GRAFFITI REMOVER RTU_Bulk

GRAFFITI REMOVER RTU_Bulk_English

Safety Data Sheet

Regulation EC No 1907/2006 Art.31

Productname :	GRAFFITI REMOVER RTU	Creationdate :	13.04.11 Version : 1.0
Ref.Nr.:	UDS000022_3_20110413 (EN)	Replaces:

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

GRAFFITI REMOVER RTU

Bulk

1.2. Relevant identified uses of the substance or mixture and uses advised against

Cleaners - Heavy duty

1.3. Details of the supplier of the safety data sheet

CRC Industries UK Ltd.

Wylds Road

Castlefield Industrial Estate

TA6 4DD Bridgwater Somerset

United Kingdom

Tel.: +44 1278 727200

Fax.: +44 1278 425644

E-mail : hse.uk@crcind.com

1.4. Emergency telephone number

(+44)(0)1278 72 7200 (office hours)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to 67/548/EEC or 1999/45/EC:

Health:

R36: Irritating to eyes.

Physical:

Not classified

Environment:

Not classified

Other hazards :

Not classified

2.2. Label elements

Warning symbol(s) :	Xi : IRRITANT

Risk-phrase(s) :

R36: Irritating to eyes.

Safety-phrase(s) :	S2: Keep out of the reach of children.
	S24/25: Avoid contact with skin and eyes.
	S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
	S37/39: Wear suitable gloves and eye/face protection.

2.3. Other hazards

None

SECTION 3: Composition/information on ingredients

3.1. Substances

Not applicable.

3.2. Mixtures

Hazardous ingredient	CAS-nr.	EC-nr	w/w %	symbol	R-phrases*	Notes
triethanolamine	102-71-6	203-049-8	1-10	Xn	48/22-41	B
2-butoxyethanol; ethylene glycol monobutyl ether; butyl cellosolve	111-76-2	203-905-0	1-10	Xn	20/21/22-36/38	A
propan-2-ol; isopropyl alcohol; isopropanol	67-63-0	200-661-7	1-10	F,Xi	11-36-67	B

Explanation notes

A : substance with Community workplace exposure limit

B : substance with national established workplace exposure limit

Hazardous ingredient	Registration number	CAS-nr.	EC-nr	w/w %	Hazard Class and Category	Hazard statement	Notes
2-butoxyethanol; ethylene glycol monobutyl ether; butyl cellosolve		111-76-2	203-905-0	1-10	Acute Tox. 4, Acute Tox. 4, Acute Tox. 4, Eye Irrit. 2, Skin Irrit. 2	H332,H312,H302,H319,H315	A
propan-2-ol; isopropyl alcohol; isopropanol		67-63-0	200-661-7	1-10	Flam. Liq. 2, Eye Irrit. 2, STOT SE 3	H225,H319,H336	B

Explanation notes

A : substance with Community workplace exposure limit

B : substance with national established workplace exposure limit

(* Explanation phrases : see chapter 16)

SECTION 4: First aid measures

4.1. Description of first aid measures

Contact with eyes :	If substance has got into eyes, immediately wash out with water for at least 15 minutes
	Remove contact lenses, if present and easy to do. Continue rinsing.
	Seek medical advice

Contact with skin :	Take off immediately all contaminated clothing.
	Wash with water and soap.
	Seek medical advice

Inhalation :	Fresh air, keep warm and at rest.
	Seek medical attention if ill effects occur

Ingestion :	If swallowed do not induce vomiting
	Seek medical advice

4.2. Most important symptoms and effects, both acute and delayed

Inhalation :	May cause irritation.
	Symptoms : sore throat, cough

Ingestion :	May cause gastrointestinal disturbances
	Symptoms : sore throat, abdominal pain, nausea, vomiting

Skin contact :	Irritating to skin
	Symptoms : redness and pain

Eye contact :	Irritating to eyes
	Symptoms : redness and pain, impaired vision

4.3. Indication of any immediate medical attention and special treatment needed

General Advice :	If you feel unwell, seek medical advice (show the label where possible
	If symptoms persist always call a doctor

SECTION 5: Firefighting measures

5.1. Extinguishing media

foam, carbon dioxide or dry agent

5.2. Special hazards arising from the substance or mixture

May give off noxious and toxic fumes in a fire

5.3. Advice for firefighters

Keep container(s) exposed to fire cool, by spraying with water

In case of fire, do not breathe fumes

Wear breathing apparatus

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Avoid contact with skin and eyes.

Ensure adequate ventilation

Wear suitable protective clothing including eye/face protection.

6.2. Environmental precautions

Do not allow to enter public sewers and watercourses

If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities

6.3. Methods and material for containment and cleaning up

Absorb spillage in suitable inert material

6.4. Reference to other sections

For further information see section 8

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Do not breathe aerosols or vapours.

Ensure adequate ventilation

Avoid contact with skin and eyes.

Wash thoroughly after use

Wear protective gloves/protective clothing/eye protection/face protection.

Eyewash bottles should be available

7.2. Conditions for safe storage, including any incompatibilities

Keep container tightly closed, in a cool, well ventilated place.

Keep out of reach of children.

7.3. Specific end use(s)

Cleaners - Heavy duty

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits :

Hazardous ingredient	CAS-nr.	method
EU established exposure limits:
2-butoxyethanol; ethylene glycol monobutyl ether; butyl cellosolve	111-76-2	TWA	20 ppm
		STEL	50 ppm
propan-2-ol; isopropyl alcohol; isopropanol	67-63-0	TWA	400 ppm
		STEL	500 ppm

8.2. Exposure controls

Control procedures :

Ensure adequate ventilation

Personal protection :

Take precautions to avoid contact with skin and eyes when handling the product.

Ensure adequate ventilation

inhalation :

In case of insufficient ventilation, wear suitable respiratory equipment.

hands and skin :

Wear suitable protective gloves

(polyvinylchloride)

eyes :

Wear safety eyewear according to EN 166.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance : physical state :

Gel.

colour :

Colorless.

odour :

Solvent.

pH :

9.0

Boiling point/range :

>200 °C

Flash point :

Not available.

Evaporation rate :

Not available.

Explosion limits : upper limit :

Not available.

lower limit :

Not available.

Vapour pressure :

Not available.

Relative density :

1.02 g/cm3.

Solubility in water :

Partly soluble in water

Auto-ignition :

Not available.

Viscosity :

Not available.

9.2. Other information

No information available

SECTION 10: Stability and reactivity

10.1. Reactivity

No hazardous reactions known if used for its intended purpose

10.2. Chemical stability

Stable

10.3. Possibility of hazardous reactions

In case of fire, do not breathe fumes

May give off noxious and toxic fumes in a fire

10.4. Conditions to avoid

heat

10.5. Incompatible materials

Strong oxidising agent

10.6. Hazardous decomposition products

CO,CO2

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Inhalation :

May cause irritation.

Ingestion :

May cause gastrointestinal disturbances

Skin contact :

Irritating to skin

Eye contact :

Irritating to eyes

Toxicological data :

Hazardous ingredient	CAS-nr.	method
propan-2-ol; isopropyl alcohol; isopropanol	67-63-0	LD50 oral rat	>2000 mg/kg
		LC50 inhal.rat	>20 mg/l
		LD50 derm.rabit	>2000 mg/kg

SECTION 12: Ecological information

12.1. Toxicity

Not classified

Ecotoxicological data:

Hazardous ingredient	CAS-nr.	method
propan-2-ol; isopropyl alcohol; isopropanol	67-63-0	IC50 algae	>100 mg/l
		LC50 fish	>100 mg/l
		EC50 daphnia	>100 mg/l

12.2. Persistence and degradability

No information available

12.3. Bioaccumulative potential

No information available

12.4. Mobility in soil

Partly soluble in water

12.5. Results of PBT and vPvB assessment

No information available

12.6. Endocrine disrupting properties

No information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product :

This material and its container must be disposed of in a safe way.

Do not discharge into drains or the environment, dispose to an authorised waste collection point.

Contaminated packaging :

Disposal should be in accordance with local, state or national legislation

SECTION 14: Transport information

14.1. UN number

UN-number :

Not classified as hazardous for transport

14.2. UN proper shipping name

Proper shipping name:

Not applicable.

14.3. Transport hazard class(es)

Class:

Not applicable.

Subsidiary risk:

Not applicable.

ADR/RID - Classification code:

Not applicable.

14.4. Packing group

Packing group:

Not applicable.

14.5. Environmental hazards

ADR/RID - Environmentally hazardous:

IMDG - Marine pollutant:

IATA/ICAO - Environmentally hazardous:

14.6. Special precautions for user

ADR/RID - Tunnelcode:

Not applicable.

IMDG - Ems:

Not applicable.

IATA/ICAO - PAX:

Not applicable.

IATA/ICAO - CAO

Not applicable.

14.7. Maritime transport in bulk according to IMO instruments

Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

The Safety Data Sheet is compiled according to the current European requirements.

EU-directive 99/45/EC

Regulation (EC) No 1907/2006 (REACH)

15.2. Chemical safety assessment

No information available

SECTION 16: Other information

*Explanation hazard statements:	H225 : Highly flammable liquid and vapour.
	H302 : Harmful if swallowed.
	H312 : Harmful in contact with skin.
	H315 : Causes skin irritation.
	H319 : Causes serious eye irritation.
	H332 : Harmful if inhaled.
	H336 : May cause drowsiness or dizziness.

This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.