Graphite Lock Lube_Aerosol_English
Safety Data Sheet Regulation EC No 1907/2006 Art.31
Productname : Graphite Lock Lube Creationdate : 23.01.15 Version : 2.0
Ref.Nr.: BDS001121_3_20150123 (EN) Replaces: BDS001121_20120117
 
SECTION 1: Identification of the substance/mixture and of the company/undertaking
 
1.1. Product identifier
 
 
Graphite Lock Lube
Aerosol
 
1.2. Relevant identified uses of the substance or mixture and uses advised against
 
Lubricants
 
1.3. Details of the supplier of the safety data sheet
 
 
CRC Industries UK Ltd.
Wylds Road
Castlefield Industrial Estate
TA6 4DD Bridgwater Somerset
United Kingdom
Tel.: +44 1278 727200
Fax.: +44 1278 425644
E-mail : hse.uk@crcind.com
 
1.4. Emergency telephone number
 
 
(+44)(0)1278 72 7200 (office hours)
 
SECTION 2: Hazards identification
 
2.1. Classification of the substance or mixture
 
Classification according to Regulation (EC) No 1272/2008
 
Physical: Aerosols, category 1
 Extremely flammable aerosol.
 Pressurised container: May burst if heated.
Health: Eye irritation, category 2
 Causes serious eye irritation.
Environment: Not classified
 
Classification according to 67/548/EEC or 1999/45/EC:
 
EXTREMELY FLAMMABLE
Health: R67: Vapours may cause drowsiness and dizziness.
Physical: EXTREMELY FLAMMABLE
Environment: Not classified
 
2.2. Label elements
 
Labelling according to Regulation (EC) No 1272/2008
 
Hazard pictogram(s):    
Signal word: Danger
Aerosols dispensers with a maximum capacity of less than 50 ml are not subject to the provisions of the Aerosol Dispenser Directive (75/324/EEC, art 1)
 The label information is reduced in accordance with section 1.5.2 of Annex I (art 29 CLP-regulation)
 
2.3. Other hazards
 
None
 
SECTION 3: Composition/information on ingredients
 
3.1. Substances
 
Not applicable.
 
3.2. Mixtures
 
 
Hazardous ingredientCAS-nr.EC-nrw/w %symbolR-phrases*Notes
ethanol; ethyl alcohol64-17-5200-578-640-60F11B
propan-2-ol; isopropyl alcohol; isopropanol67-63-0200-661-7<20F,Xi11-36-67B
Graphite7782-42-5<10--G
2-methylpropan-2-ol; tert-butyl alcohol75-65-0200-889-7<1F,Xn11-20-36/37B
Explanation notes
B : substance with national established workplace exposure limit
G : exempted from the obligation to register in accordance with art.2(7)of REACH Regulation No 1907/2006
 
Hazardous ingredientRegistration numberCAS-nr.EC-nrw/w %Hazard Class and CategoryHazard statementNotes
ethanol; ethyl alcohol01-2119457610-4364-17-5200-578-640-60Flam. Liq. 2H225B
propan-2-ol; isopropyl alcohol; isopropanol01-2119457558-2567-63-0200-661-7<20Flam. Liq. 2, Eye Irrit. 2, STOT SE 3H225,H319,H336B
Graphite7782-42-5<10--G
2-methylpropan-2-ol; tert-butyl alcohol75-65-0200-889-7<1Flam. Liq. 2, Acute Tox. 4, Eye Irrit. 2, STOT SE 3H225,H332,H319,H335B
Explanation notes
B : substance with national established workplace exposure limit
G : exempted from the obligation to register in accordance with art.2(7)of REACH Regulation No 1907/2006
(* Explanation phrases : see chapter 16)
 
SECTION 4: First aid measures
 
4.1. Description of first aid measures
 
Contact with eyes : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 If eye irritation persists: Get medical advice/attention.
Contact with skin : Take off contaminated clothing and wash before reuse.
 IF ON SKIN: Wash with plenty of water.
 If skin irritation occurs: Get medical advice/attention.
Inhalation : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
 Call a POISON CENTER or doctor/physician if you feel unwell.
Ingestion : If swallowed accidentally, do not induce vomiting and seek medical advice.
 
4.2. Most important symptoms and effects, both acute and delayed
 
Inhalation : Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Ingestion : May cause gastrointestinal disturbances
 Symptoms : sore throat, abdominal pain, nausea, vomiting
Skin contact : May cause irritation.
 Symptoms : redness and pain
Eye contact : Irritating to eyes
 Symptoms : redness and pain
 
4.3. Indication of any immediate medical attention and special treatment needed
 
General Advice : If you feel unwell, seek medical advice (show the label where possible
 If symptoms persist always call a doctor
 
SECTION 5: Firefighting measures
 
5.1. Extinguishing media
 
foam, carbon dioxide or dry agent
 
5.2. Special hazards arising from the substance or mixture
 
Aerosols may explode if heated above 50°C
Forms hazardous decomposition products
CO,CO2
 
5.3. Advice for firefighters
 
Keep container(s) exposed to fire cool, by spraying with water
In case of fire, do not breathe fumes
 
SECTION 6: Accidental release measures
 
6.1. Personal precautions, protective equipment and emergency procedures
 
Shut off all ignition sources
Ensure adequate ventilation
Wear suitable protective clothing and gloves.
 
6.2. Environmental precautions
 
Do not allow to enter public sewers and watercourses
If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities
 
6.3. Methods and material for containment and cleaning up
 
Absorb spillage in suitable inert material
Place in appropriate container
 
6.4. Reference to other sections
 
For further information see section 8
 
SECTION 7: Handling and storage
 
7.1. Precautions for safe handling
 
Keep away from heat and sources of ignition
Take precautionary measures against static discharges
Equipment should be earthed
Use explosion-proof electrical/ventilating/lighting/.../equipment.
Use only non-sparking tools.
Do not breathe aerosols or vapours.
Ensure adequate ventilation
Avoid contact with skin and eyes.
Wash thoroughly after use
Wear protective gloves/protective clothing/eye protection/face protection.
Eyewash bottles should be available
 
7.2. Conditions for safe storage, including any incompatibilities
 
Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C.
Keep out of reach of children.
 
7.3. Specific end use(s)
 
Lubricants
 
SECTION 8: Exposure controls/personal protection
 
8.1. Control parameters
 
Exposure limits :
 
 
Hazardous ingredientCAS-nr.method
EU established exposure limits:
propan-2-ol; isopropyl alcohol; isopropanol67-63-0TWA400 ppm
STEL500 ppm
National established exposure limits, United Kingdom
ethanol; ethyl alcohol64-17-5TWA1000 ppm
 
8.2. Exposure controls
 
Control procedures : Ensure adequate ventilation
 Keep away from heat and sources of ignition
 Take precautionary measures against static discharges
Personal protection : Take precautions to avoid contact with skin and eyes when handling the product.
 Ensure adequate ventilation
inhalation : In case of insufficient ventilation, wear suitable respiratory equipment.
recommended respiratory protection: Air purifying respirator equiped with organic gas/vapor cartridge (type A or AX) in combination with an oil proof solid and liquid particulate filter
hands and skin : Wear suitable protective gloves
Recommended gloves: Nitrile
eyes : Wear safety eyewear according to EN 166.
Environmental protection: Avoid release to the environment.
 Collect spillage.
 
SECTION 9: Physical and chemical properties
 
9.1. Information on basic physical and chemical properties
 
(for aerosols data for the product without propellant)
Appearance : physical state : Propane/butane propelled liquid.
colour : Black.
odour : Characteristic odor.
pH : Not applicable.
Boiling point/range : Not available.
Flash point : < 0 °C
Evaporation rate : Not available.
Explosion limits : upper limit : Not available.
lower limit : Not available.
Vapour pressure : 400 kPa (@ 20°C).
Relative density : 0.82 g/cm3 (@ 20°C).
Solubility in water : Insoluble in water
Auto-ignition : > 200 °C
Viscosity : Not available.
 
9.2. Other information
 
SECTION 10: Stability and reactivity
 
10.1. Reactivity
 
No hazardous reactions known if used for its intended purpose
 
10.2. Chemical stability
 
Stable
 
10.3. Possibility of hazardous reactions
 
No hazardous reactions known if used for its intended purpose
 
10.4. Conditions to avoid
 
Avoid overheating
 
10.5. Incompatible materials
 
Strong oxidising agent
 
10.6. Hazardous decomposition products
 
CO,CO2
 
SECTION 11: Toxicological information
 
11.1. Information on toxicological effects
 
Information on likely routes of exposure:
 
Inhalation : Inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Ingestion : May cause gastrointestinal disturbances
Skin contact : May cause irritation.
Eye contact : Irritating to eyes
 
Toxicological data :
 
 
Hazardous ingredientCAS-nr.method
ethanol; ethyl alcohol64-17-5LD50 oral rat> 2000 mg/kg
LD50 derm.rabit> 2000 mg/kg
propan-2-ol; isopropyl alcohol; isopropanol67-63-0LD50 oral rat> 5000 mg/kg
LC50 inhal.rat> 20 mg/l
LD50 derm.rabit> 5000 mg/kg
 
SECTION 12: Ecological information
 
12.1. Toxicity
 
Not classified
 
Ecotoxicological data:
 
 
Hazardous ingredientCAS-nr.method
ethanol; ethyl alcohol64-17-5LC50 fish> 100 mg/l
propan-2-ol; isopropyl alcohol; isopropanol67-63-0IC50 algae> 1000 mg/l
LC50 fish> 1000 mg/l
EC50 daphnia> 1000 mg/l
 
12.2. Persistence and degradability
 
No experimental data available
 
12.3. Bioaccumulative potential
 
No experimental data available
 
12.4. Mobility in soil
 
Insoluble in water
 
12.5. Results of PBT and vPvB assessment
 
No information available
 
12.6. Endocrine disrupting properties
 
SECTION 13: Disposal considerations
 
13.1. Waste treatment methods
 
Product : This material and its container must be disposed of in a safe way.
 Do not discharge into drains or the environment, dispose to an authorised waste collection point.
National regulations : Disposal should be in accordance with local, state or national legislation
 
SECTION 14: Transport information
 
14.1. UN number
 
UN-number : 1950
 
14.2. UN proper shipping name
 
Proper shipping name: AEROSOLS
 
14.3. Transport hazard class(es)
 
Class: 2.1
ADR/RID - Classification code: 5F
 
14.4. Packing group
 
Packing group: Not applicable.
 
14.5. Environmental hazards
 
ADR/RID - Environmentally hazardous: No
IMDG - Marine pollutant: No
IATA/ICAO - Environmentally hazardous: No
 
14.6. Special precautions for user
 
IMDG - Ems: F-D, S-U
IATA/ICAO - PAX: 203
IATA/ICAO - CAO 203
 
14.7. Maritime transport in bulk according to IMO instruments
 
Not applicable.
 
SECTION 15: Regulatory information
 
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
 
The Safety Data Sheet is compiled according to the current European requirements.
EU-directive 99/45/EC
Regulation (EC) No 1907/2006 (REACH)
 
15.2. Chemical safety assessment
 
No information available
 
SECTION 16: Other information
 
*Explanation hazard statements: - : -
 H225 : Highly flammable liquid and vapour.
 H319 : Causes serious eye irritation.
 H332 : Harmful if inhaled.
 H335 : May cause respiratory irritation.
 H336 : May cause drowsiness or dizziness.
REVISIONS IN CHAPTRE : 2.2. Label elements
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.