| SECTION 1: Identification of the substance/mixture and of the company/undertaking |
| 1.2. Relevant identified uses of the substance or mixture and uses advised against |
| 1.3. Details of the supplier of the safety data sheet |
| CRC Industries Europe bvba |
| Touwslagerstraat 1 |
| 9240 Zele |
| Belgium |
| Tel.: +32(0)52/45.60.11 |
| Fax.: +32(0)52/45.00.34 |
| E-mail : hse@crcind.com |
| Subsidiaries | | Tel | Fax |
| CRC Industries Finland Oy | Laurinkatu 57 A 23 B, 08100 Lohja | +358/(19)32.921 | |
| CRC Industries France | 6, avenue du marais, C.S. 90028, 95102 Argenteuil Cedex | 01.34.11.20.00 | 01.34.11.09.96 |
| CRC Industries Deutschland GmbH | Südring 9, D-76473 Iffezheim | (07229) 303 0 | (07229)30 32 66 |
| CRC INDUSTRIES IBERIA S.L.U. | GREMIO DEL CUERO-PARC.96, POLIGONO INDUSTR. DE HONTORIA, 40195 SEGOVIA | 0034/921.427.546 | 0034/921.436.270 |
| CRC Industries Sweden | Laxfiskevägen 16, 433 38 Partille | 0046/31 706 84 80 | 0046/31 27 39 91 |
| 1.4. Emergency telephone number |
| CRC Industries Europe, Belgium: Tel.: +32(0)52/45.60.11 (office hours: 9-17h pm CET) |
| SECTION 2: Hazards identification |
| 2.1. Classification of the substance or mixture |
| Classification according to Regulation (EC) No 1272/2008 |
| Classification is based on test data. |
| Health: |
Skin corrosion, category 1A |
| | Causes severe skin burns and eye damage. |
| Classification based on calculation method. |
| Environment: |
Not classified |
| Classification based on calculation method. |
| Other hazards : |
Not classified |
| Labelling according to Regulation (EC) No 1272/2008 |
| Product identifier: |
Contains: |
| | phosphoric acid,orthophosphoric acid |
| | Alcohols, C13-15, ethoxylated |
| Hazard pictogram(s): |
 |
|
|
|
| Hazard statement(s): |
H314 : Causes severe skin burns and eye damage. |
| Precautionary statement(s): |
P101 : If medical advice is needed, have product container or label at hand. |
| | P102 : Keep out of reach of children. |
|
P280 : Wear protective gloves/protective clothing/eye protection/face protection. |
|
P303/361/353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. |
| | P305/351/338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| | P310 : Immediately call a POISON CENTER or doctor/physician. |
|
P501-2 : Dispose of contents/container to an authorised waste collection point. |
| Regulation (EC) No 648/2004 on detergents: | non-ionic surfactants | 5 - 15 % |
| SECTION 3: Composition/information on ingredients |
| Hazardous ingredient | Registration number | CAS-nr. | EC-nr | w/w % | Hazard Class and Category | Hazard statement | Notes |
| phosphoric acid,orthophosphoric acid | 01-211948592-24 | 7664-38-2 | 231-633-2 | 10-20 | Skin Corr. 1B | H314 | A |
| Alcohols, C13-15, branched and linear, ethoxylated | | 157627-86-6 | 500-337-8 (NLP) | <10 | Acute Tox. 4, Eye Dam. 1, Aquatic Chronic 3 | H302,H318,H412 | |
| Explanation notes |
A : substance with Community workplace exposure limit |
| (* Explanation phrases : see chapter 16) |
| SECTION 4: First aid measures |
| 4.1. Description of first aid measures |
| Contact with eyes : |
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Contact with skin : |
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. |
| | Wash contaminated clothing before reuse. |
| | Immediately call a POISON CENTER or doctor/physician. |
| Inhalation : |
IF INHALED: Remove person to fresh air and keep comfortable for breathing. |
| Ingestion : |
IF SWALLOWED: rinse mouth. Do NOT induce vomiting. |
| | Immediately call a POISON CENTER or doctor/physician. |
| 4.2. Most important symptoms and effects, both acute and delayed |
| Inhalation : |
May cause irritation. |
| | Symptoms : sore throat, cough |
| Ingestion : |
May cause gastrointestinal disturbances |
| | Symptoms : sore throat, abdominal pain, nausea, vomiting |
| Skin contact : |
Causes severe burns. |
| | Symptoms : redness and pain |
| Eye contact : |
Causes serious eye damage. |
| | Symptoms : redness and pain, impaired vision |
| 4.3. Indication of any immediate medical attention and special treatment needed |
| General Advice : |
If you feel unwell, seek medical advice (show the label where possible |
| | If symptoms persist always call a doctor |
| SECTION 5: Firefighting measures |
| foam, carbon dioxide or dry agent |
| 5.2. Special hazards arising from the substance or mixture |
| May give off noxious and toxic fumes in a fire |
| 5.3. Advice for firefighters |
| Keep container(s) exposed to fire cool, by spraying with water |
| In case of fire, do not breathe fumes |
| SECTION 6: Accidental release measures |
| 6.1. Personal precautions, protective equipment and emergency procedures |
| Avoid contact with skin and eyes. |
| Ensure adequate ventilation |
| Wear suitable protective clothing including eye/face protection. |
| 6.2. Environmental precautions |
| Do not allow to enter public sewers and watercourses |
| If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities |
| 6.3. Methods and material for containment and cleaning up |
| Absorb spillage in suitable inert material |
| 6.4. Reference to other sections |
| For further information see section 8 |
| SECTION 7: Handling and storage |
| 7.1. Precautions for safe handling |
| Do not breathe aerosols or vapours. |
| Ensure adequate ventilation |
| Avoid contact with skin and eyes. |
| Wash thoroughly after use |
| Wear protective gloves/protective clothing/eye protection/face protection. |
| Eyewash bottles should be available |
| 7.2. Conditions for safe storage, including any incompatibilities |
| Keep container tightly closed, in a cool, well ventilated place. |
| Keep out of reach of children. |
| SECTION 8: Exposure controls/personal protection |
| Hazardous ingredient | CAS-nr. | method | | |
| EU established exposure limits: |
| phosphoric acid,orthophosphoric acid | 7664-38-2 | TWA | 1 mg/m3 |
| | STEL | 3 mg/m3 |
| National established exposure limits, United Kingdom |
| phosphoric acid,orthophosphoric acid | 7664-38-2 | TWA | 1 mg/m3 |
| | STEL | 2 mg/m3 |
| Control procedures : |
Ensure adequate ventilation |
| Personal protection : |
Take precautions to avoid contact with skin and eyes when handling the product. |
| | It is good practice to wear gloves and to provide adequate ventilation whenever using the product. |
| | In all cases handle and use the product in accordance with good industrial hygiene practices. |
| inhalation : |
In case of insufficient ventilation, wear suitable respiratory equipment. |
| recommended respiratory protection: |
Air purifying respirator equiped with ABEK type cartridge |
| hands and skin : |
When handling the product wear chemical-resistant gloves (standard EN 374). |
| | The breakthrough time of the glove should be longer than the total duration of product use. If work lasts longer than the breakthrough time, gloves should be changed part-way through. |
| Recommended gloves: |
(neoprene) |
| eyes : |
Wear safety eyewear according to EN 166. |
| Environmental protection: |
Avoid release to the environment. |
| | Collect spillage. |
| SECTION 9: Physical and chemical properties |
| 9.1. Information on basic physical and chemical properties |
| Appearance : physical state : |
Liquid. |
| Boiling point/range : |
100 °C |
| Flash point : |
Not available. |
| Evaporation rate : |
Not available. |
| Explosion limits : upper limit : |
Not available. |
| lower limit : |
Not available. |
| Vapour pressure : |
Not available. |
| Relative density : |
1.10 g/cm3. |
| Solubility in water : |
Soluble in water |
| Auto-ignition : |
Not available. |
| Viscosity : |
Not available. |
| SECTION 10: Stability and reactivity |
| No hazardous reactions known if used for its intended purpose |
| 10.3. Possibility of hazardous reactions |
| In case of fire, do not breathe fumes |
| May give off noxious and toxic fumes in a fire |
| 10.4. Conditions to avoid |
| 10.5. Incompatible materials |
| Strong oxidising agent |
| May be corrosive to metals. |
| 10.6. Hazardous decomposition products |
| SECTION 11: Toxicological information |
| 11.1. Information on toxicological effects |
| acute toxicity: |
based on available data the classification criteria are not met |
| skin corrosion/irritation: |
Causes severe skin burns and eye damage. |
| serious eye damage/irritation: |
Causes severe skin burns and eye damage. |
| respiratory or skin sensitisation: |
based on available data the classification criteria are not met |
| germ cell mutagenicity: |
based on available data the classification criteria are not met |
| carcinogenicity: |
based on available data the classification criteria are not met |
| toxicity for reproduction: |
based on available data the classification criteria are not met |
| STOT-single exposure: |
based on available data the classification criteria are not met |
| STOT repeated exposure: |
based on available data the classification criteria are not met |
| aspiration hazard: |
based on available data the classification criteria are not met |
| Information on likely routes of exposure: |
| Inhalation : |
May cause irritation. |
| Ingestion : |
May cause gastrointestinal disturbances |
| Skin contact : |
Causes severe burns. |
| Eye contact : |
Causes serious eye damage. |
| SECTION 12: Ecological information |
| 12.2. Persistence and degradability |
| 12.3. Bioaccumulative potential |
| 12.5. Results of PBT and vPvB assessment |
| 12.6. Endocrine disrupting properties |
| SECTION 13: Disposal considerations |
| 13.1. Waste treatment methods |
| Product : |
This material and its container must be disposed of in a safe way. |
|
Do not discharge into drains or the environment, dispose to an authorised waste collection point. |
| Contaminated packaging : |
Disposal should be in accordance with local, state or national legislation |
| SECTION 14: Transport information |
| 14.2. UN proper shipping name |
| Proper shipping name: |
PHOSPHORIC ACID SOLUTION |
| 14.3. Transport hazard class(es) |
| ADR/RID - Classification code: |
C1 |
| 14.5. Environmental hazards |
| ADR/RID - Environmentally hazardous: |
No |
| IMDG - Marine pollutant: |
No |
| IATA/ICAO - Environmentally hazardous: |
No |
| 14.6. Special precautions for user |
| ADR/RID - Tunnelcode: |
(E) |
| 14.7. Maritime transport in bulk according to IMO instruments |
| SECTION 15: Regulatory information |
| 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture |
| The Safety Data Sheet is compiled according to the current European requirements. |
| Regulation (EC) No 1907/2006 (REACH)
|
| Regulation (EC) No 1272/2008 (CLP)
|
|
| 15.2. Chemical safety assessment |
| SECTION 16: Other information |
| *Explanation hazard statements: |
H302 : Harmful if swallowed. |
| | H314 : Causes severe skin burns and eye damage. |
| | H318 : Causes serious eye damage. |
| | H412 : Harmful to aquatic life with long lasting effects. |
| REVISIONS IN CHAPTRE : |
8.2. Exposure controls |
| acronyms and synonyms: |
TWA = time weight average |
| | STEL = short time exposure limit |
| | VOC = volatile organic compounds |
| | PBT = persistant bioaccumulative toxic |
| | vPvB = very persitant very bioaccumulative |
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC. |
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