Seek medical attention if irritation persists |
| Inhalation : |
Fresh air, keep warm and at rest. |
| | Seek medical attention if ill effects occur |
| Ingestion : |
If swallowed do not induce vomiting |
| | Seek medical advice |
| 4.2. Most important symptoms and effects, both acute and delayed |
| Inhalation : |
Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness |
| Ingestion : |
May cause gastrointestinal disturbances |
| | Symptoms : sore throat, abdominal pain, nausea, vomiting |
| Skin contact : |
Mildly irritating to skin |
| | Symptoms : redness and pain |
| Eye contact : |
Irritating to eyes |
| | Symptoms : redness and pain, impaired vision |
| 4.3. Indication of any immediate medical attention and special treatment needed |
| General Advice : |
If you feel unwell, seek medical advice (show the label where possible |
| | If symptoms persist always call a doctor |
| SECTION 5: Firefighting measures |
| foam, carbon dioxide or dry agent |
| 5.2. Special hazards arising from the substance or mixture |
| May form explosive vapour/air mixtures |
| Forms hazardous decomposition products |
| 5.3. Advice for firefighters |
| Keep container(s) exposed to fire cool, by spraying with water |
| In case of fire, do not breathe fumes |
| SECTION 6: Accidental release measures |
| 6.1. Personal precautions, protective equipment and emergency procedures |
| Shut off all ignition sources |
| Ensure adequate ventilation |
| Wear suitable protective clothing including eye/face protection. |
| 6.2. Environmental precautions |
| Do not allow to enter public sewers and watercourses |
| 6.3. Methods and material for containment and cleaning up |
| Absorb spillage in suitable inert material |
| 6.4. Reference to other sections |
| For further information see section 8 |
| SECTION 7: Handling and storage |
| 7.1. Precautions for safe handling |
| Keep away from heat and sources of ignition |
| Take precautionary measures against static discharges |
| Equipment should be earthed |
| Use explosion-proof electrical/ventilating/lighting/.../equipment. |
| Use only non-sparking tools. |
| Do not breathe aerosols or vapours. |
| Ensure adequate ventilation |
| Avoid contact with skin and eyes. |
| Wash thoroughly after use |
| Wear protective gloves/protective clothing/eye protection/face protection. |
| Eyewash bottles should be available |
| 7.2. Conditions for safe storage, including any incompatibilities |
| Keep container tightly closed, in a cool, well ventilated place. |
| Keep out of reach of children. |
| SECTION 8: Exposure controls/personal protection |
| Control procedures : |
Ensure adequate ventilation |
|
Keep away from heat and sources of ignition |
|
Take precautionary measures against static discharges |
| Personal protection : |
Take precautions to avoid contact with skin and eyes when handling the product. |
|
Ensure adequate ventilation |
| inhalation : |
In case of insufficient ventilation, wear suitable respiratory equipment. |
| recommended respiratory protection: |
Air purifying respirator equiped with organic gas/vapor cartridge (type A) |
| hands and skin : |
Wear suitable protective gloves |
| Recommended gloves: |
Nitrile |
| eyes : |
Wear safety eyewear according to EN 166. |
| SECTION 9: Physical and chemical properties |
| 9.1. Information on basic physical and chemical properties |
| Appearance : physical state : |
Liquid. |
| odour : |
Characteristic odor. |
| Boiling point/range : |
Not available. |
| Evaporation rate : |
Not applicable. |
| Explosion limits : upper limit : |
Not available. |
| lower limit : |
Not available. |
| Vapour pressure : |
Not available. |
| Relative density : |
0.874 g/cm3 (@ 20°C). |
| Solubility in water : |
Insoluble in water |
| Viscosity : |
490 mPa.s (@ 20°C). |
| VOC = volatile organic compounds |
460 g/l |
| SECTION 10: Stability and reactivity |
| No hazardous reactions known if used for its intended purpose |
| 10.3. Possibility of hazardous reactions |
| No hazardous reactions known if used for its intended purpose |
| 10.4. Conditions to avoid |
| 10.5. Incompatible materials |
| 10.6. Hazardous decomposition products |
| SECTION 11: Toxicological information |
| 11.1. Information on toxicological effects |
| acute toxicity: |
based on available data the classification criteria are not met |
| skin corrosion/irritation: |
based on available data the classification criteria are not met |
| serious eye damage/irritation: |
Causes serious eye irritation. |
| respiratory or skin sensitisation: |
based on available data the classification criteria are not met |
| germ cell mutagenicity: |
based on available data the classification criteria are not met |
| carcinogenicity: |
based on available data the classification criteria are not met |
| toxicity for reproduction: |
based on available data the classification criteria are not met |
| STOT-single exposure: |
based on available data the classification criteria are not met |
| STOT repeated exposure: |
Causes damage to organs through prolonged or repeated exposure. |
| aspiration hazard: |
based on available data the classification criteria are not met |
| Information on likely routes of exposure: |
| Inhalation : |
Excessive inhalation of vapours may give rise to irritation and affect the nervous system |
| Skin contact : |
Prolonged skin contact will result in defatting of the skin, leading to irritation, and in some cases, dermatitis |
| Eye contact : |
Irritating to eyes |
| Hazardous ingredient | CAS-nr. | method | | |
| Distillates (petroleum), hydrotreated light; Kerosine - unspecified | 64742-47-8 | LD50 oral rat | > 2000 mg/kg |
| | LD50 derm.rabit | > 2000 mg/kg |
| SECTION 12: Ecological information |
| Hazardous to the aquatic environment, chronic category 2 |
| Toxic to aquatic life with long lasting effects. |
| 12.2. Persistence and degradability |
| No experimental data available |
| 12.3. Bioaccumulative potential |
| No experimental data available |
| 12.5. Results of PBT and vPvB assessment |
| 12.6. Endocrine disrupting properties |
| No experimental data available |
| SECTION 13: Disposal considerations |
| 13.1. Waste treatment methods |
| Product : |
This material and its container must be disposed of in a safe way. |
|
Do not discharge into drains or the environment, dispose to an authorised waste collection point. |
| National regulations : |
Disposal should be in accordance with local, state or national legislation |
| SECTION 14: Transport information |
| 14.2. UN proper shipping name |
| Proper shipping name: |
PETROLEUM PRODUCTS, N.O.S. (solvent naphtha) |
| 14.3. Transport hazard class(es) |
| ADR/RID - Classification code: |
F1 |
| 14.5. Environmental hazards |
| ADR/RID - Environmentally hazardous: |
Yes |
| IMDG - Marine pollutant: |
Marine pollutant |
| IATA/ICAO - Environmentally hazardous: |
Yes |
| 14.6. Special precautions for user |
| ADR/RID - Tunnelcode: |
(D/E) |
| 14.7. Maritime transport in bulk according to IMO instruments |
| SECTION 15: Regulatory information |
| 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture |
| The Safety Data Sheet is compiled according to the current European requirements. |
| Regulation (EC) No 1907/2006 (REACH)
|
| Regulation (EC) No 1272/2008 (CLP)
|
|
| 15.2. Chemical safety assessment |
| SECTION 16: Other information |
| *Explanation hazard statements: |
H226 : Flammable liquid and vapour. |
| | H304 : May be fatal if swallowed and enters airways. |
| | H319 : Causes serious eye irritation. |
| | H336 : May cause drowsiness or dizziness. |
| | H372 : Causes damage to organs through prolonged or repeated exposure. |
| | H411 : Toxic to aquatic life with long lasting effects. |
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation. The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties. Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC. |
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