| SECTION 1: Identification of the substance/mixture and of the company/undertaking |
| 1.2. Relevant identified uses of the substance or mixture and uses advised against |
| 1.3. Details of the supplier of the safety data sheet |
| CRC Industries UK Ltd. |
| Wylds Road |
| Castlefield Industrial Estate |
| TA6 4DD Bridgwater Somerset |
| United Kingdom |
| Tel.: +44 1278 727200 |
| Fax.: +44 1278 425644 |
| E-mail : hse.uk@crcind.com |
| 1.4. Emergency telephone number |
| (+44)(0)1278 72 7200
(office hours) |
| SECTION 2: Hazards identification |
| 2.1. Classification of the substance or mixture |
| Classification according to Regulation (EC) No 1272/2008 |
| Physical: |
Flammable liquid, category 2 |
| | Highly flammable liquid and vapour. |
| Classification is based on test data. |
| Health: |
Aspiration Hazard Category 1 |
| | May be fatal if swallowed and enters airways. |
| | Skin irritation, category 2 |
| | Causes skin irritation. |
| | Specific target organ toxicity - single exposure, category 3 |
| | May cause drowsiness or dizziness. |
| Classification based on calculation method. |
| Environment: |
Hazardous to the aquatic environment, chronic category 2 |
| | Toxic to aquatic life with long lasting effects. |
| Classification based on calculation method. |
| Other hazards : |
Contains: |
| | Siloxanes/silicones silyl-oxy-terminat. |
| | May produce an allergic reaction. |
| Other hazards : |
Not classified |
| Labelling according to Regulation (EC) No 1272/2008 |
| Product identifier: |
Contains: |
| | Alkanes, C7-10-iso- |
| | Naphtha (petroleum), light alkylate; Low boiling point modified naphtha |
| | Siloxanes/silicones silyl-oxy-terminat. |
| Hazard statement(s): |
H225 : Highly flammable liquid and vapour. |
| | H304 : May be fatal if swallowed and enters airways. |
| | H315 : Causes skin irritation. |
| | H336 : May cause drowsiness or dizziness. |
| | H411 : Toxic to aquatic life with long lasting effects. |
| Precautionary statement(s): |
P101 : If medical advice is needed, have product container or label at hand. |
| | P102 : Keep out of reach of children. |
|
P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. |
| | P271 : Use only outdoors or in a well-ventilated area. |
|
P301/310 : IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. |
| | P331 : Do NOT induce vomiting. |
|
P501-2 : Dispose of contents/container to an authorised waste collection point. |
| Supplemental Hazard information: |
Contains: |
| | Siloxanes/silicones silyl-oxy-terminat. |
| | May produce an allergic reaction. |
| SECTION 3: Composition/information on ingredients |
| Hazardous ingredient | Registration number | CAS-nr. | EC-nr | w/w % | Hazard Class and Category | Hazard statement | Notes |
| Alkanes, C7-10-iso- | - | 90622-56-3 | 292-458-5 | 60-100 | Flam. Liq. 2, Asp. Tox. 1, C50S, STOT SE 3, Aquatic Chronic 2 | H225,H304,H315,H336,H411 | B |
| Naphtha (petroleum), light alkylate; Low boiling point modified naphtha | 01-2119463272-43 | 64741-66-8 | 265-068-8 | 20-40 | Flam. Liq. 2, Asp. Tox. 1 | H225,H304 | |
| Siloxanes/silicones silyl-oxy-terminat. | - | 14324771-92-5 | 481-810-5 | <1 | Flam. liq. 1, Pyr. Liq. 1, Water-react. 1, Acute Tox. 4, STOT SE 3, Skin Irrit. 2, Eye Dam. 1, Skin Sens. 1 | H224,H250,H260,H332,H335,H315,H318,H317 | |
| Explanation notes |
B : substance with national established workplace exposure limit |
| (* Explanation phrases : see chapter 16) |
| SECTION 4: First aid measures |
| 4.1. Description of first aid measures |
| Contact with eyes : |
If substance has got into eyes, immediately wash out with water for at least 15 minutes |
| | Seek medical attention if irritation persists |
| Contact with skin : |
Remove contaminated clothing immediately and wipe affected skin with dry cloth. Then wash with soap and water |
| | Seek medical attention if irritation persists |
| Inhalation : |
Fresh air, keep warm and at rest. |
| | Seek medical attention if ill effects occur |
| Ingestion : |
If swallowed do not induce vomiting because of risk of aspiration into the lungs. If aspiration is suspected obtain immediate medical attention |
| 4.2. Most important symptoms and effects, both acute and delayed |
| Inhalation : |
Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness |
| Ingestion : |
After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia. |
| | Symptoms : sore throat, abdominal pain, nausea, vomiting |
| Skin contact : |
Irritating to skin |
| | Symptoms : redness and pain |
| Eye contact : |
Mildly irritating to eyes |
| | Symptoms : redness and pain |
| 4.3. Indication of any immediate medical attention and special treatment needed |
| General Advice : |
If you feel unwell, seek medical advice (show the label where possible |
| | If symptoms persist always call a doctor |
| SECTION 5: Firefighting measures |
| foam, carbon dioxide or dry agent |
| 5.2. Special hazards arising from the substance or mixture |
| May form explosive vapour/air mixtures |
| Forms hazardous decomposition products |
| 5.3. Advice for firefighters |
| Keep container(s) exposed to fire cool, by spraying with water |
| In case of fire, do not breathe fumes |
| SECTION 6: Accidental release measures |
| 6.1. Personal precautions, protective equipment and emergency procedures |
| Shut off all ignition sources |
| Ensure adequate ventilation |
| Wear suitable protective clothing including eye/face protection. |
| 6.2. Environmental precautions |
| Do not allow to enter public sewers and watercourses |
| If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities |
| 6.3. Methods and material for containment and cleaning up |
| Absorb spillage in suitable inert material |
| Place in appropriate container |
| This material and/or its container must be disposed of as hazardous waste. |
| 6.4. Reference to other sections |
| For further information see section 8 |
| SECTION 7: Handling and storage |
| 7.1. Precautions for safe handling |
| Keep away from heat and sources of ignition |
| Take precautionary measures against static discharges |
| Equipment should be earthed |
| Use explosion-proof electrical/ventilating/lighting/.../equipment. |
| Use only non-sparking tools. |
| Do not breathe aerosols or vapours. |
| Ensure adequate ventilation |
| Avoid contact with skin and eyes. |
| Wash thoroughly after use |
| Wear protective gloves/protective clothing/eye protection/face protection. |
| 7.2. Conditions for safe storage, including any incompatibilities |
| Keep container tightly closed, in a cool, well ventilated place. |
| Keep out of reach of children. |
| SECTION 8: Exposure controls/personal protection |
| Control procedures : |
Ensure adequate ventilation |
|
Keep away from heat and sources of ignition |
|
Take precautionary measures against static discharges |
| Personal protection : |
Take precautions to avoid contact with skin and eyes when handling the product. |
| | It is good practice to wear gloves and to provide adequate ventilation whenever using the product. |
| | In all cases handle and use the product in accordance with good industrial hygiene practices. |
| inhalation : |
In case of insufficient ventilation, wear suitable respiratory equipment. |
| hands and skin : |
When handling the product wear chemical-resistant gloves (standard EN 374). |
| | Use a reusable glove with a minimum breakthrough time of 30 minutes. The breakthrough time of the glove should be longer than the total duration of product use. If work lasts longer than the breakthrough time, gloves should be changed part-way through. |
| Recommended gloves: |
Nitrile |
| eyes : |
Wear safety eyewear according to EN 166. |
| SECTION 9: Physical and chemical properties |
| 9.1. Information on basic physical and chemical properties |
| Appearance : physical state : |
Liquid. |
| Boiling point/range : |
>112 °C |
| Flash point : |
7 °C (Closed Cup) |
| Evaporation rate : |
Not available. |
| Explosion limits : upper limit : |
6.2 % |
| Vapour pressure : |
Not available. |
| Relative density : |
0.720 g/cm3 (@ 20°C). |
| Solubility in water : |
Immiscible with water |
| Viscosity : |
Not available. |
| SECTION 10: Stability and reactivity |
| No hazardous reactions known if used for its intended purpose |
| 10.3. Possibility of hazardous reactions |
| No hazardous reactions known if used for its intended purpose |
| 10.4. Conditions to avoid |
| 10.5. Incompatible materials |
| 10.6. Hazardous decomposition products |
| SECTION 11: Toxicological information |
| 11.1. Information on toxicological effects |
| acute toxicity: |
based on available data the classification criteria are not met |
| skin corrosion/irritation: |
Causes skin irritation. |
| serious eye damage/irritation: |
based on available data the classification criteria are not met |
| respiratory or skin sensitisation: |
based on available data the classification criteria are not met |
| germ cell mutagenicity: |
based on available data the classification criteria are not met |
| carcinogenicity: |
based on available data the classification criteria are not met |
| toxicity for reproduction: |
based on available data the classification criteria are not met |
| STOT-single exposure: |
May cause drowsiness or dizziness. |
| STOT repeated exposure: |
based on available data the classification criteria are not met |
| aspiration hazard: |
May be fatal if swallowed and enters airways. |
| Information on likely routes of exposure: |
| Inhalation : |
Inhalation of solvent vapours may give rise to nausea, headaches and dizziness |
| Ingestion : |
After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia. |
| Skin contact : |
Irritating to skin |
| Eye contact : |
May cause irritation. |
| SECTION 12: Ecological information |
| Hazardous to the aquatic environment, chronic category 2 |
| Toxic to aquatic life with long lasting effects. |
| 12.2. Persistence and degradability |
| 12.3. Bioaccumulative potential |
| 12.5. Results of PBT and vPvB assessment |
| 12.6. Endocrine disrupting properties |
| SECTION 13: Disposal considerations |
| 13.1. Waste treatment methods |
| Product : |
This material and its container must be disposed of in a safe way. |
|
Do not discharge into drains or the environment, dispose to an authorised waste collection point. |
| National regulations : |
Disposal should be in accordance with local, state or national legislation |
| SECTION 14: Transport information |
| 14.2. UN proper shipping name |
| Proper shipping name: |
RESIN SOLUTION, flammable |
| 14.3. Transport hazard class(es) |
| ADR/RID - Classification code: |
F1 |
| 14.5. Environmental hazards |
| ADR/RID - Environmentally hazardous: |
Yes |
| IMDG - Marine pollutant: |
Marine pollutant |
| IATA/ICAO - Environmentally hazardous: |
Yes |
| 14.6. Special precautions for user |
| ADR/RID - Tunnelcode: |
(D/E) |
| 14.7. Maritime transport in bulk according to IMO instruments |
| SECTION 15: Regulatory information |
| 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture |
| The Safety Data Sheet is compiled according to the current European requirements. |
| Regulation (EC) No 1907/2006 (REACH)
|
| Regulation (EC) No 1272/2008 (CLP)
|
|
| 15.2. Chemical safety assessment |
| SECTION 16: Other information |
| *Explanation hazard statements: |
H224 : Extremely flammable liquid and vapour. |
| | H225 : Highly flammable liquid and vapour. |
| | H250 : Catches fire spontaneously if exposed to air. |
| | H260 : In contact with water releases flammable gases which may ignite spontaneously. |
| | H304 : May be fatal if swallowed and enters airways. |
| | H315 : Causes skin irritation. |
| | H317 : May cause an allergic skin reaction. |
| | H318 : Causes serious eye damage. |
| | H332 : Harmful if inhaled. |
| | H335 : May cause respiratory irritation. |
| | H336 : May cause drowsiness or dizziness. |
| | H411 : Toxic to aquatic life with long lasting effects. |
| REVISIONS IN CHAPTRE : |
8.2. Exposure controls |
| acronyms and synonyms: |
TWA = time weight average |
| | STEL = short time exposure limit |
| | VOC = volatile organic compounds |
| | PBT = persistant bioaccumulative toxic |
| | vPvB = very persitant very bioaccumulative |
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation. The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties. Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC. |
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