GRAFFITI REMOVER_Bulk_English
Safety Data Sheet Regulation EC No 1907/2006 Art.31
Productname : GRAFFITI REMOVER Creationdate : 10.04.12 Version : 1.0
Ref.Nr.: UDS000023_3_20120410 (EN) Replaces:
 
SECTION 1: Identification of the substance/mixture and of the company/undertaking
 
1.1. Product identifier
 
 
GRAFFITI REMOVER
Bulk
 
1.2. Relevant identified uses of the substance or mixture and uses advised against
 
Cleaners - Heavy duty
 
1.3. Details of the supplier of the safety data sheet
 
 
CRC Industries Europe bvba
Touwslagerstraat 1
9240 Zele
Belgium
Tel.: +32(0)52/45.60.11
Fax.: +32(0)52/45.00.34
E-mail : hse@crcind.com
 
SubsidiariesTelFax
CRC Industries Finland OyLaurinkatu 57 A 23 B, 08100 Lohja+358/(19)32.921+358/(19)383.676
CRC Industries France6, avenue du marais, B.P. 90028, 95102 Argenteuil Cedex01.34.11.20.0001.34.11.09.96
CRC Industries Deutschland GmbHSüdring 9, D-76473 Iffezheim(07229) 303.0(07229)30 32 66
CRC INDUSTRIES IBERIA S.L.U.GREMIO DEL CUERO-PARC.96, POLIGONO INDUSTR. DE HONTORIA, 40195 SEGOVIA0034/921.427.5460034/921.436.270
CRC Industries SwedenLaxfiskevägen 16, 433 38 Partille0046/31 706 84 800046/31 27 39 91
 
1.4. Emergency telephone number
 
 
CRC Industries Europe, Belgium: Tel.: +32(0)52/45.60.11 (office hours: 9-17h pm CET)
 
SECTION 2: Hazards identification
 
2.1. Classification of the substance or mixture
 
Classification according to 67/548/EEC or 1999/45/EC:
 
Health: R36: Irritating to eyes.
Physical: Not classified
Environment: Not classified
Other hazards : Not classified
 
2.2. Label elements
 
Warning symbol(s) : Xi : IRRITANT
 
Risk-phrase(s) : R36: Irritating to eyes.
Safety-phrase(s) : S2: Keep out of the reach of children.
 S24/25: Avoid contact with skin and eyes.
 S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
 S37/39: Wear suitable gloves and eye/face protection.
 
2.3. Other hazards
 
None
 
SECTION 3: Composition/information on ingredients
 
3.1. Substances
 
Not applicable.
 
3.2. Mixtures
 
 
Hazardous ingredientCAS-nr.EC-nrw/w %symbolR-phrases*Notes
triethanolamine102-71-6203-049-81-10Xn48/22-41B
2-butoxyethanol; ethylene glycol monobutyl ether; butyl cellosolve111-76-2203-905-01-10Xn20/21/22-36/38A
propan-2-ol; isopropyl alcohol; isopropanol67-63-0200-661-71-10F,Xi11-36-67B
Explanation notes
A : substance with Community workplace exposure limit
B : substance with national established workplace exposure limit
 
Hazardous ingredientRegistration numberCAS-nr.EC-nrw/w %Hazard Class and CategoryHazard statementNotes
2-butoxyethanol; ethylene glycol monobutyl ether; butyl cellosolve111-76-2203-905-01-10Acute Tox. 4, Acute Tox. 4, Acute Tox. 4, Eye Irrit. 2, Skin Irrit. 2H332,H312,H302,H319,H315A
propan-2-ol; isopropyl alcohol; isopropanol01-2119457558-2567-63-0200-661-71-10Flam. Liq. 2, Eye Irrit. 2, STOT SE 3H225,H319,H336B
Explanation notes
A : substance with Community workplace exposure limit
B : substance with national established workplace exposure limit
(* Explanation phrases : see chapter 16)
 
SECTION 4: First aid measures
 
4.1. Description of first aid measures
 
Contact with eyes : If substance has got into eyes, immediately wash out with water for at least 15 minutes
 Remove contact lenses, if present and easy to do. Continue rinsing.
 Seek medical advice
Contact with skin : Take off immediately all contaminated clothing.
 Wash with water and soap.
 Seek medical advice
Inhalation : Fresh air, keep warm and at rest.
 Seek medical attention if ill effects occur
Ingestion : If swallowed do not induce vomiting
 Seek medical advice
 
4.2. Most important symptoms and effects, both acute and delayed
 
Inhalation : May cause irritation.
 Symptoms : sore throat, cough
Ingestion : May cause gastrointestinal disturbances
 Symptoms : sore throat, abdominal pain, nausea, vomiting
Skin contact : Irritating to skin
 Symptoms : redness and pain
Eye contact : Irritating to eyes
 Symptoms : redness and pain, impaired vision
 
4.3. Indication of any immediate medical attention and special treatment needed
 
General Advice : If you feel unwell, seek medical advice (show the label where possible
 If symptoms persist always call a doctor
 
SECTION 5: Firefighting measures
 
5.1. Extinguishing media
 
foam, carbon dioxide or dry agent
 
5.2. Special hazards arising from the substance or mixture
 
May give off noxious and toxic fumes in a fire
 
5.3. Advice for firefighters
 
Keep container(s) exposed to fire cool, by spraying with water
In case of fire, do not breathe fumes
Wear breathing apparatus
 
SECTION 6: Accidental release measures
 
6.1. Personal precautions, protective equipment and emergency procedures
 
Avoid contact with skin and eyes.
Ensure adequate ventilation
Wear suitable protective clothing including eye/face protection.
 
6.2. Environmental precautions
 
Do not allow to enter public sewers and watercourses
If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities
 
6.3. Methods and material for containment and cleaning up
 
Absorb spillage in suitable inert material
 
6.4. Reference to other sections
 
For further information see section 8
 
SECTION 7: Handling and storage
 
7.1. Precautions for safe handling
 
Do not breathe aerosols or vapours.
Ensure adequate ventilation
Avoid contact with skin and eyes.
Wash thoroughly after use
Wear protective gloves/protective clothing/eye protection/face protection.
Eyewash bottles should be available
 
7.2. Conditions for safe storage, including any incompatibilities
 
Keep container tightly closed, in a cool, well ventilated place.
Keep out of reach of children.
 
7.3. Specific end use(s)
 
Cleaners - Heavy duty
 
SECTION 8: Exposure controls/personal protection
 
8.1. Control parameters
 
Exposure limits :
 
 
Hazardous ingredientCAS-nr.method
EU established exposure limits:
2-butoxyethanol; ethylene glycol monobutyl ether; butyl cellosolve111-76-2TWA20 ppm
STEL50 ppm
propan-2-ol; isopropyl alcohol; isopropanol67-63-0TWA400 ppm
STEL500 ppm
 
8.2. Exposure controls
 
Control procedures : Ensure adequate ventilation
Personal protection : Take precautions to avoid contact with skin and eyes when handling the product.
Ensure adequate ventilation
inhalation : In case of insufficient ventilation, wear suitable respiratory equipment.
hands and skin : Wear suitable protective gloves
(polyvinylchloride)
eyes : Wear safety eyewear according to EN 166.
 
SECTION 9: Physical and chemical properties
 
9.1. Information on basic physical and chemical properties
 
Appearance : physical state : Gel.
colour : Colorless.
odour : Solvent.
pH : 9.0
Boiling point/range : >200 °C
Flash point : Not available.
Evaporation rate : Not available.
Explosion limits : upper limit : Not available.
lower limit : Not available.
Vapour pressure : Not available.
Relative density : 1.02 g/cm3.
Solubility in water : Partly soluble in water
Auto-ignition : Not available.
Viscosity : Not available.
 
9.2. Other information
 
SECTION 10: Stability and reactivity
 
10.1. Reactivity
 
No hazardous reactions known if used for its intended purpose
 
10.2. Chemical stability
 
Stable
 
10.3. Possibility of hazardous reactions
 
In case of fire, do not breathe fumes
May give off noxious and toxic fumes in a fire
 
10.4. Conditions to avoid
 
heat
 
10.5. Incompatible materials
 
Strong oxidising agent
 
10.6. Hazardous decomposition products
 
CO,CO2
 
SECTION 11: Toxicological information
 
11.1. Information on toxicological effects
 
Inhalation : May cause irritation.
Ingestion : May cause gastrointestinal disturbances
Skin contact : Irritating to skin
Eye contact : Irritating to eyes
 
Toxicological data :
 
 
Hazardous ingredientCAS-nr.method
propan-2-ol; isopropyl alcohol; isopropanol67-63-0LD50 oral rat>2000 mg/kg
LC50 inhal.rat>20 mg/l
LD50 derm.rabit>2000 mg/kg
 
SECTION 12: Ecological information
 
12.1. Toxicity
 
Not classified
 
Ecotoxicological data:
 
 
Hazardous ingredientCAS-nr.method
propan-2-ol; isopropyl alcohol; isopropanol67-63-0IC50 algae>100 mg/l
LC50 fish>100 mg/l
EC50 daphnia>100 mg/l
 
12.2. Persistence and degradability
 
No information available
 
12.3. Bioaccumulative potential
 
No information available
 
12.4. Mobility in soil
 
Partly soluble in water
 
12.5. Results of PBT and vPvB assessment
 
No information available
 
12.6. Endocrine disrupting properties
 
No information available
 
SECTION 13: Disposal considerations
 
13.1. Waste treatment methods
 
Product : This material and its container must be disposed of in a safe way.
Do not discharge into drains or the environment, dispose to an authorised waste collection point.
Contaminated packaging : Disposal should be in accordance with local, state or national legislation
 
SECTION 14: Transport information
 
14.1. UN number
 
UN-number : Not classified as hazardous for transport
 
14.2. UN proper shipping name
 
Proper shipping name: Not applicable.
 
14.3. Transport hazard class(es)
 
Class: Not applicable.
Subsidiary risk: Not applicable.
ADR/RID - Classification code: Not applicable.
 
14.4. Packing group
 
Packing group: Not applicable.
 
14.5. Environmental hazards
 
ADR/RID - Environmentally hazardous: No
IMDG - Marine pollutant: No
IATA/ICAO - Environmentally hazardous: No
 
14.6. Special precautions for user
 
ADR/RID - Tunnelcode: Not applicable.
IMDG - Ems: Not applicable.
IATA/ICAO - PAX: Not applicable.
IATA/ICAO - CAO Not applicable.
 
14.7. Maritime transport in bulk according to IMO instruments
 
Not applicable.
 
SECTION 15: Regulatory information
 
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
 
The Safety Data Sheet is compiled according to the current European requirements.
EU-directive 99/45/EC
Regulation (EC) No 1907/2006 (REACH)
 
15.2. Chemical safety assessment
 
No information available
 
SECTION 16: Other information
 
*Explanation hazard statements: H225 : Highly flammable liquid and vapour.
 H302 : Harmful if swallowed.
 H312 : Harmful in contact with skin.
 H315 : Causes skin irritation.
 H319 : Causes serious eye irritation.
 H332 : Harmful if inhaled.
 H336 : May cause drowsiness or dizziness.
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.