Gear & Wire Rope Lube_Aerosol

Gear & Wire Rope Lube_Aerosol_English

Safety Data Sheet

Regulation EC No 1907/2006 Art.31

Productname :	Gear & Wire Rope Lube	Creationdate :	31.03.16 Version : 1.0
Ref.Nr.:	UDS000618_3_20160331 (EN)	Replaces:	UDS000618_20141212

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Gear & Wire Rope Lube

Aerosol

1.2. Relevant identified uses of the substance or mixture and uses advised against

Lubricants

1.3. Details of the supplier of the safety data sheet

CRC Industries Europe bvba

Touwslagerstraat 1

9240 Zele

Belgium

Tel.: +32(0)52/45.60.11

Fax.: +32(0)52/45.00.34

E-mail : hse@crcind.com

Subsidiaries		Tel	Fax
CRC Industries Finland Oy	Laurinkatu 57 A 23 B, 08100 Lohja	+358/(19)32.921
CRC Industries France	6, avenue du marais, C.S. 90028, 95102 Argenteuil Cedex	01.34.11.20.00	01.34.11.09.96
CRC Industries Deutschland GmbH	Südring 9, D-76473 Iffezheim	(07229) 303 0	(07229)30 32 66
CRC INDUSTRIES IBERIA S.L.U.	GREMIO DEL CUERO-PARC.96, POLIGONO INDUSTR. DE HONTORIA, 40195 SEGOVIA	0034/921.427.546	0034/921.436.270
CRC Industries Sweden	Laxfiskevägen 16, 433 38 Partille	0046/31 706 84 80	0046/31 27 39 91

1.4. Emergency telephone number

CRC Industries Europe, Belgium: Tel.: +32(0)52/45.60.11 (office hours: 9-17h pm CET)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Physical:	Aerosols, category 1
	Extremely flammable aerosol.
	Pressurised container: May burst if heated.

Health:	Skin irritation, category 2
	Causes skin irritation.
	Specific Target Organ Toxicity - Repeated Exposure Category 2
	May cause damage to organs through prolonged or repeated exposure .

Environment:	Hazardous to the aquatic environment, chronic category 3
	Harmful to aquatic life with long lasting effects.

2.2. Label elements

Labelling according to Regulation (EC) No 1272/2008

Product identifier:	Contains:
	Naphtha (petroleum), hydrodesulfurized heavy

Hazard pictogram(s):

Signal word:

Danger

Hazard statement(s):	H222 : Extremely flammable aerosol.
	H229 : Pressurised container: May burst if heated.
	H315 : Causes skin irritation.
	H373 : May cause damage to organs through prolonged or repeated exposure .
	H412 : Harmful to aquatic life with long lasting effects.

Precautionary statement(s):

P102 : Keep out of reach of children.

	P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
	P211 : Do not spray on an open flame or other ignition source.
	P251 : Do not pierce or burn, even after use.
	P260 : Do not breathe dust/fume/gas/mist/vapours/spray.

P410/412 : Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.

P501-2 : Dispose of contents/container to an authorised waste collection point.

2.3. Other hazards

None

SECTION 3: Composition/information on ingredients

3.1. Substances

Not applicable.

3.2. Mixtures

Hazardous ingredient	Registration number	CAS-nr.	EC-nr	w/w %	Hazard Class and Category	Hazard statement	Notes
Hydrocarbons,C3-4-rich, petroleum distillate Petroleumgas (1,3-butadiene < 0.1%)	-	68512-91-4	270-990-9	60-100	Press. Gas, Flam. Gas 1	H280,H220	K,G
xylene		1330-20-7	215-535-7	5-10	Flam. Liq. 3, Acute Tox. 4, Acute Tox. 4, Skin Irrit. 2, Asp. Tox. 1	H226,H312,H332,H315,H304	A
Hydrocarbons, C7, n-alkanes,isoalkanes, cyclic	01-2119475515-33	-	927-510-4	5-10	Flam. Liq. 2, Skin Irrit. 2, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2	H225,H315,H336,H304,H411	B
Naphtha (petroleum), hydrodesulfurized heavy	01-2119458049-33	64742-82-1	265-185-4	1-5	Flam. Liq. 3, STOT SE 3, STOT RE 1, Aquatic Chronic 2, Asp. Tox. 1	H226,H336,H372,H411,H304	B,P

Explanation notes

A : substance with Community workplace exposure limit

B : substance with national established workplace exposure limit

G : exempted from the obligation to register in accordance with art.2(7)of REACH Regulation No 1907/2006

K : not classified as carcinogen, less than 0.1% w/w 1,3-butadiene (Einecs-nr. 203-450-8)

P : not classified as carcinogen, less than 0.1% w/w benzene (Einecs-nr. 200-753-7)

(* Explanation phrases : see chapter 16)

SECTION 4: First aid measures

4.1. Description of first aid measures

Contact with eyes :	If substance has got into eyes, immediately wash out with plenty of water
	If eye irritation persists: Get medical advice/attention.

Contact with skin :	Take off contaminated clothing and wash before reuse.
	IF ON SKIN: Wash with plenty of water.
	If skin irritation occurs: Get medical advice/attention.

Inhalation :	IF INHALED: Remove person to fresh air and keep comfortable for breathing.
	Call a POISON CENTER or doctor/physician if you feel unwell.

Ingestion :	If swallowed do not induce vomiting because of risk of aspiration into the lungs. If aspiration is suspected obtain immediate medical attention

4.2. Most important symptoms and effects, both acute and delayed

Inhalation :

Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness

Ingestion :	After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia.
	Symptoms : sore throat, abdominal pain, nausea, vomiting

Skin contact :	Irritating to skin
	Symptoms : redness and pain

Eye contact :	May cause irritation.
	Symptoms : redness and pain

4.3. Indication of any immediate medical attention and special treatment needed

General Advice :	If you feel unwell, seek medical advice (show the label where possible
	If symptoms persist always call a doctor

SECTION 5: Firefighting measures

5.1. Extinguishing media

foam, carbon dioxide or dry agent

5.2. Special hazards arising from the substance or mixture

Aerosols may explode if heated above 50°C

Forms hazardous decomposition products

CO,CO2

5.3. Advice for firefighters

Keep container(s) exposed to fire cool, by spraying with water

In case of fire, do not breathe fumes

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Shut off all ignition sources

Ensure adequate ventilation

Wear suitable protective clothing and gloves.

6.2. Environmental precautions

Do not allow to enter public sewers and watercourses

6.3. Methods and material for containment and cleaning up

Absorb spillage in suitable inert material

6.4. Reference to other sections

For further information see section 8

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Keep away from heat and sources of ignition

Take precautionary measures against static discharges

Equipment should be earthed

Use explosion-proof electrical/ventilating/lighting/.../equipment.

Use only non-sparking tools.

Do not breathe aerosols or vapours.

Ensure adequate ventilation

Avoid contact with skin and eyes.

Wash thoroughly after use

Wear protective gloves/protective clothing/eye protection/face protection.

7.2. Conditions for safe storage, including any incompatibilities

Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C.

Keep out of reach of children.

7.3. Specific end use(s)

Lubricants

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits :

Hazardous ingredient	CAS-nr.	method
EU established exposure limits:
xylene	1330-20-7	TWA	50 ppm
		STEL	100 ppm
National established exposure limits, United Kingdom
xylene	1330-20-7	TWA	50 ppm
		STEL	100 ppm

8.2. Exposure controls

Control procedures :	Ensure adequate ventilation
	Keep away from heat and sources of ignition
	Take precautionary measures against static discharges

Personal protection :	Take precautions to avoid contact with skin and eyes when handling the product.
	In all cases handle and use the product in accordance with good industrial hygiene practices.
	Ensure adequate ventilation

inhalation :

In case of insufficient ventilation, wear suitable respiratory equipment.

recommended respiratory protection:

Air purifying respirator equiped with organic gas/vapor cartridge (type A)

hands and skin :	When handling the product wear chemical-resistant gloves (standard EN 374).
	Use a reusable glove with a minimum breakthrough time of 30 minutes. The breakthrough time of the glove should be longer than the total duration of product use. If work lasts longer than the breakthrough time, gloves should be changed part-way through.

Recommended gloves:

Nitrile

eyes :

Wear safety eyewear according to EN 166.

Environmental protection:	Avoid release to the environment.
	Collect spillage.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

(for aerosols data for the product without propellant)

Appearance : physical state :

Propane/butane propelled liquid.

colour :

Black.

odour :

Characteristic odor.

pH :	Not applicable.

Boiling point/range :

94 °C

Flash point :

- 4 °C

Evaporation rate :

Not available.

Explosion limits : upper limit :

9.4 %

lower limit :

0.9 %

Vapour pressure :

Not available.

Relative density :

0.862 g/cm3 (@ 20°C).

Solubility in water :

Insoluble in water

Auto-ignition :

> 200 °C

Viscosity :

Not available.

9.2. Other information

SECTION 10: Stability and reactivity

10.1. Reactivity

No hazardous reactions known if used for its intended purpose

10.2. Chemical stability

Stable

10.3. Possibility of hazardous reactions

No hazardous reactions known if used for its intended purpose

10.4. Conditions to avoid

Avoid overheating

10.5. Incompatible materials

Strong oxidising agent

10.6. Hazardous decomposition products

CO,CO2

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Information on likely routes of exposure:

Inhalation :

Inhalation of solvent vapours may give rise to nausea, headaches and dizziness

Ingestion :

After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia.

Skin contact :

Irritating to skin

Eye contact :

May cause irritation.

Toxicological data :

Hazardous ingredient	CAS-nr.	method
Naphtha (petroleum), hydrodesulfurized heavy	64742-82-1	LD50 oral rat	> 2000 mg/kg
Hydrocarbons, C7, n-alkanes,isoalkanes, cyclic	-	LD50 oral rat	> 5000 mg/kg
		LC50 inhal.rat	> 20 mg/l
		LD50 derm.rat	> 2000 mg/kg

SECTION 12: Ecological information

12.1. Toxicity

Hazardous to the aquatic environment, chronic category 3

Harmful to aquatic life with long lasting effects.

Ecotoxicological data:

Hazardous ingredient	CAS-nr.	method
Naphtha (petroleum), hydrodesulfurized heavy	64742-82-1	IC50 algae	1 - 10 mg/l
		LC50 fish	10 - 100 mg/l
		EC50 daphnia	10 - 100 mg/l
Hydrocarbons, C7, n-alkanes,isoalkanes, cyclic	-	IC50 algae	10-30 mg/l
		LC50 fish	> 10 mg/l
		EC50 daphnia	3 mg/l

12.2. Persistence and degradability

No information available

12.3. Bioaccumulative potential

No information available

12.4. Mobility in soil

Insoluble in water

12.5. Results of PBT and vPvB assessment

No information available

12.6. Endocrine disrupting properties

No information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product :	This material and its container must be disposed of in a safe way.
	Do not discharge into drains or the environment, dispose to an authorised waste collection point.

Contaminated packaging :

Disposal should be in accordance with local, state or national legislation

SECTION 14: Transport information

14.1. UN number

UN-number :

1950

14.2. UN proper shipping name

Proper shipping name:

AEROSOLS

14.3. Transport hazard class(es)

Class:

2.1

ADR/RID - Classification code:

14.4. Packing group

Packing group:

Not applicable.

14.5. Environmental hazards

ADR/RID - Environmentally hazardous:

IMDG - Marine pollutant:

IATA/ICAO - Environmentally hazardous:

14.6. Special precautions for user

ADR/RID - Tunnelcode:

(D)

IMDG - Ems:

F-D, S-U

IATA/ICAO - PAX:

203

IATA/ICAO - CAO

203

14.7. Maritime transport in bulk according to IMO instruments

Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

The Safety Data Sheet is compiled according to the current European requirements.

Dir. 2013/10/EU, 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC.

EU-directive 99/45/EC

Regulation (EC) No 1272/2008 (CLP)

Regulation (EC) No 1907/2006 (REACH)

15.2. Chemical safety assessment

No information available

SECTION 16: Other information

*Explanation hazard statements:	H220 : Extremely flammable gas.
	H225 : Highly flammable liquid and vapour.
	H226 : Flammable liquid and vapour.
	H280 : Contains gas under pressure; may explode if heated.
	H304 : May be fatal if swallowed and enters airways.
	H312 : Harmful in contact with skin.
	H315 : Causes skin irritation.
	H332 : Harmful if inhaled.
	H336 : May cause drowsiness or dizziness.
	H372 : Causes damage to organs through prolonged or repeated exposure.
	H411 : Toxic to aquatic life with long lasting effects.

This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC.