Acryl RAL_Aerosol

Acryl RAL_Aerosol_English

Safety Data Sheet

Regulation EC No 1907/2006 Art.31

Productname :	Acryl RAL	Creationdate :	18.09.13 Version : 2.0
Ref.Nr.:	BDS001212_3_20130918 (EN)	Replaces:	BDS001212_20120614

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Acryl RAL

CHROME Gold

Aerosol

1.2. Relevant identified uses of the substance or mixture and uses advised against

Paints

1.3. Details of the supplier of the safety data sheet

CRC Industries Europe bvba

Touwslagerstraat 1

9240 Zele

Belgium

Tel.: +32(0)52/45.60.11

Fax.: +32(0)52/45.00.34

E-mail : hse@crcind.com

Subsidiaries		Tel	Fax
CRC Industries Finland Oy	Laurinkatu 57 A 23 B, 08100 Lohja	+358/(19)32.921	+358/(19)383.676
CRC Industries France	6, avenue du marais, C.S. 90028, 95102 Argenteuil Cedex	01.34.11.20.00	01.34.11.09.96
CRC Industries Deutschland GmbH	Südring 9, D-76473 Iffezheim	(07229) 303.0	(07229)30 32 66
CRC INDUSTRIES IBERIA S.L.U.	GREMIO DEL CUERO-PARC.96, POLIGONO INDUSTR. DE HONTORIA, 40195 SEGOVIA	0034/921.427.546	0034/921.436.270
CRC Industries Sweden	Laxfiskevägen 16, 433 38 Partille	0046/31 706 84 80	0046/31 27 39 91

1.4. Emergency telephone number

CRC Industries Europe, Belgium: Tel.: +32(0)52/45.60.11 (office hours: 9-17h pm CET)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Physical:	Aerosols, category 1
	Extremely flammable aerosol.
	Pressurised container: May burst if heated.

Health:	Skin irritation, category 2
	Causes skin irritation.
	Eye irritation, category 2
	Causes serious eye irritation.

Environment:

Not classified

Classification according to 67/548/EEC or 1999/45/EC:

Health:

R20/21: Harmful by inhalation and in contact with skin.

Physical:

EXTREMELY FLAMMABLE

Environment:

Not classified

2.2. Label elements

Labelling according to Regulation (EC) No 1272/2008

Hazard pictogram(s):

Signal word:

Danger

Hazard statement(s):	H222 : Extremely flammable aerosol.
	H229 : Pressurised container: May burst if heated.
	H315 : Causes skin irritation.
	H319 : Causes serious eye irritation.

Precautionary statement(s):	P101 : If medical advice is needed, have product container or label at hand.
	P102 : Keep out of reach of children.

	P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
	P211 : Do not spray on an open flame or other ignition source.
	P251 : Do not pierce or burn, even after use.
	P260 : Do not breathe dust/fume/gas/mist/vapours/spray.

P410/412 : Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.

P501-2 : Dispose of contents/container to an authorised waste collection point.

2.3. Other hazards

None

SECTION 3: Composition/information on ingredients

3.1. Substances

Not applicable.

3.2. Mixtures

Hazardous ingredient	CAS-nr.	EC-nr	w/w %	symbol	R-phrases*	Notes
butane (<= 0,1 % butadiene)	106-97-8	203-448-7	10-25	F+	12
xylene	1330-20-7	215-535-7	10-25	Xn	10-20/21-38	A
acetone; propan-2-one; propanone	67-64-1	200-662-2	10-25	F,Xi	11-36-66-67	A
propane	74-98-6	200-827-9	10-25	F+	12	B
ethylbenzene	100-41-4	202-849-4	5-10	F,Xn	11-20	A
isobutane	75-28-5	200-857-2	5-10	F+	12

Explanation notes

A : substance with Community workplace exposure limit

B : substance with national established workplace exposure limit

Hazardous ingredient	Registration number	CAS-nr.	EC-nr	w/w %	Hazard Class and Category	Hazard statement	Notes
butane (<= 0,1 % butadiene)		106-97-8	203-448-7	10-25	Flam. Gas 1, Press. Gas	H220
xylene		1330-20-7	215-535-7	10-25	Flam. Liq. 3, Acute Tox. 4, Acute Tox. 4, Skin Irrit. 2	H226,H332,H312,H315	A
acetone; propan-2-one; propanone	01-2119471330-49	67-64-1	200-662-2	10-25	Flam. Liq. 2, Eye Irrit. 2, STOT SE 3	H225,H319,H336	A
propane		74-98-6	200-827-9	10-25	Flam. Gas 1, Press. Gas	H220	B
ethylbenzene		100-41-4	202-849-4	5-10	Flam. Liq. 2, Acute Tox. 4	H225,H332	A
isobutane		75-28-5	200-857-2	5-10	Flam. Gas 1, Press. Gas	H220

Explanation notes

A : substance with Community workplace exposure limit

B : substance with national established workplace exposure limit

(* Explanation phrases : see chapter 16)

SECTION 4: First aid measures

4.1. Description of first aid measures

Contact with eyes :	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
	If eye irritation persists: Get medical advice/attention.

Contact with skin :	Take off contaminated clothing and wash before reuse.
	IF ON SKIN: Wash with plenty of water.
	If skin irritation occurs: Get medical advice/attention.

Inhalation :	IF INHALED: Remove person to fresh air and keep comfortable for breathing.
	Call a POISON CENTER or doctor/physician if you feel unwell.

Ingestion :

If swallowed do not induce vomiting because of risk of aspiration into the lungs. If aspiration is suspected obtain immediate medical attention

4.2. Most important symptoms and effects, both acute and delayed

Inhalation :

Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness

Ingestion :	After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia.
	Symptoms : sore throat, abdominal pain, nausea, vomiting

Skin contact :	Irritating to skin
	Symptoms : redness and pain

Eye contact :	Irritating to eyes
	Symptoms : redness and pain, impaired vision

4.3. Indication of any immediate medical attention and special treatment needed

General Advice :	If you feel unwell, seek medical advice (show the label where possible
	If symptoms persist always call a doctor

SECTION 5: Firefighting measures

5.1. Extinguishing media

foam, carbon dioxide or dry agent

5.2. Special hazards arising from the substance or mixture

Aerosols may explode if heated above 50°C

Forms hazardous decomposition products

CO,CO2

5.3. Advice for firefighters

Keep container(s) exposed to fire cool, by spraying with water

In case of fire, do not breathe fumes

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Shut off all ignition sources

Ensure adequate ventilation

Wear suitable protective clothing and gloves.

6.2. Environmental precautions

Do not allow to enter public sewers and watercourses

If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities

6.3. Methods and material for containment and cleaning up

Absorb spillage in suitable inert material

Place in appropriate container

This material and/or its container must be disposed of as hazardous waste.

6.4. Reference to other sections

For further information see section 8

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Keep away from heat and sources of ignition

Take precautionary measures against static discharges

Equipment should be earthed

Use explosion-proof electrical/ventilating/lighting/.../equipment.

Use only non-sparking tools.

Do not breathe aerosols or vapours.

Ensure adequate ventilation

Avoid contact with skin and eyes.

Wash thoroughly after use

Wear protective gloves/protective clothing/eye protection/face protection.

Eyewash bottles should be available

7.2. Conditions for safe storage, including any incompatibilities

Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C.

Keep out of reach of children.

7.3. Specific end use(s)

Paints

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits :

Hazardous ingredient	CAS-nr.	method
EU established exposure limits:
ethylbenzene	100-41-4	TWA	100 ppm
		STEL	200 ppm
xylene	1330-20-7	TWA	50 ppm
		STEL	100 ppm
acetone; propan-2-one; propanone	67-64-1	TWA	500 ppm
National established exposure limits, United Kingdom
ethylbenzene	100-41-4	TWA	100 ppm
		STEL	125 ppm
butane (<= 0,1 % butadiene)	106-97-8	TWA	600 ppm
		STEL	750 ppm
xylene	1330-20-7	TWA	50 ppm
		STEL	100 ppm
acetone; propan-2-one; propanone	67-64-1	TWA	500 ppm
		STEL	1500 ppm

8.2. Exposure controls

Control procedures :	Ensure adequate ventilation
	Keep away from heat and sources of ignition
	Take precautionary measures against static discharges

Personal protection :	Take precautions to avoid contact with skin and eyes when handling the product.
	Ensure adequate ventilation

inhalation :

In case of insufficient ventilation, wear suitable respiratory equipment.

Air purifying respirator equiped with organic gas/vapor cartridge (type A)

hands and skin :

Wear suitable protective gloves

Nitrile

eyes :

Wear safety eyewear according to EN 166.

Environmental protection:	Avoid release to the environment.
	Collect spillage.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

(for aerosols data for the product without propellant)

Appearance : physical state :

Propane/butane propelled liquid.

colour :

Yellow.

odour :

Characteristic odor.

pH :	Not applicable.

Boiling point/range :

Not available.

Flash point :

< 0 °C

Evaporation rate :

Not available.

Explosion limits : upper limit :

13 %

lower limit :

1.1 %

Vapour pressure :

Not available.

Relative density :

1.0 g/cm3 (@ 20°C).

Solubility in water :

Insoluble in water

Auto-ignition :

Not available.

Viscosity :

Not applicable.

9.2. Other information

VOC = volatile organic compounds

773 g/l

SECTION 10: Stability and reactivity

10.1. Reactivity

No hazardous reactions known if used for its intended purpose

10.2. Chemical stability

Stable

10.3. Possibility of hazardous reactions

No hazardous reactions known if used for its intended purpose

10.4. Conditions to avoid

Avoid overheating

10.5. Incompatible materials

Strong oxidising agent

10.6. Hazardous decomposition products

CO,CO2

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Inhalation :

Inhalation of solvent vapours may give rise to nausea, headaches and dizziness

Ingestion :

After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia.

Skin contact :

Irritating to skin

Eye contact :

Irritating to eyes

Toxicological data :

Hazardous ingredient	CAS-nr.	method
acetone; propan-2-one; propanone	67-64-1	LD50 oral rat	> 5000 mg/kg
		LC50 inhal.rat	> 20 mg/l
		LD50 derm.rabit	> 2000 mg/kg

SECTION 12: Ecological information

12.1. Toxicity

Not classified

Ecotoxicological data:

Hazardous ingredient	CAS-nr.	method
acetone; propan-2-one; propanone	67-64-1	IC50 algae	> 100 mg/l
		LC50 fish	> 100 mg/l
		EC50 daphnia	> 100 mg/l

12.2. Persistence and degradability

No experimental data available

12.3. Bioaccumulative potential

No experimental data available

12.4. Mobility in soil

No experimental data available

12.5. Results of PBT and vPvB assessment

No information available

12.6. Endocrine disrupting properties

No experimental data available

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product :	This material and its container must be disposed of in a safe way.
	Do not discharge into drains or the environment, dispose to an authorised waste collection point.

National regulations :

Disposal should be in accordance with local, state or national legislation

SECTION 14: Transport information

14.1. UN number

UN-number :

1950

14.2. UN proper shipping name

Proper shipping name:

AEROSOLS

14.3. Transport hazard class(es)

Class:

2.1

ADR/RID - Classification code:

14.4. Packing group

Packing group:

Not applicable.

14.5. Environmental hazards

ADR/RID - Environmentally hazardous:

IMDG - Marine pollutant:

IATA/ICAO - Environmentally hazardous:

14.6. Special precautions for user

ADR/RID - Tunnelcode:

(D)

IMDG - Ems:

F-D, S-U

IATA/ICAO - PAX:

203

IATA/ICAO - CAO

203

14.7. Maritime transport in bulk according to IMO instruments

Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

The Safety Data Sheet is compiled according to the current European requirements.

Dir. 2013/10/EU, 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC.

EU-directive 99/45/EC

Regulation (EC) No 1272/2008 (CLP)

Regulation (EC) No 1907/2006 (REACH)

15.2. Chemical safety assessment

No information available

SECTION 16: Other information

*Explanation hazard statements:	H220 : Extremely flammable gas.
	H225 : Highly flammable liquid and vapour.
	H226 : Flammable liquid and vapour.
	H312 : Harmful in contact with skin.
	H315 : Causes skin irritation.
	H319 : Causes serious eye irritation.
	H332 : Harmful if inhaled.
	H336 : May cause drowsiness or dizziness.

REVISIONS IN CHAPTRE :	2.2. Label elements
	8.2. Exposure controls

This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.