| SECTION 1: Identification of the substance/mixture and of the company/undertaking |
| 1.2. Relevant identified uses of the substance or mixture and uses advised against |
| 1.3. Details of the supplier of the safety data sheet |
| CRC Industries UK Ltd. |
| Wylds Road |
| Castlefield Industrial Estate |
| TA6 4DD Bridgwater Somerset |
| United Kingdom |
| Tel.: +44 1278 727200 |
| Fax.: +44 1278 425644 |
| E-mail : hse.uk@crcind.com |
| 1.4. Emergency telephone number |
| (+44)(0)1278 72 7200
(office hours) |
| SECTION 2: Hazards identification |
| 2.1. Classification of the substance or mixture |
| Classification according to Regulation (EC) No 1272/2008 |
| Classification is based on test data. |
| Health: |
Eye irritation, category 2 |
| | Causes serious eye irritation. |
| Classification based on calculation method. |
| Environment: |
Not classified |
| Classification based on calculation method. |
| Other hazards : |
Not classified |
| Labelling according to Regulation (EC) No 1272/2008 |
| Hazard pictogram(s): |
 |
|
|
|
| Hazard statement(s): |
H319 : Causes serious eye irritation. |
| Precautionary statement(s): |
P101 : If medical advice is needed, have product container or label at hand. |
| | P102 : Keep out of reach of children. |
|
P280 : Wear protective gloves/protective clothing/eye protection/face protection. |
|
P305/351/338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| | P337/313 : If eye irritation persists: Get medical advice/attention. |
|
P501-2 : Dispose of contents/container to an authorised waste collection point. |
| Regulation (EC) No 648/2004 on detergents: | aliphatic hydrocarbons | < 5 % |
| anionic surfactants | < 5 % |
| perfumes | benzyl alcohol, limonene |
| SECTION 3: Composition/information on ingredients |
| Hazardous ingredient | Registration number | CAS-nr. | EC-nr | w/w % | Hazard Class and Category | Hazard statement | Notes |
| (2-methoxymethylethoxy)propanol | 01-2119450011-60 | 34590-94-8 | 252-104-2 | 5-10 | - | - | A |
| Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics | 01-2119456620-43 | - | (926-141-6) | 1-5 | Asp. Tox. 1 | H304 | B,Q |
| Glycine, N-methyl-N-(1-oxododecyl)-, sodium salt | 01-2119527780-39 | 137-16-6 | 205-281-5 | <3 | Eye Dam. 1, Skin Irrit. 2, Acute Tox. 2 | H318,H315,H330 | |
| ammonia .... % | 01-2119982985-14 | 1336-21-6 | 215-647-6 | 0-1 | Skin Corr. 1B, Aquatic Acute 1 | H314,H400 | |
| Explanation notes |
A : substance with Community workplace exposure limit |
B : substance with national established workplace exposure limit |
Q : The CAS-no is only an indicative identifier to be used outside the EU for global inventory entries. |
| (* Explanation phrases : see chapter 16) |
| SECTION 4: First aid measures |
| 4.1. Description of first aid measures |
| Contact with eyes : |
If substance has got into eyes, immediately wash out with water for at least 15 minutes |
| | Remove contact lenses, if present and easy to do. Continue rinsing. |
| | Seek medical advice |
| Contact with skin : |
Wash with water and soap. |
| | Seek medical attention if irritation persists |
| Inhalation : |
Fresh air, keep warm and at rest. |
| | Seek medical attention if ill effects occur |
| Ingestion : |
If swallowed do not induce vomiting |
| | Seek medical advice |
| 4.2. Most important symptoms and effects, both acute and delayed |
| Inhalation : |
May cause irritation. |
| | Symptoms : sore throat, cough |
| Ingestion : |
May cause gastrointestinal disturbances |
| | Symptoms : sore throat, abdominal pain, nausea, vomiting |
| Skin contact : |
May cause irritation. |
| | Symptoms : redness and pain |
| Eye contact : |
Irritating to eyes |
| | Symptoms : redness and pain, impaired vision |
| 4.3. Indication of any immediate medical attention and special treatment needed |
| General Advice : |
If you feel unwell, seek medical advice (show the label where possible |
| | If symptoms persist always call a doctor |
| SECTION 5: Firefighting measures |
| foam, carbon dioxide or dry agent |
| 5.2. Special hazards arising from the substance or mixture |
| May give off noxious and toxic fumes in a fire |
| 5.3. Advice for firefighters |
| Keep container(s) exposed to fire cool, by spraying with water |
| In case of fire, do not breathe fumes |
| SECTION 6: Accidental release measures |
| 6.1. Personal precautions, protective equipment and emergency procedures |
| Avoid contact with skin and eyes. |
| Ensure adequate ventilation |
| Wear suitable protective clothing including eye/face protection. |
| 6.2. Environmental precautions |
| Do not allow to enter public sewers and watercourses |
| If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities |
| 6.3. Methods and material for containment and cleaning up |
| Absorb spillage in suitable inert material |
| 6.4. Reference to other sections |
| For further information see section 8 |
| SECTION 7: Handling and storage |
| 7.1. Precautions for safe handling |
| Do not breathe aerosols or vapours. |
| Ensure adequate ventilation |
| Avoid contact with skin and eyes. |
| Wash thoroughly after use |
| Wear protective gloves/protective clothing/eye protection/face protection. |
| Eyewash bottles should be available |
| 7.2. Conditions for safe storage, including any incompatibilities |
| Keep container tightly closed, in a cool, well ventilated place. |
| Keep out of reach of children. |
| SECTION 8: Exposure controls/personal protection |
| Hazardous ingredient | CAS-nr. | method | | |
| EU established exposure limits: |
| (2-methoxymethylethoxy)propanol | 34590-94-8 | TWA | 50 ppm |
| National established exposure limits, United Kingdom |
| (2-methoxymethylethoxy)propanol | 34590-94-8 | TWA | 50 ppm |
| Control procedures : |
Ensure adequate ventilation |
| Personal protection : |
Take precautions to avoid contact with skin and eyes when handling the product. |
| | It is good practice to wear gloves and to provide adequate ventilation whenever using the product. |
| | In all cases handle and use the product in accordance with good industrial hygiene practices. |
| inhalation : |
In case of insufficient ventilation, wear suitable respiratory equipment. |
| hands and skin : |
For accidental contact the use of disposable gloves should be sufficient provided they are changed immediately after a splash or spill may occur.
If intentional contact is expected reusable gloves should be used with a breakthrough time greater than the total duration of the product use. |
| Recommended gloves: |
Nitrile |
| eyes : |
Wear safety eyewear according to EN 166. |
| SECTION 9: Physical and chemical properties |
| 9.1. Information on basic physical and chemical properties |
| Appearance : physical state : |
Liquid. |
| odour : |
Characteristic odor. |
| Boiling point/range : |
100 °C |
| Evaporation rate : |
Not available. |
| Explosion limits : upper limit : |
15 % |
| Vapour pressure : |
Not available. |
| Relative density : |
1 g/cm3 (@ 20°C). |
| Solubility in water : |
Soluble in water |
| Viscosity : |
Not available. |
| SECTION 10: Stability and reactivity |
| No hazardous reactions known if used for its intended purpose |
| 10.3. Possibility of hazardous reactions |
| In case of fire, do not breathe fumes |
| May give off noxious and toxic fumes in a fire |
| 10.4. Conditions to avoid |
| 10.5. Incompatible materials |
| 10.6. Hazardous decomposition products |
| SECTION 11: Toxicological information |
| 11.1. Information on toxicological effects |
| acute toxicity: |
based on available data the classification criteria are not met |
| skin corrosion/irritation: |
based on available data the classification criteria are not met |
| serious eye damage/irritation: |
Causes serious eye irritation. |
| respiratory or skin sensitisation: |
based on available data the classification criteria are not met |
| germ cell mutagenicity: |
based on available data the classification criteria are not met |
| carcinogenicity: |
based on available data the classification criteria are not met |
| toxicity for reproduction: |
based on available data the classification criteria are not met |
| STOT-single exposure: |
based on available data the classification criteria are not met |
| STOT repeated exposure: |
based on available data the classification criteria are not met |
| aspiration hazard: |
based on available data the classification criteria are not met |
| Information on likely routes of exposure: |
| Inhalation : |
May cause irritation. |
| Ingestion : |
May cause gastrointestinal disturbances |
| Skin contact : |
May cause irritation. |
| Eye contact : |
Irritating to eyes |
| Hazardous ingredient | CAS-nr. | method | | |
| (2-methoxymethylethoxy)propanol | 34590-94-8 | LD50 oral rat | > 5000 mg/kg |
| | LD50 derm.rabit | > 10000 mg/kg |
| Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics | - | LD50 oral rat | > 5000 mg/kg |
| | LC50 inhal.rat | >5000 mg/kg |
| | LD50 derm.rabit | > 5000 mg/kg |
| SECTION 12: Ecological information |
| Hazardous ingredient | CAS-nr. | method | | |
| (2-methoxymethylethoxy)propanol | 34590-94-8 | IC50 algae | > 100 mg/l |
| | LC50 fish | > 10000 mg/l |
| | EC50 daphnia | > 100 mg/l |
| Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics | - | IC50 algae | 1000 mg/l |
| | LC50 fish | 1000 mg/l |
| | EC50 daphnia | 1000 mg/l |
| 12.2. Persistence and degradability |
| 12.3. Bioaccumulative potential |
| 12.5. Results of PBT and vPvB assessment |
| 12.6. Endocrine disrupting properties |
| SECTION 13: Disposal considerations |
| 13.1. Waste treatment methods |
| Product : |
This material and its container must be disposed of in a safe way. |
|
Do not discharge into drains or the environment, dispose to an authorised waste collection point. |
| Contaminated packaging : |
Disposal should be in accordance with local, state or national legislation |
| SECTION 14: Transport information |
| UN-number : |
Not classified as hazardous for transport |
| 14.2. UN proper shipping name |
| Proper shipping name: |
Not applicable. |
| 14.3. Transport hazard class(es) |
| Subsidiary risk: |
Not applicable. |
| ADR/RID - Classification code: |
Not applicable. |
| Packing group: |
Not applicable. |
| 14.5. Environmental hazards |
| ADR/RID - Environmentally hazardous: |
No |
| IMDG - Marine pollutant: |
No |
| IATA/ICAO - Environmentally hazardous: |
No |
| 14.6. Special precautions for user |
| ADR/RID - Tunnelcode: |
Not applicable. |
| IMDG - Ems: |
Not applicable. |
| IATA/ICAO - PAX: |
Not applicable. |
| IATA/ICAO - CAO |
Not applicable. |
| 14.7. Maritime transport in bulk according to IMO instruments |
| SECTION 15: Regulatory information |
| 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture |
| The Safety Data Sheet is compiled according to the current European requirements. |
| Regulation (EC) No 1907/2006 (REACH)
|
| Regulation (EC) No 1272/2008 (CLP)
|
|
| 15.2. Chemical safety assessment |
| SECTION 16: Other information |
| *Explanation hazard statements: |
- : - |
| | H304 : May be fatal if swallowed and enters airways. |
| | H314 : Causes severe skin burns and eye damage. |
| | H315 : Causes skin irritation. |
| | H318 : Causes serious eye damage. |
| | H330 : Fatal if inhaled. |
| | H400 : Very toxic to aquatic life. |
| REVISIONS IN CHAPTRE : |
8.2. Exposure controls |
| acronyms and synonyms: |
TWA = time weight average |
| | STEL = short time exposure limit |
| | VOC = volatile organic compounds |
| | PBT = persistant bioaccumulative toxic |
| | vPvB = very persitant very bioaccumulative |
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation. The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties. Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC. |
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