SERVISOL FREEZE IT 25_Aerosol_English

Safety Data Sheet Regulation EC No 1907/2006 Art.31

Productname : SERVISOL FREEZE IT 25 Creationdate : 16.05.12 Version : 1.0
Ref.Nr.: UDS000379_3_20120516 (EN) Replaces:

 
SECTION 1: Identification of the substance/mixture and of the company/undertaking
 
1.1. Product identifier
 
 
SERVISOL FREEZE IT 25
Aerosol
 
1.2. Relevant identified uses of the substance or mixture and uses advised against
 
Cooling agent
 
1.3. Details of the supplier of the safety data sheet
 
 
CRC Industries UK Ltd.
Wylds Road
Castlefield Industrial Estate
TA6 4DD Bridgwater Somerset
United Kingdom
Tel.: +44 1278 727200
Fax.: +44 1278 425644
E-mail : hse.uk@crcind.com
 
SubsidiariesTelFax
CRC Industries Deutschland GmbHSüdring 9, D-76473 Iffezheim(07229) 303.0(07229)30 32 66
 
1.4. Emergency telephone number
 
 
(+44)(0)1278 72 7200 (office hours)
 
SECTION 2: Hazards identification
 
2.1. Classification of the substance or mixture
 
Classification according to 67/548/EEC or 1999/45/EC:
 
Health: Not classified
Physical: Not classified
Environment: Not classified
 
2.2. Label elements
 
Safety-phrase(s) : S2: Keep out of the reach of children.
Extra label elements according to Aerosol Dispenser Directive 75/324/EC: Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material.
 7 % by mass of the contents are flammable.
 
2.3. Other hazards
 
In case of contact with liquid product frostbite symptoms may occur.
Aerosols may explode if heated above 50°C
 
SECTION 3: Composition/information on ingredients
 
3.1. Substances
 
Not applicable.
 
3.2. Mixtures
 
 
Hazardous ingredientCAS-nr.EC-nrw/w %symbolR-phrases*Notes
tetrafluoroethane811-97-2212-377-060-100--B
dimethyl ether115-10-6204-065-85-10F+12A
Explanation notes
A : substance with Community workplace exposure limit
B : substance with national established workplace exposure limit
 
Hazardous ingredientRegistration numberCAS-nr.EC-nrw/w %Hazard Class and CategoryHazard statementNotes
dimethyl ether01-2119472128-37115-10-6204-065-85-10Flam. Gas 1, Press. GasH220,H280A
Explanation notes
A : substance with Community workplace exposure limit
(* Explanation phrases : see chapter 16)
 
SECTION 4: First aid measures
 
4.1. Description of first aid measures
 
Contact with eyes : Seek immediate medical attention
Contact with skin : In case of contact with liquid, thaw frosted parts with water, remove clothing carefully and wash with soap & water
 Seek medical advice
Inhalation : Fresh air, keep warm and at rest.
Ingestion : In case of accident or if you feel unwell, seek medical advice (show the label where possible)
 
4.2. Most important symptoms and effects, both acute and delayed
 
Inhalation : Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Ingestion : In case of exposure to substance or its vapours, obtain special treatment by doctor as soon as possible
Skin contact : In case of contact with liquid product frostbite symptoms may occur.
Eye contact : In case of contact with liquid product frostbite symptoms may occur.
 
4.3. Indication of any immediate medical attention and special treatment needed
 
General Advice : In case of accident or if you feel unwell, seek medical advice (show the label where possible)
 If symptoms persist always call a doctor
 
SECTION 5: Firefighting measures
 
5.1. Extinguishing media
 
water, foam, carbon dioxide or dry agent
 
5.2. Special hazards arising from the substance or mixture
 
Aerosols may explode if heated above 50°C
Forms hazardous decomposition products
CO,CO2
HF may be formed under condition of fire
 
5.3. Advice for firefighters
 
Keep container(s) exposed to fire cool, by spraying with water
In case of fire, do not breathe fumes
 
SECTION 6: Accidental release measures
 
6.1. Personal precautions, protective equipment and emergency procedures
 
Shut off all ignition sources
Ensure adequate ventilation
Wear suitable protective clothing and gloves.
 
6.2. Environmental precautions
 
Do not allow to enter public sewers and watercourses
 
6.3. Methods and material for containment and cleaning up
 
Allow product to evaporate
 
6.4. Reference to other sections
 
For further information see section 8
 
SECTION 7: Handling and storage
 
7.1. Precautions for safe handling
 
Keep away from heat and sources of ignition
Do not spray on a naked flame or incandescent material.
Do not pierce or burn aerosols, even after use.
Do not breathe aerosols or vapours.
Ensure adequate ventilation
Avoid contact with skin and eyes.
 
7.2. Conditions for safe storage, including any incompatibilities
 
Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use.
Store in a well-ventilated place.
Keep out of reach of children.
 
7.3. Specific end use(s)
 
Cooling agent
 
SECTION 8: Exposure controls/personal protection
 
8.1. Control parameters
 
Exposure limits :
 
 
Hazardous ingredientCAS-nr.method
EU established exposure limits:
dimethyl ether115-10-6TWA1000 ppm
National established exposure limits, United Kingdom
dimethyl ether115-10-6TWA400 ppm
STEL500 ppm
tetrafluoroethane811-97-2TWA1000 ppm
 
8.2. Exposure controls
 
Control procedures : Ensure adequate ventilation
 Keep away from heat and sources of ignition
Personal protection : Take precautions to avoid contact with skin and eyes when handling the product.
 Ensure adequate ventilation
inhalation : In case of insufficient ventilation, wear suitable respiratory equipment.
hands and skin : Wear suitable protective gloves
Nitrile
eyes : Wear safety eyewear according to EN 166.
 
SECTION 9: Physical and chemical properties
 
9.1. Information on basic physical and chemical properties
 
(for aerosols data for the product without propellant)
Apperance : physical state : Liquified gas.
colour : Colorless.
odour : Characteristic odor.
pH : Not applicable.
Boiling point/range : Not available.
Flash point : None
Evaporation rate : Not available.
Explosion limits : upper limit : Not available.
lower limit : Not available.
Vapour pressure : Not available.
Relative density : Not available.
Solubility in water : Insoluble in water
Auto-ignition : > 200 °C
Viscosity : Not available.
 
9.2. Other information
 
SECTION 10: Stability and reactivity
 
10.1. Reactivity
 
No hazardous reactions known if used for its intended purpose
 
10.2. Chemical stability
 
Stable
 
10.3. Possibility of hazardous reactions
 
No hazardous reactions known if used for its intended purpose
 
10.4. Conditions to avoid
 
Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C.
Avoid overheating
 
10.5. Incompatible materials
 
Strong oxidising agent
 
10.6. Hazardous decomposition products
 
CO,CO2
HF may be formed under condition of fire
 
SECTION 11: Toxicological information
 
11.1. Information on toxicological effects
 
Inhalation : Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness
Ingestion : Ingestion is unlikely to occur
Skin contact : In case of contact with liquid product frostbite symptoms may occur.
Eye contact : In case of contact with liquid product frostbite symptoms may occur.
 
Toxicological data :
 
 
No information available
 
SECTION 12: Ecological information
 
12.1. Toxicity
 
Not classified
 
Ecotoxicological data:
 
 
No information available
 
12.2. Persistence and degradability
 
No information available
 
12.3. Bioaccumulative potential
 
No information available
 
12.4. Mobility in soil
 
Insoluble in water
 
12.5. Results of PBT and vPvB assessment
 
No information available
 
12.6. Other adverse effects
 
No information available
 
SECTION 13: Disposal considerations
 
13.1. Waste treatment methods
 
Product : This material and its container must be disposed of in a safe way.
 Do not discharge into drains or the environment, dispose to an authorised waste collection point.
Contaminated packaging : Disposal should be in accordance with local, state or national legislation
 
SECTION 14: Transport information
 
14.1. UN number
 
UN-number : 1950
 
14.2. UN proper shipping name
 
Proper shipping name: AEROSOLS
 
14.3. Transport hazard class(es)
 
Class: 2.2
ADR/RID - Classification code: 5A
 
14.4. Packing group
 
Packing group: Not applicable.
 
14.5. Environmental hazards
 
ADR/RID - Environmentally hazardous: No
IMDG - Marine pollutant: No
IATA/ICAO - Environmentally hazardous: No
 
14.6. Special precautions for user
 
ADR/RID - Tunnelcode: (E)
IMDG - Ems: F-D, S-U
IATA/ICAO - PAX: 203
IATA/ICAO - CAO 203
 
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
 
Not applicable.
 
SECTION 15: Regulatory information
 
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
 
The Safety Data Sheet is compiled according to the current European requirements.
Dir. 2013/10/EU, 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC.
EU-directive 99/45/EC
Regulation (EC) No 1907/2006 (REACH)
 
15.2. Chemical safety assessment
 
No information available
 
SECTION 16: Other information
 
*Explanation hazard statements: H220 : Extremely flammable gas.
 H280 : Contains gas under pressure; may explode if heated.
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.