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CRC Industries Europe bvba Touwslagerstraat 1 9240 Zele - Belgium Tel (+32) (0) 52 / 45 60 11 - Fax (+32) (0) 52 / 45 00 34 |
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Material Safety Data Sheet | Regulation EC No 1907/2006 Art.31 |
Productname : | GALVA BRITE | Creationdate : | 29.11.10 |
Ref.Nr.: | AB10740-3-291110 | Replaces: | 06.07.10 |
Productname : |
GALVA BRITE Aerosol |
Application : |
Anti Corrosion Products |
Company : |
CRC Industries Europe
bvba Touwslagerstraat 1 9240 ZELE Belgium Tel.: (+32)(0)52/456011 Fax: (+32)(0)52/450034 E-mail : hse@crcind.com |
In case of emergency : |
(+32) (0)52/45 60 11 |
Subsidiaries |
|
Tel |
Fax |
CRC
Industries Finland |
Asemanrinne
13, 08500 Lohja AS |
(+358)(0)19/32921 |
(+358)(0)19/383676 |
CRC
Industries France |
12,
Bld des Martyrs de Chateaubriant F-95102
Argenteuil Cédex |
(+33)(0)1/34112000 |
(+33)(0)1/34110996 |
CRC
Industries Deutschland |
Südring
9, 76473 Iffezheim |
(+49)(0)7229/3030 |
(+49)(0)7229/303266 |
CRC
Industries Iberia |
Gremio
del cuero S/N, 40195
Segovia |
(+34)921/427546 |
(+34)921/436270 |
CRC
Industries Sweden |
Kryptongatan
14, 43153 Mölndal |
(+46)(0)31/7068480 |
(+46)(0)31/273991 |
Health and Safety : |
Extremely Flammable (DME propellant) Remark: Preparations classified as harmful on the basis of an aspiration hazard need not be labelled as harmful with R65 when placed on the market in aerosol containers or in containers fitted with a sealed spray attachment. (EU-Directive 67/548 Annex VI 9.4) |
Environment : |
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
Other hazards : |
Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Without adequate ventilation formation of explosive mixtures may be possible. |
Hazardous ingredient | CAS-nbr. | EINECS | w/w % | symbol | R-phrases* | Notes |
mesitylene1,3,5-trimethylbenzene | 108-67-8 | 203-604-4 | <1 | Xi,N | 10-37-51/53 | A |
dimethyl ether | 115-10-6 | 204-065-8 | 30-60 | F+ | 12 | A |
n-butyl acetate | 123-86-4 | 204-658-1 | 1-5 | 10-66-67 | ||
zinc oxide | 1314-13-2 | 215-222-5 | 0.25-2.5 | N | 50/53 | B |
ethyl acetate | 141-78-6 | 205-500-4 | 5-10 | F,Xi | 11-36-66-67 | B |
Naphtha (petroleum), hydrotreated light (benzene<0.1%) | 64742-49-0 | 265-151-9 | 5-10 | Xn | 65 | B,P |
Naphtha (petroleum), hydrodesulfurized heavy (benzene<0.1%) | 64742-82-1 | 265-185-4 | 5-15 | Xn | 65 | B,P |
aluminium powder (stabilized) | 7429-90-5 | 231-072-3 | 1-5 | F | 11-15 | A |
1,2,4-trimethylbenzene | 95-63-6 | 202-436-9 | <1 | Xn,N | 10-20-36/37/38-51/53 | A |
2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime | 96-29-7 | 202-496-6 | <0.1 | Xn | 21-40-41-43 | B |
Explanation notes | ||||||
A : substance with Community workplace exposure limit | ||||||
B : substance with national established workplace exposure limit | ||||||
P : not classified as carcinogen, less than 0.1% w/w benzene (Einecs-nr. 200-753-7) |
General Advice : |
If symptoms persist always call a doctor |
Contact with eyes : |
If substance has got into eyes, immediately wash out with plenty of water for several minutes Seek medical advice |
Contact with skin : |
Wash with water and soap. Seek medical attention if irritation persists |
Inhalation : |
Fresh air, keep warm and at rest. Seek medical attention if ill effects occur |
Ingestion : |
Ingestion is unlikely to occur If swallowed do not induce vomiting because of risk of aspiration into the lungs. If aspiration is suspected obtain immediate medical attention |
Flash point (without propellant): |
< 0 °C |
Explosion limits : upper limit : |
Not available. |
lower limit : |
Not available. |
Extinguishing media : |
foam, carbon dioxide or dry agent |
Fire-fighting procedures : |
Keep container(s) exposed to fire cool, by spraying with water |
Unusual exposure hazard : |
Aerosols may explode if heated above 50°C In case of fire, do not breathe fumes |
Personal precautions : |
Shut off all ignition sources Ensure adequate ventilation |
Environmental precautions : |
Do not allow to enter public sewers and watercourses If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities |
Cleaning methods : |
Absorb spillage in suitable inert material |
Handling procedures : |
Use only in well ventilated areas Keep away from heat and sources of ignition Do not spray on a naked flame or incandescent material. Do not pierce or burn aerosols, even after use. Do not breathe aerosols or vapours. Avoid contact with skin and eyes. |
Storage procedures : |
Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C. Keep in a cool, dry, well ventilated place Keep out of reach of children. |
Control procedures : |
Ensure adequate ventilation Keep away from heat and sources of ignition Take precautionary measures against static discharges |
Personal protection : |
It is advisable to take precautions to avoid contact with skin and eyes when handling the product. Use only in well ventilated areas |
inhalation : |
In case of insufficient ventilation, wear suitable respiratory equipment. (Filter type A) Wear breathing apparatus |
hands and skin : |
Wear suitable protective gloves (nitrile) |
eyes : |
Wear safety goggles. |
Exposure limits : |
Hazardous ingredient | CAS-nbr. | method | |
EU established exposure limits: | |||
mesitylene1,3,5-trimethylbenzene | 108-67-8 | TWA | 20 ppm |
dimethyl ether | 115-10-6 | TWA | 1000 ppm |
1,2,4-trimethylbenzene | 95-63-6 | TWA | 20 ppm |
Apperance : physical state : |
DME propelled liquid. |
colour : |
Grey. |
odour : |
Solvent. |
Boiling point/range : |
Not available. |
Relative density : |
0.969 g/cm3 (@ 20°C). |
pH : |
Not applicable. |
Vapour pressure : |
Not available. |
Relative vapour density : |
Not available. |
Solubility in water : |
Insoluble in water |
Flash point : |
< 0 °C |
Auto-ignition : |
> 200 °C |
Viscosity : |
Not applicable. |
Evaporation rate : |
Not available. |
Conditions to be avoided : |
Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C. Keep away from heat and sources of ignition |
Materials to be avoided : |
Strong oxidising agent |
Hazardous decomposition compounds : |
CO,CO2 |
Inhalation : |
Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness |
Ingestion : |
Ingestion is unlikely to occur After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia. |
Skin contact : |
Prolonged skin contact will result in defatting of the skin, leading to irritation, and in some cases, dermatitis |
Eye contact : |
May cause irritation. |
Other adverse effects : |
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
|
Do not allow to enter public sewers and watercourses |
Product : |
Do not discharge into drains or the environment, dispose to an authorised waste collection point. This material and its container must be disposed of in a safe way. |
|
Disposal should be in accordance with local, state or national legislation |
UN-number : |
1950 |
Road/Rail - ADR/RID : |
UN1950 Aerosols Class : 2, PG : NA, Class code : 5F, Label : 2.1, Tunnel-code : (D) |
Sea - IMDG : |
UN1950 Aerosols Class : 2, PG : NA, Label : 2.1 |
EmS |
F-D, S-U |
Air - IATA/ICAO : |
UN1950 Aerosols, flammable Class : 2, PG : NA, Label : 2.1 |
Warning symbol(s) : |
F+ : EXTREMELY FLAMMABLE |
Risk-phrase(s) : |
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
Safety-phrase(s) : |
S2: Keep out of the reach of children. S16: Keep away from sources of ignition - No smoking. S23: Do not breathe vapours/spray. S35: This material and its container must be disposed of in a safe way. S51: Use only in well-ventilated areas. |
Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Without adequate ventilation formation of explosive mixtures may be possible. |
Classified according to Dir. 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC. Remark: Preparations classified as harmful on the basis of an aspiration hazard need not be labelled as harmful with R65 when placed on the market in aerosol containers or in containers fitted with a sealed spray attachment. (EU-Directive 67/548 Annex VI 9.4) Classification according to EU-directive 99/45/EC |
This product should be stored, handled and used in accordance with good
industrial hygiene practices and in conformity with any legal
regulation. The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties. Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks, no part of these documents may be reproduced by any process without written permission from CRC. |
REVISIONS IN CHAPTRE : |
2,3,8,11,14,15 |
*Explanation risk-phrases: |
R10: Flammable. R11: Highly flammable. R12: Extremely flammable. R15: Contact with water liberates extremely flammable gases. R36: Irritating to eyes. R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65: Harmful: may cause lung damage if swallowed. R66: Repeated exposure may cause skin dryness or cracking. R67: Vapours may cause drowsiness and dizziness. |
This Material Safety Data Sheet may already have been revised at this moment for reason such as legislation, availability of components and newly acquired experiences. The latest and only valid version of this Material Safety Data Sheet will be sent to you upon simple request or can be found on our website : www.crcind.com. We recommend you to register on this website for this product so you will be able to receive any future updated version automatically. |