| SECTION 1: Identification of the substance/mixture and of the company/undertaking |
| 1.2. Relevant identified uses of the substance or mixture and uses advised against |
| 1.3. Details of the supplier of the safety data sheet |
| CRC Industries UK Ltd. |
| Wylds Road |
| Castlefield Industrial Estate |
| TA6 4DD Bridgwater Somerset |
| United Kingdom |
| Tel.: +44 1278 727200 |
| Fax.: +44 1278 425644 |
| E-mail : hse.uk@crcind.com |
| 1.4. Emergency telephone number |
| (+44)(0)1278 72 7200
(office hours) |
| SECTION 2: Hazards identification |
| 2.1. Classification of the substance or mixture |
| Classification according to Regulation (EC) No 1272/2008 |
| Physical: |
Flammable liquid, category 2 |
| | Highly flammable liquid and vapour. |
| Classification is based on test data. |
| Health: |
Eye irritation, category 2 |
| | Causes serious eye irritation. |
| | Specific target organ toxicity - single exposure, category 3 |
| | May cause drowsiness or dizziness. |
| Classification based on calculation method. |
| Environment: |
Not classified |
| Classification based on calculation method. |
| Other hazards : |
Repeated exposure may cause skin dryness or cracking. |
| Other hazards : |
Not classified |
| Labelling according to Regulation (EC) No 1272/2008 |
| Product identifier: |
Contains: |
| | acetone; propan-2-one; propanone |
| Hazard pictogram(s): |
 |
 |
|
|
| Hazard statement(s): |
H225 : Highly flammable liquid and vapour. |
| | H319 : Causes serious eye irritation. |
| | H336 : May cause drowsiness or dizziness. |
| Precautionary statement(s): |
P101 : If medical advice is needed, have product container or label at hand. |
| | P102 : Keep out of reach of children. |
|
P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. |
| | P271 : Use only outdoors or in a well-ventilated area. |
|
P305/351/338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| | P337/313 : If eye irritation persists: Get medical advice/attention. |
|
P501-2 : Dispose of contents/container to an authorised waste collection point. |
| Supplemental Hazard information: |
Repeated exposure may cause skin dryness or cracking. |
| SECTION 3: Composition/information on ingredients |
| Hazardous ingredient | Registration number | CAS-nr. | EC-nr | w/w % | Hazard Class and Category | Hazard statement | Notes |
| acetone; propan-2-one; propanone | 01-2119471330-49 | 67-64-1 | 200-662-2 | 10-30 | Flam. Liq. 2, Eye Irrit. 2, STOT SE 3 | H225,H319,H336 | A |
| Butanedioic acid, dimethyl ester | 01-2119486681-29 | 106-65-0 | 203-419-9 | 10-20 | Eye Irrit. 2 | H319 | B |
| methanol | 01-2119433307-44 | 67-56-1 | 200-659-6 | 0-1 | Flam. Liq. 2, Acute Tox. 3, Acute Tox. 3, Acute Tox. 3, STOT SE 1 | H225,H331,H311,H301,H370 | A |
| Explanation notes |
A : substance with Community workplace exposure limit |
B : substance with national established workplace exposure limit |
| (* Explanation phrases : see chapter 16) |
| SECTION 4: First aid measures |
| 4.1. Description of first aid measures |
| Contact with eyes : |
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Contact with skin : |
Wash with water and soap. |
| | Seek medical attention if irritation persists |
| Inhalation : |
Fresh air, keep warm and at rest. |
| | Seek medical attention if ill effects occur |
| Ingestion : |
If swallowed do not induce vomiting |
| | Seek medical advice |
| 4.2. Most important symptoms and effects, both acute and delayed |
| Inhalation : |
Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness |
| Ingestion : |
May cause gastrointestinal disturbances |
| | Symptoms : sore throat, abdominal pain, nausea, vomiting |
| Skin contact : |
Mildly irritating to skin |
| | Symptoms : redness and pain |
| Eye contact : |
Irritating to eyes |
| | Symptoms : redness and pain, impaired vision |
| 4.3. Indication of any immediate medical attention and special treatment needed |
| General Advice : |
If you feel unwell, seek medical advice (show the label where possible |
| | If symptoms persist always call a doctor |
| SECTION 5: Firefighting measures |
| foam, carbon dioxide or dry agent |
| 5.2. Special hazards arising from the substance or mixture |
| May form explosive vapour/air mixtures |
| Forms hazardous decomposition products |
| 5.3. Advice for firefighters |
| Keep container(s) exposed to fire cool, by spraying with water |
| In case of fire, do not breathe fumes |
| SECTION 6: Accidental release measures |
| 6.1. Personal precautions, protective equipment and emergency procedures |
| Shut off all ignition sources |
| Ensure adequate ventilation |
| Wear suitable protective clothing including eye/face protection. |
| 6.2. Environmental precautions |
| Do not allow to enter public sewers and watercourses |
| 6.3. Methods and material for containment and cleaning up |
| Absorb spillage in suitable inert material |
| 6.4. Reference to other sections |
| For further information see section 8 |
| SECTION 7: Handling and storage |
| 7.1. Precautions for safe handling |
| Keep away from heat and sources of ignition |
| Take precautionary measures against static discharges |
| Equipment should be earthed |
| Use explosion-proof electrical/ventilating/lighting/.../equipment. |
| Use only non-sparking tools. |
| Do not breathe aerosols or vapours. |
| Ensure adequate ventilation |
| Avoid contact with skin and eyes. |
| Wash thoroughly after use |
| Wear protective gloves/protective clothing/eye protection/face protection. |
| Eyewash bottles should be available |
| 7.2. Conditions for safe storage, including any incompatibilities |
| Keep container tightly closed, in a cool, well ventilated place. |
| Keep out of reach of children. |
| SECTION 8: Exposure controls/personal protection |
| Hazardous ingredient | CAS-nr. | method | | |
| EU established exposure limits: |
| methanol | 67-56-1 | TWA | 200 ppm |
| acetone; propan-2-one; propanone | 67-64-1 | TWA | 500 ppm |
| National established exposure limits, United Kingdom |
| methanol | 67-56-1 | TWA | 200 ppm |
| | STEL | 250 ppm |
| acetone; propan-2-one; propanone | 67-64-1 | TWA | 500 ppm |
| | STEL | 1500 ppm |
| Control procedures : |
Ensure adequate ventilation |
|
Keep away from heat and sources of ignition |
|
Take precautionary measures against static discharges |
| Personal protection : |
Take precautions to avoid contact with skin and eyes when handling the product. |
| | It is good practice to wear gloves and to provide adequate ventilation whenever using the product. |
| | In all cases handle and use the product in accordance with good industrial hygiene practices. |
| inhalation : |
In case of insufficient ventilation, wear suitable respiratory equipment. |
| recommended respiratory protection: |
Air purifying respirator equiped with organic gas/vapor cartridge (type AX) |
| hands and skin : |
Wear suitable protective gloves against chemicals.
Check the appropriateness of the recommended gloves for your own particular conditions of use and replace gloves regularly after check for signs of damage or defects. |
| Recommended gloves: |
Nitrile |
| eyes : |
Wear safety eyewear according to EN 166. |
| SECTION 9: Physical and chemical properties |
| 9.1. Information on basic physical and chemical properties |
| Appearance : physical state : |
Liquid. |
| odour : |
Characteristic odor. |
| Boiling point/range : |
56 °C |
| Evaporation rate : |
Not available. |
| Explosion limits : upper limit : |
13 % |
| Vapour pressure : |
Not available. |
| Relative density : |
0.979 g/cm3 (@ 20°C). |
| Solubility in water : |
Partly soluble in water |
| Viscosity : |
Not available. |
| SECTION 10: Stability and reactivity |
| No hazardous reactions known if used for its intended purpose |
| 10.3. Possibility of hazardous reactions |
| No hazardous reactions known if used for its intended purpose |
| 10.4. Conditions to avoid |
| 10.5. Incompatible materials |
| 10.6. Hazardous decomposition products |
| SECTION 11: Toxicological information |
| 11.1. Information on toxicological effects |
| acute toxicity: |
based on available data the classification criteria are not met |
| skin corrosion/irritation: |
based on available data the classification criteria are not met |
| serious eye damage/irritation: |
Causes serious eye irritation. |
| respiratory or skin sensitisation: |
based on available data the classification criteria are not met |
| germ cell mutagenicity: |
based on available data the classification criteria are not met |
| carcinogenicity: |
based on available data the classification criteria are not met |
| toxicity for reproduction: |
based on available data the classification criteria are not met |
| STOT-single exposure: |
May cause drowsiness or dizziness. |
| STOT repeated exposure: |
based on available data the classification criteria are not met |
| aspiration hazard: |
based on available data the classification criteria are not met |
| Information on likely routes of exposure: |
| Inhalation : |
Excessive inhalation of vapours may give rise to irritation and affect the nervous system |
| Skin contact : |
Prolonged skin contact will result in defatting of the skin, leading to irritation, and in some cases, dermatitis |
| Eye contact : |
Irritating to eyes |
| Hazardous ingredient | CAS-nr. | method | | |
| acetone; propan-2-one; propanone | 67-64-1 | LD50 oral rat | > 5800 mg/kg |
| | LC50 inhal.rat | 76 mg/l |
| | LD50 derm.rabit | > 15800 mg/kg |
| SECTION 12: Ecological information |
| Hazardous ingredient | CAS-nr. | method | | |
| acetone; propan-2-one; propanone | 67-64-1 | IC50 algae | 530 mg/l |
| | LC50 fish | 5540 mg/l |
| | EC50 daphnia | 8800 mg/l |
| 12.2. Persistence and degradability |
| 12.3. Bioaccumulative potential |
| 12.5. Results of PBT and vPvB assessment |
| 12.6. Endocrine disrupting properties |
| SECTION 13: Disposal considerations |
| 13.1. Waste treatment methods |
| Product : |
This material and its container must be disposed of in a safe way. |
|
Do not discharge into drains or the environment, dispose to an authorised waste collection point. |
| National regulations : |
Disposal should be in accordance with local, state or national legislation |
| SECTION 14: Transport information |
| 14.2. UN proper shipping name |
| Proper shipping name: |
ACETONE |
| 14.3. Transport hazard class(es) |
| ADR/RID - Classification code: |
F1 |
| 14.5. Environmental hazards |
| ADR/RID - Environmentally hazardous: |
No |
| IMDG - Marine pollutant: |
No |
| IATA/ICAO - Environmentally hazardous: |
No |
| 14.6. Special precautions for user |
| ADR/RID - Tunnelcode: |
(D/E) |
| 14.7. Maritime transport in bulk according to IMO instruments |
| SECTION 15: Regulatory information |
| 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture |
| The Safety Data Sheet is compiled according to the current European requirements. |
| Regulation (EC) No 1907/2006 (REACH)
|
| Regulation (EC) No 1272/2008 (CLP)
|
|
| 15.2. Chemical safety assessment |
| SECTION 16: Other information |
| *Explanation hazard statements: |
H225 : Highly flammable liquid and vapour. |
| | H301 : Toxic if swallowed. |
| | H311 : Toxic in contact with skin. |
| | H319 : Causes serious eye irritation. |
| | H331 : Toxic if inhaled. |
| | H336 : May cause drowsiness or dizziness. |
| | H370 : Causes damage to organs . |
| REVISIONS IN CHAPTRE : |
8.2. Exposure controls |
| acronyms and synonyms: |
TWA = time weight average |
| | STEL = short time exposure limit |
| | VOC = volatile organic compounds |
| | PBT = persistant bioaccumulative toxic |
| | vPvB = very persitant very bioaccumulative |
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation. The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties. Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC. |
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