MOUSSE PU COUPE FEU PISTOLABLE_Aerosol

MOUSSE PU COUPE FEU PISTOLABLE_Aerosol_English

Safety Data Sheet

Regulation EC No 1907/2006 Art.31

Productname :	MOUSSE PU COUPE FEU PISTOLABLE	Creationdate :	09.04.13 Version : 2.0
Ref.Nr.:	BDS001139_3_20130409 (EN)	Replaces:	BDS001139_20120119

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

MOUSSE PU COUPE FEU PISTOLABLE

Aerosol

1.2. Relevant identified uses of the substance or mixture and uses advised against

Sealants and Isolation

1.3. Details of the supplier of the safety data sheet

CRC Industries Europe bvba

Touwslagerstraat 1

9240 Zele

Belgium

Tel.: +32(0)52/45.60.11

Fax.: +32(0)52/45.00.34

E-mail : hse@crcind.com

Subsidiaries		Tel	Fax
CRC Industries Finland Oy	Laurinkatu 57 A 23 B, 08100 Lohja	+358/(19)32.921	+358/(19)383.676
CRC Industries France	6, avenue du marais, C.S. 90028, 95102 Argenteuil Cedex	01.34.11.20.00	01.34.11.09.96
CRC Industries Deutschland GmbH	Südring 9, D-76473 Iffezheim	(07229) 303.0	(07229)30 32 66
CRC INDUSTRIES IBERIA S.L.U.	GREMIO DEL CUERO-PARC.96, POLIGONO INDUSTR. DE HONTORIA, 40195 SEGOVIA	0034/921.427.546	0034/921.436.270
CRC Industries Sweden	Laxfiskevägen 16, 433 38 Partille	0046/31 706 84 80	0046/31 27 39 91

1.4. Emergency telephone number

CRC Industries Europe, Belgium: Tel.: +32(0)52/45.60.11 (office hours: 9-17h pm CET)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to 67/548/EEC or 1999/45/EC:

Health:	R20: Harmful by inhalation.
	R36/37/38: Irritating to eyes, respiratory system and skin.
	R40: Limited evidence of a carcinogenic effect.
	R42/43: May cause sensitization by inhalation and skin contact.
	R48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation.

Physical:

EXTREMELY FLAMMABLE

Environment:

Not classified

2.2. Label elements

Contains:

diphenylmethandiisocyanate, isomeres and homologues

Warning symbol(s) :	EXTREMELY FLAMMABLE

	Xn : HARMFUL

Risk-phrase(s) :	R20: Harmful by inhalation.
	R36/37/38: Irritating to eyes, respiratory system and skin.
	R40: Limited evidence of a carcinogenic effect.
	R42/43: May cause sensitization by inhalation and skin contact.
	R48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation.

Safety-phrase(s) :	S2: Keep out of the reach of children.
	S16: Keep away from sources of ignition - No smoking.
	S23: Do not breathe vapours/spray.
	S36/37: Wear suitable protective clothing and gloves.
	S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
	S51: Use only in well-ventilated areas.
	S60: This material and its container must be disposed of as hazardous waste.

Special labelling provisions:	Contains isocyanates. See information supplied by the manufacturer.
	Restricted to professional users.

Extra label elements according to Aerosol Dispenser Directive 75/324/EC:	Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material.
	Without adequate ventilation formation of explosive mixtures may be possible.

2.3. Other hazards

Persons already sensitised to diisocyanates may develop allergic reactions when using this product.
Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product.

SECTION 3: Composition/information on ingredients

3.1. Substances

Not applicable.

3.2. Mixtures

Hazardous ingredient	CAS-nr.	EC-nr	w/w %	symbol	R-phrases*	Notes
diphenylmethandiisocyanate, isomeres and homologues	9016-87-9	202-966-0	30-50	Xn	20-40-48/20-42/43-36/37/38
Reaction products of phosphoryl trichloride and 2-methyloxirane	1244733-77-4	911-815-4	10-20	Xn	22
dimethyl ether	115-10-6	204-065-8	5-10	F+	12	A
Castor oil	8001-79-4	232-293-8	5-10	Xi	38	G
1-Propanol, 2,2-dimethyl-, tribromo deriv.	36483-57-5	253-057-0	1-5	Xi	36
propane	74-98-6	200-827-9	1-5	F+	12	B
isobutane	75-28-5	200-857-2	1-5	F+	12

Explanation notes

A : substance with Community workplace exposure limit

B : substance with national established workplace exposure limit

G : exempted from the obligation to register in accordance with art.2(7)of REACH Regulation No 1907/2006

Hazardous ingredient	Registration number	CAS-nr.	EC-nr	w/w %	Hazard Class and Category	Hazard statement	Notes
diphenylmethandiisocyanate, isomeres and homologues		9016-87-9	202-966-0	30-50	Resp. Sens. 1, Carc. 2, STOT RE 2, Acute Tox. 4, Skin Irrit. 2, Eye Irrit. 2, Skin Sens. 1, STOT SE 3	H334,H351,H373,H332,H315,H319,H317,H335
Reaction products of phosphoryl trichloride and 2-methyloxirane		1244733-77-4	911-815-4	10-20	Acute Tox. 4	H302
dimethyl ether	01-2119472128-37	115-10-6	204-065-8	5-10	Flam. Gas 1, Press. Gas	H220,H280	A
Castor oil		8001-79-4	232-293-8	5-10	Skin Irrit. 2	H315	G
1-Propanol, 2,2-dimethyl-, tribromo deriv.		36483-57-5	253-057-0	1-5	Eye Irrit. 2	H319
propane		74-98-6	200-827-9	1-5	Flam. Gas 1, Press. Gas	H220	B
isobutane		75-28-5	200-857-2	1-5	Flam. Gas 1, Press. Gas	H220

Explanation notes

A : substance with Community workplace exposure limit

B : substance with national established workplace exposure limit

G : exempted from the obligation to register in accordance with art.2(7)of REACH Regulation No 1907/2006

(* Explanation phrases : see chapter 16)

SECTION 4: First aid measures

4.1. Description of first aid measures

Contact with eyes :	If substance has got into eyes, immediately wash out with water for at least 15 minutes
	Continue flushing with water until medical help arrives
	Seek immediate medical attention

Contact with skin :	Remove contaminated clothing immediately and drench affected skin with plenty of water. Then wash with soap and water
	Seek immediate medical attention

Inhalation :	Remove patient to fresh air
	Persons who have inhaled substance may not exhibit symptoms immediately
	In case of unconsciousness place patient in stable side position.
	Apply artificial respiration only if patient is not breathing
	Seek immediate medical attention

Ingestion :

If swallowed seek medical advice immediately and show this container or label.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation :	May cause sensitization by inhalation.
	Vapours may be irritating to respiratory system and nassal passages.

Ingestion :	May cause gastrointestinal disturbances
	Symptoms : sore throat, abdominal pain, nausea, vomiting

Skin contact :	Irritating to skin
	May cause sensitisation by skin contact.
	Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product.

Eye contact :	Irritating to eyes
	Symptoms : redness and pain

4.3. Indication of any immediate medical attention and special treatment needed

General Advice :	In case of accident or if you feel unwell, seek medical advice (show the label where possible)
	If symptoms persist always call a doctor

In case of repeated exposures, regular medical examination is advised

SECTION 5: Firefighting measures

5.1. Extinguishing media

water, foam, carbon dioxide or dry agent

5.2. Special hazards arising from the substance or mixture

Aerosols may explode if heated above 50°C

Forms hazardous decomposition products

CO,CO2

5.3. Advice for firefighters

Keep container(s) exposed to fire cool, by spraying with water

In case of fire, do not breathe fumes

Substance evolves toxic fumes, wear self-contained breathing apparatus

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Shut off all ignition sources

Ensure adequate ventilation

Evacuate the area

Wear suitable protective clothing including eye/face protection and gloves.

6.2. Environmental precautions

Do not allow to enter public sewers and watercourses

If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities

6.3. Methods and material for containment and cleaning up

Absorb spillage in suitable inert material

Place in appropriate container

6.4. Reference to other sections

For further information see section 8

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Keep away from heat and sources of ignition

Take precautionary measures against static discharges

Equipment should be earthed

Use explosion-proof electrical/ventilating/lighting/.../equipment.

Use only non-sparking tools.

Do not breathe aerosols or vapours.

Ensure adequate ventilation

Avoid contact with skin and eyes.

Wash thoroughly after use

Wear protective gloves/protective clothing/eye protection/face protection.

7.2. Conditions for safe storage, including any incompatibilities

Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C.

Keep in a cool, dry, well ventilated place

Keep out of reach of children.

7.3. Specific end use(s)

Sealants and Isolation

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits :

Hazardous ingredient	CAS-nr.	method
EU established exposure limits:
dimethyl ether	115-10-6	TWA	1000 ppm
National established exposure limits, United Kingdom
dimethyl ether	115-10-6	TWA	400 ppm
		STEL	500 ppm

8.2. Exposure controls

Control procedures :	Ensure adequate ventilation
	Keep away from heat and sources of ignition
	Take precautionary measures against static discharges

Personal protection :	Take precautions to avoid contact with skin and eyes when handling the product.
	Ensure adequate ventilation

inhalation :

In case of insufficient ventilation, wear suitable respiratory equipment.

Air purifying respirator equiped with organic gas/vapor cartridge (type A)

hands and skin :

Wear suitable protective gloves

Nitrile

eyes :

Wear safety eyewear according to EN 166.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

(for aerosols data for the product without propellant)

Appearance : physical state :

Liquid under pressure.

colour :

Green.

odour :

Characteristic odor.

pH :

Neutral.

Boiling point/range :

Not available.

Flash point :

- 97 °C

Evaporation rate :

Not available.

Explosion limits : upper limit :

18.6 %

lower limit :

3.0 %

Vapour pressure :

0.01 kPa (@ 20°C).

Relative density :

1.06 g/cm3 (@ 20°C).

Solubility in water :

Insoluble in water

Auto-ignition :

350 °C

Viscosity :

Not available.

9.2. Other information

VOC = volatile organic compounds

179.5 g/l

SECTION 10: Stability and reactivity

10.1. Reactivity

No hazardous reactions known if used for its intended purpose

10.2. Chemical stability

Stable

10.3. Possibility of hazardous reactions

No hazardous reactions known if used for its intended purpose

10.4. Conditions to avoid

Avoid overheating

10.5. Incompatible materials

Strong oxidising agent

10.6. Hazardous decomposition products

CO,CO2

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Danger of serious damage to health by prolonged exposure.

Limited evidence of a carcinogenic effect

Inhalation :	Harmful: danger of serious damage to health by prolonged exposure through inhalation.
	May cause sensitization by inhalation.
	Irritating to respiratory system.

Ingestion :

Ingestion is unlikely to occur

Skin contact :	May cause sensitization by skin contact.
	Irritating to skin

Eye contact :

Irritating to eyes

Toxicological data :

Hazardous ingredient	CAS-nr.	method
Reaction products of phosphoryl trichloride and 2-methyloxirane	1244733-77-4	LD50 oral rat	> 2000 mg/kg
		LC50 inhal.rat	7 mg/l

May cause damage to organs through prolonged or repeated exposure .

Limited evidence of a carcinogenic effect

SECTION 12: Ecological information

12.1. Toxicity

Not classified

Ecotoxicological data:

Hazardous ingredient	CAS-nr.	method
Reaction products of phosphoryl trichloride and 2-methyloxirane	1244733-77-4	LC50 fish	51 mg/l
		EC50 daphnia	131 mg/l

NOEC > 1000 mg/l (Daphnia magna/Algae)

12.2. Persistence and degradability

No experimental data available

12.3. Bioaccumulative potential

No experimental data available

12.4. Mobility in soil

No experimental data available

12.5. Results of PBT and vPvB assessment

No information available

12.6. Endocrine disrupting properties

No experimental data available

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product :	This material and its container must be disposed of in a safe way.
	Do not discharge into drains or the environment, dispose to an authorised waste collection point.

Contaminated packaging :

Disposal should be in accordance with local, state or national legislation

SECTION 14: Transport information

14.1. UN number

UN-number :

1950

14.2. UN proper shipping name

Proper shipping name:

AEROSOLS

14.3. Transport hazard class(es)

Class:

2.1

ADR/RID - Classification code:

14.4. Packing group

Packing group:

Not applicable.

14.5. Environmental hazards

ADR/RID - Environmentally hazardous:

IMDG - Marine pollutant:

IATA/ICAO - Environmentally hazardous:

14.6. Special precautions for user

ADR/RID - Tunnelcode:

(D)

IMDG - Ems:

F-D, S-U

IATA/ICAO - PAX:

203

IATA/ICAO - CAO

203

14.7. Maritime transport in bulk according to IMO instruments

Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

The Safety Data Sheet is compiled according to the current European requirements.

Dir. 2013/10/EU, 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC.

EU-directive 99/45/EC

Regulation (EC) No 1272/2008 (CLP)

Regulation (EC) No 1907/2006 (REACH)

15.2. Chemical safety assessment

No information available

SECTION 16: Other information

*Explanation hazard statements:	H220 : Extremely flammable gas.
	H280 : Contains gas under pressure; may explode if heated.
	H302 : Harmful if swallowed.
	H315 : Causes skin irritation.
	H317 : May cause an allergic skin reaction.
	H319 : Causes serious eye irritation.
	H332 : Harmful if inhaled.
	H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled.
	H335 : May cause respiratory irritation.
	H351 : Suspected of causing cancer .
	H373 : May cause damage to organs through prolonged or repeated exposure .

REVISIONS IN CHAPTRE :	Classification according to 67/548/EEC or 1999/45/EC:
	2.2. Label elements

This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.