| SECTION 1: Identification of the substance/mixture and of the company/undertaking |
| 1.2. Relevant identified uses of the substance or mixture and uses advised against |
| 1.3. Details of the supplier of the safety data sheet |
| CRC Industries Europe bvba |
| Touwslagerstraat 1 |
| 9240 Zele |
| Belgium |
| Tel.: +32(0)52/45.60.11 |
| Fax.: +32(0)52/45.00.34 |
| E-mail : hse@crcind.com |
| Subsidiaries | | Tel | Fax |
| CRC Industries Finland Oy | Asemanrinne 13, 08500 Lohja | +358/(19)32.921 | +358/(19)383.676 |
| CRC Industries France | 6, avenue du marais, B.P. 90028, 95102 Argenteuil Cedex | 01.34.11.20.00 | 01.34.11.09.96 |
| CRC Industries Deutschland GmbH | Südring 9, D-76473 Iffezheim | (07229) 303.0 | (07229)30 32 66 |
| CRC INDUSTRIES IBERIA S.L.U. | GREMIO DEL CUERO-PARC.96, POLIGONO INDUSTR. DE HONTORIA, 40195 SEGOVIA | 0034/921.427.546 | 0034/921.436.270 |
| CRC Industries Sweden | Kryptongatan 14, 431 53 Mölndal | 0046/31 706 84 80 | 0046/31 27 39 91 |
| 1.4. Emergency telephone number |
| CRC Industries Europe, Belgium: Tel.: +32(0)52/45.60.11 (office hours) |
| SECTION 2: Hazards identification |
| 2.1. Classification of the substance or mixture |
| Classification according to 67/548/EEC or 1999/45/EC: |
| Health: |
R38: Irritating to skin. |
| | R67: Vapours may cause drowsiness and dizziness. |
| Physical: |
R12: Extremely flammable. |
| | EXTREMELY FLAMMABLE |
| Environment: |
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| Warning symbol(s) : |
EXTREMELY FLAMMABLE |
| |  |
| | Xi : IRRITANT |
| |  |
| | N : DANGEROUS FOR THE ENVIRONMENT |
| |  |
| Risk-phrase(s) : |
R12: Extremely flammable. |
| | R38: Irritating to skin. |
| | R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| | R67: Vapours may cause drowsiness and dizziness. |
| Safety-phrase(s) : |
S2: Keep out of the reach of children. |
| | S16: Keep away from sources of ignition - No smoking. |
| | S23: Do not breathe vapours/spray. |
| | S24: Avoid contact with skin. |
| | S51: Use only in well-ventilated areas. |
| Extra label elements according to Aerosol Dispenser Directive 75/324/EC: |
Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. |
| Other extra label elements: |
Remark: Preparations classified as harmful on the basis of an aspiration hazard need not be labelled as harmful with
R65 when placed on the market in aerosol containers or in containers fitted with a sealed spray attachment.
(EU-Directive 67/548 Annex VI 9.4) |
| SECTION 3: Composition/information on ingredients |
| Hazardous ingredient | CAS-nr. | EC-nr | w/w % | symbol | R-phrases* | Notes |
| Hydrocarbons,C3-4-rich, petroleum distillate Petroleumgas (1,3-butadiene < 0.1%) | 68512-91-4 | 270-990-9 | 30-60 | F+ | 12 | K |
| hydrocarbons,C6,isoalkanes,< 5% n-hexane | - | 931-254-9 | 30-60 | F,Xn,N | 11-38-51/53-65-67 | B,P |
| Explanation notes |
| B : substance with national established workplace exposure limit |
| K : not classified as carcinogen, less than 0.1% w/w 1,3-butadiene (Einecs-nr. 203-450-8) |
| P : not classified as carcinogen, less than 0.1% w/w benzene (Einecs-nr. 200-753-7) |
| (* Explanation phrases : see chapter 16) |
| SECTION 4: First aid measures |
| 4.1. Description of first aid measures |
| Contact with eyes : |
If substance has got into eyes, immediately wash out with plenty of water |
| | Seek medical advice |
| Contact with skin : |
Remove contaminated clothing immediately and drench affected skin with plenty of water. Then wash with soap and water |
| | Seek medical advice |
| Inhalation : |
Fresh air, keep warm and at rest. |
| | Seek medical attention if ill effects occur |
| Ingestion : |
If swallowed do not induce vomiting because of risk of aspiration into the lungs. If aspiration is suspected obtain immediate medical attention |
| |
|
| 4.2. Most important symptoms and effects, both acute and delayed |
| Inhalation : |
Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness |
| Ingestion : |
After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia. |
| | Symptoms : sore throat, abdominal pain, nausea, vomiting |
| Skin contact : |
Irritating to skin |
| | Symptoms : redness and pain |
| Eye contact : |
May cause irritation. |
| | Symptoms : redness and pain |
| 4.3. Indication of any immediate medical attention and special treatment needed |
| General Advice : |
If you feel unwell, seek medical advice (show the label where possible |
| | If symptoms persist always call a doctor |
| SECTION 5: Firefighting measures |
| foam, carbon dioxide or dry agent |
| 5.2. Special hazards arising from the substance or mixture |
| Aerosols may explode if heated above 50°C |
| Forms hazardous decomposition products |
| CO,CO2 |
| 5.3. Advice for firefighters |
| Keep container(s) exposed to fire cool, by spraying with water |
| In case of fire, do not breathe fumes |
| SECTION 6: Accidental release measures |
| 6.1. Personal precautions, protective equipment and emergency procedures |
| Shut off all ignition sources |
| Ensure adequate ventilation |
| Wear suitable protective clothing and gloves. |
| 6.2. Environmental precautions |
| Do not allow to enter public sewers and watercourses |
| 6.3. Methods and material for containment and cleaning up |
| Absorb spillage in suitable inert material |
| 6.4. Reference to other sections |
| For further information see section 8 |
| SECTION 7: Handling and storage |
| 7.1. Precautions for safe handling |
| Keep away from heat and sources of ignition |
| Take precautionary measures against static discharges |
| Equipment should be earthed |
| Use explosion-proof electrical/ventilating/lighting/.../equipment. |
| Use only non-sparking tools. |
| Do not breathe aerosols or vapours. |
| Ensure adequate ventilation |
| Avoid contact with skin and eyes. |
| Wash thoroughly after use |
| Wear protective gloves/protective clothing/eye protection/face protection. |
| 7.2. Conditions for safe storage, including any incompatibilities |
| Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C. |
| Keep out of reach of children. |
| SECTION 8: Exposure controls/personal protection |
| Control procedures : |
Ensure adequate ventilation |
| | Keep away from heat and sources of ignition |
| | Take precautionary measures against static discharges |
| Personal protection : |
Take precautions to avoid contact with skin and eyes when handling the product. |
| | Ensure adequate ventilation |
| inhalation : |
In case of insufficient ventilation, wear suitable respiratory equipment. |
| hands and skin : |
Wear suitable protective gloves against chemicals |
| eyes : |
Wear safety goggles. |
| SECTION 9: Physical and chemical properties |
| 9.1. Information on basic physical and chemical properties |
| (for aerosols data for the product without propellant) |
| Apperance : physical state : |
Propane/butane propelled liquid. |
| colour : |
Colourless to yellow. |
| Boiling point/range : |
55 °C |
| Evaporation rate : |
Not available. |
| Explosion limits : upper limit : |
9.4 % |
| Vapour pressure : |
Not available. |
| Relative density : |
0.718 g/cm3 (@ 20°C). |
| Solubility in water : |
Insoluble in water |
| Viscosity : |
Not available. |
| SECTION 10: Stability and reactivity |
| No hazardous reactions known if used for its intended purpose |
| 10.3. Possibility of hazardous reactions |
| No hazardous reactions known if used for its intended purpose |
| 10.4. Conditions to avoid |
| 10.5. Incompatible materials |
| 10.6. Hazardous decomposition products |
| SECTION 11: Toxicological information |
| 11.1. Information on toxicological effects |
| Inhalation : |
Inhalation of solvent vapours may give rise to nausea, headaches and dizziness |
| Ingestion : |
After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia. |
| Skin contact : |
Irritating to skin |
| Eye contact : |
May cause irritation. |
| SECTION 12: Ecological information |
| R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| 12.2. Persistence and degradability |
| 12.3. Bioaccumulative potential |
| 12.5. Results of PBT and vPvB assessment |
| 12.6. Other adverse effects |
| SECTION 13: Disposal considerations |
| 13.1. Waste treatment methods |
| Product : |
This material and its container must be disposed of in a safe way. |
| | Do not discharge into drains or the environment, dispose to an authorised waste collection point. |
| Contaminated packaging : |
Disposal should be in accordance with local, state or national legislation |
| SECTION 14: Transport information |
| 14.2. UN proper shipping name |
| Proper shipping name: |
AEROSOLS |
| 14.3. Transport hazard class(es) |
| ADR/RID - Classification code: |
5F |
| Packing group: |
Not applicable. |
| 14.5. Environmental hazards |
| ADR/RID - Environmentally hazardous: |
Yes |
| IMDG - Marine pollutant: |
Marine pollutant |
| IATA/ICAO - Environmentally hazardous: |
Yes |
| 14.6. Special precautions for user |
| ADR/RID - Tunnelcode: |
(D) |
| 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code |
| SECTION 15: Regulatory information |
| 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture |
| The Safety Data Sheet is compiled according to the current European requirements. |
| Dir. 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC. |
| EU-directive 99/45/EC
|
| Regulation (EC) No 1907/2006 (REACH)
|
| 15.2. Chemical safety assessment |
| SECTION 16: Other information |
| *Explanation risk-phrases: |
R11: Highly flammable. |
| | R12: Extremely flammable. |
| | R38: Irritating to skin. |
| | R65: Harmful: may cause lung damage if swallowed. |
| | R67: Vapours may cause drowsiness and dizziness. |
| | R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks, no part of these documents may be reproduced by any process without written permission from CRC. |
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